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===================== Product Identification ===================== Product ID:BLASOCUT 4000 UNIVERSAL ART, 872 Preparer's Name:OH&S COORDINATOR CAGE:IO424 CAGE:IO424 ============= Composition/Information on Ingredients ============= Ingred Name:CITRIC ACID CAS:77-92-9 RTECS #:GE7350000 OSHA PEL:N/K ACGIH TLV:N/K Ingred Name:TARTARIC ACID CAS:87-69-4 RTECS #:WW7875000 OSHA PEL:N/K ACGIH TLV:N/K Ingred Name:L-ASCORBIC ACID; (ASCORBIC ACID) CAS:50-81-7 RTECS #:CI7650000 OSHA PEL:N/K ACGIH TLV:N/K Ingred Name:L-ASCORBIC ACID, 6-PALMITATE; (ASCORBYLPALMITATE) CAS:137-66-6 RTECS #:CI7671040 OSHA PEL:N/K ACGIH TLV:N/K Ingred Name:OLEYLSARCOSINE OSHA PEL:N/K ACGIH TLV:N/K Ingred Name:STABILIZER; (1-HYDROXYETHYL-2-OLEYL-IMIDAZOLINE) OSHA PEL:N/K ACGIH TLV:N/K Ingred Name:GLYCEROL; (GLYCERIN) CAS:56-81-5 RTECS #:MA8050000 OSHA PEL:N/K ACGIH TLV:N/K Ingred Name:BENZO(A)PYRENE. %:<10 PPM. CAS:50-32-8 RTECS #:DJ3675000 Fraction by Wt: <0.1% OSHA PEL:N/K ACGIH TLV:N/K EPA Rpt Qty:1 LB DOT Rpt Qty:1 LB Ingred Name:MINERAL OIL, PETROLEUM DISTILLATES, HYDROTREATED (SEVERE) HEAVY NAPHTHENIC; (SEVERELY HYDROTREATED MINERAL OIL) CAS:64742-52-5 RTECS #:PY8035001 Fraction by Wt: 45-65% OSHA PEL:5MG/M3 OIL MIST(MFR) ACGIH TLV:5MG/M3 OIL MIST(MFR) Ingred Name:EMULSIFIERS; (CONSISTING OF INGS 2 - 4) CAS:68608-26-4 Fraction by Wt: 30-45% OSHA PEL:N/K ACGIH TLV:N/K Ingred Name:TALL OIL FATTY A. K. SALT; (EMULSIFIER) CAS:61790-44-1 OSHA PEL:N/K ACGIH TLV:N/K Ingred Name:EMULSIFIERS CAS:61791-12-6 OSHA PEL:N/K ACGIH TLV:N/K Ingred Name:CHLORINATED PARAFFINS; (C*16-20 LESS THAN 50% CHLORINE) CAS:61788-76-9 Fraction by Wt: 5-15% OSHA PEL:N/K ACGIH TLV:N/K Ingred Name:ANIMAL FATTY OIL; (POLAR ADDITIVES) (CONSISTING OF INGS 6 & 7) CAS:8016-28-2 Fraction by Wt: 2-5% OSHA PEL:5 MG/M3 (0IL MIST) ACGIH TLV:5 MG/M3 (OIL MIST) Ingred Name:POLAR ADDITIVES CAS:61788-66-7 OSHA PEL:N/K ACGIH TLV:N/K Ingred Name:CORROSION AND FUNGI INHIBITORS Fraction by Wt: 0.5-1% OSHA PEL:N/K ACGIH TLV:N/K Ingred Name:ODORANT AND DYE (TECHNICAL GRADE OF FOOD DYE) Fraction by Wt: <0.1% OSHA PEL:N/K ACGIH TLV:N/K Ingred Name:STABILIZERS (CONSISTING OF INGS 11-22) Fraction by Wt: <2% OSHA PEL:N/K ACGIH TLV:N/K Ingred Name:BENZOIC ACID, SODIUM SALT; (NA-BENZOATE) CAS:532-32-1 RTECS #:DH6650000 OSHA PEL:N/K ACGIH TLV:N/K Ingred Name:STABILIZER; (2,3-PENTANDIOL, 2-METHYL) OSHA PEL:N/K ACGIH TLV:N/K Ingred Name:1-PHENOXY-2-PROPANOL; (2-PROPANOL, 1-PHENOXY) OSHA PEL:N/K ACGIH TLV:N/K Ingred Name:ACETIC ACID, CALCIUM SALT; (CA-ACETATE) CAS:62-54-4 RTECS #:AF7525000 OSHA PEL:N/K ACGIH TLV:N/K Ingred Name:ALPHA-TOCOPHEROL OSHA PEL:N/K ACGIH TLV:N/K ===================== Hazards Identification ===================== LD50 LC50 Mixture:LD50: >15 G/KG. Routes of Entry: Inhalation:NOSkin:NO Ingestion:NO Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:BLASOCUT HAS BEEN EXTENSIVELY TESTED AS A WHOLE FOR IT'S HEALTH HAZARDS: EYE IRRITATION/SKIN SENSITIZING:NEGATIVE. INHALATION UNLIKELY. INGESTION:ACCIDENTAL ONLY. COPIES OF ACTUAL TEST CONDUCTED BY IN DEPENDENT LABS ARE AVAILABLE FOR INSPECTION ON REQUEST. Explanation of Carcinogenicity:NOT RELEVANT Effects of Overexposure:NONE ESTABLISHED. Medical Cond Aggravated by Exposure:NOT ESTABLISHED. ======================= First Aid Measures ======================= First Aid:SKIN:WASH W/PLENTY OF SOAP & FRESH WATER (GOOD PERSONAL HYGIENE PRACTICES ARE SUFFICIENT). REMOVE ANY CONTAMINATED CLOTHING & LAUNDER BEFORE REUSE. EYE:RINSE W/PLENTY OF FRESH WATER FOR AT LEAST 20 MI NUTES. CONSULT MD IF NECESSARY. INHAL:REMOVE TO FRESH AIR. INGEST:DO NOT INDUCE VOMITING. PULMONARY ASPIRATION HAZARD, CONSULT MD W/OUT DELAY. ===================== Fire Fighting Measures ===================== Flash Point Method:COC Flash Point:>334F,>168C Extinguishing Media:CO*2, DRY CHEMICAL, FOAM. Fire Fighting Procedures:USE NIOSH APPROVED SCBA & FULL PROTECTIVE EQUIPMENT . COOL EXPOSED CONTAINERS W/WATER MIST. Unusual Fire/Explosion Hazard:PRODS FORMED UNDER ABNORM CNDTNS:THERMAL DECOMP OF CONC >176F MAY PRDCE TRACE AMTS OF HCL. HAZ COMBUST PRODS:OXIDES OF CARBON, NITROGEN & TRACES OF (SUPP DATA) ================== Accidental Release Measures ================== Spill Release Procedures:AS WITH ANY OTHER INDUSTRIAL LUBRICATING OIL, USE OIL-BINDING AGENTS. SPILLS OR LEAKS MAY CAUSE SLIPPERY CONDITIONS. Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER. ======================Handling and Storage ====================== Handling and Storage Precautions:AVOID DIRECT SOLAR IRRADIATION OF CONCENTRATE DRUMS. Other Precautions:DO NOT STORE W/STRONG OXIDIZERS. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:NIOSH APPROVED RESPIRATOR APPROPRIATE FOR EXPOSURE OF CONCERN . NOT GENERALLY REQUIRED. Ventilation:NORMAL GENERAL VENTILATION IS SUFFICIENT. Other Protective Equipment:EYE WASH FOUNTAIN & DELUGE SHOWER WHICH MEET ANSI DESIGN CRITERIA . Work Hygienic Practices:THOROUGH PERSONAL HYGIENE & CLEAN WORKING PRACTICES ARE SUFFICIENT. Supplemental Safety and Health PH @ 5%:AFTER 24 HRS:8.7. EXPLO HAZ:OXIDES OF CHLORINE & SULFUR, HCL. CNDTNS(STAB):AWAY FROM STRONG OXIDIZERS. ================== Physical/Chemical Properties ================== Boiling Pt:B.P. Text:572F,300C Vapor Pres:NOT VOLAT Spec Gravity:0.976 pH:SUPDAT Solubility in Water:EMULSIFIES Appearance and Odor:GREEN LIQUID; PLEASANT ODOR (ALMONDS). Percent Volatiles by Volume:NIL ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES CONCENTRATE:STRONG OXIDIZERS; END USE DILUTIONS:MAGNESIUM. Stability Condition to Avoid:AVOID DIRECT SOLAR IRRADIATION OF DRUMS. GOOD & SAFE HOUSEKEEPING PROCS SUGGEST THAT ALL COMBUST MATLS BE STORED(SUPDAT) Hazardous Decomposition Products:THERMAL DECOMPOSITION (CONCENTRATE) ABOVE 176F:TRACE AMOUNTS OF HCL. ==================== Disposal Considerations ==================== Waste Disposal Methods:SPLIT EMULSION W/ADSORBING AGENTS, SALTS OR ULTRA-FILTRATION. DISPOSE ACCORDING TO ALL APPLICABLE FEDERAL, STATE & LOCAL REGULATIONS.
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:CADMIUM CHLORIDE, HYDRATED CAGE:94480 CAGE:1B464 CAGE:94480 ============= Composition/Information on Ingredients ============= Ingred Name:CADMIUM CHLORIDE (SARA III) CAS:10108-64-2 RTECS #:EV0175000 Fraction by Wt: 100%. OSHA PEL:SEE 1910.1027 ACGIH TLV:0.05 MG(CD)/M3; 9293 EPA Rpt Qty:10 LBS DOT Rpt Qty:10 LBS ===================== Hazards Identification ===================== LD50 LC50 Mixture:194 MG/KG ORAL MOUSE LD50 Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES Reports of Carcinogenicity:NTP:YES IARC:YES OSHA:NO Health Hazards Acute and Chronic:NEPHROTOXIN. UPPER RESPIRATORY TRACT IRRITATION, LUNG/KIDNEY/LIVER DAMAGE, PULMONAY EDEMA, RHINITIS, BRONCHITIS, EMPHYSEMA, DYSPNEA, ABNORMAL LUNG FUNCTION, FIBROSIS, SKIN IRRITATION, DERMATITIS, EYE IRRITATION, CONJUNCTIVITIS, FAACIAL EDEMA, GASSTROINTESTINAL DISTURBANCES, HYPOTENSION, RESPIRATORY ARREST, DEATH. Explanation of Carcinogenicity:CADMIUM CHLORIDE IS CLASSED AS ANTICIPATED HUMAN CARCINOGEN BY NTP AND GROUP 2A BY IARC. Effects of Overexposure:COUGH, CHEST PAIN, DIZZINESS, ABDOMINAL PAIN, NAUSEA, VOMITING, LUNG/KIDNY/LIVER DAMAGE, DEATH, DECREASED CONCENTRATING CAPACITY, YELLOWING OF TEETH, DECREASED CREATININE EXCRETION, BACK PAIN, PAIN IN EXTREMETIES,PAIN ON BONE PRESSURE, SKIN IRRITATION, EYE IRRITATION, FACIAL EDEMA. Medical Cond Aggravated by Exposure:NONE SPECIFIED BY MANUFACTURER. ======================= First Aid Measures ======================= First Aid:INHALATION: REMOVE FROM EXPOSURE. RESTORE BREATHING. KEEP WARM AND QUIET. GET MEDICAL ATTENTION. SKIN: WASH AFFECTED AREA THOROUGHLY WITH SOAP AND WATER. IF IRRITATION PERSISTS, GET MEDICAL ATTENTION.EYES: FLUSH WITH LARGE AMOUNTS OF WATER FOR 15 MINUTES. GET MEDICAL ATTENTION. INGESTION: IF VOMITING HAS NOT OCCURRED, USE EMISIS OR GASTRIC LAVAGE. KEEP HEAD BELOW HIPS. GET MEDICAL ATTENTION. ===================== Fire Fighting Measures ===================== Flash Point:NON FLAMMABLE Lower Limits:NOT GIVEN Upper Limits:NOT GIVEN Extinguishing Media:DRY CHEMICAL, CARBON DIOXIDE, WATER SPRAY, REGULAR FOAM Fire Fighting Procedures:MOVE CONTAINER FROM FIRE IF CAN DO SO WITHOUT RISK. DO NOT SCATTER SPILLED MATERIAL WITH HIGH PRESSURE WATER STREAM. Unusual Fire/Explosion Hazard:AVOID BREATHING HAZARDOUS VAPORS. KEEP UPWIND. ================== Accidental Release Measures ================== Spill Release Procedures:DO NOT TOUCH SPILLED MATERIAL. STOP LEAK IF CAN DO SO WITHOUT RISK. TAKE UP WITH SAND OR OTHER ABSORBENT MATERIAL AND PLACE INTO CONTAINERS FOR DISPOSAL. REPORTABLE QUANTITY IS 100 POUNDS. Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER. ======================Handling and Storage ====================== Handling and Storage Precautions:PREVENT DISPERSION OF DUST IN AIR. Other Precautions:DO NOT ALLOW MATERIAL TO CONTAMINATE WATER SOURCES. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:IF VENTILATION DOES NOT MAINTAIN INHALATION EXOSURES BELOW PEL (TLV), USE NIOSH/MSHA APPROVED RESPIRATOR AS PER CURRENT 29 CFR 1910.134, INSTRUCTIONS/WARNINGS AND NIOSH RESPIRATOR SELECTION. Ventilation:PROVIDE LOCAL EXHAUST OR PROCESS ENCLOSURE VENTILATION TO MEET PUBLISHED EXPOSURE LIMITS. Other Protective Equipment:EYEWASH FOUNTAIN AND QUICK DRENCH EMERGENCY SHOWER. Work Hygienic Practices:WASH WITH SOAP AND WATER AFTER HANDLING PRODUCT AND BEFORE EATING DRINKING OR SMOKING. Supplemental Safety and Health ANTIDOTE: DO NOT GIVE DIMERCAPROL. IF SYMPTOMS PERSIST, GIVE CALCIUM DISODIUM EDETATE. GIVE 15-25 MG/KG IN 250-500 ML OF DEXTROSE INTRAVENOUSLY OVER A 1-2 HOUR PERIOD, TWICE DAILY. ================== Physical/Chemical Properties ================== HCC:T6 Boiling Pt:B.P. Text:NOT GIVEN Melt/Freeze Pt:M.P/F.P Text:93.0F,33.9C Vapor Pres:NOT GIVEN Vapor Density:NOT GIVEN Spec Gravity:3.3 Evaporation Rate & Reference:NIL Solubility in Water:COMPLETE Appearance and Odor:EFFLORESCENT GRANULES OR RHOMBOHEDRAL LEAFLETS Percent Volatiles by Volume:NIL ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES BROMINE TRIFLUORIDE, POTASSIUM Stability Condition to Avoid:EXTREME TEMPERATURES Hazardous Decomposition Products:CADMIUM OXIDES AND FUMES OF CHLORIDES ==================== Disposal Considerations ==================== Waste Disposal Methods:PREVENT WASTE FROM CONTAMINATING SURROUNDING ENVIRONMENT. DISCARD ANY PRODUCT, RESIDUE, DISPOSAL CONTAINER OR LINER IN ACCORDANCE WITH ALL FEDERAL, STATE AND LOCAL REGULATIONS.
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:TYPE I, ALIPHATIC ISOCYANATE MIL-PRF-85285C (MIL-C-85285B) Preparer's Name:ERNEST CARTER CAGE:33461 CAGE:33461 ============= Composition/Information on Ingredients ============= Ingred Name:POLY HEXAMETHYLENE DIISOCYANATE CAS:28182-81-2 Code:F RTECS #:NQ9170000 = Wt:35. Ingred Name:C8&10 AROMATIC HYDROCARBON CAS:64742-95-6 Code:F RTECS #:WF3400000 < Wt:5. Ingred Name:N-BUTYL ACETATE CAS:123-86-4 RTECS #:AF7350000 < Wt:5. OSHA PEL:710 MG/M3;150 PPM ACGIH TLV:713 MG/M3;150 PPM ACGIH STEL:950 MG/M3;200 PPM EPA Rpt Qty:5000 LBS DOT Rpt Qty:5000 LBS Ingred Name:ETHYL 3-ETHOXYPROPIONATE CAS:763-69-9 RTECS #:UF3325000 = Wt:20. ===================== Hazards Identification ===================== Health Hazards Acute and Chronic:VAPORS ARE IRRITATING TO EYES, NOSE AND THROAT. INHALATION MAY CAUSE HEADACHES, DIFFICULT BREATHING AND LOSS OF CONSCIOUSNESS. AS A RESULT OF PREVIOUS REPEATED OVEREXPOSURE OR A SINGLE LARGE DOSE, CER TAIN INDIVIDUALS WILL DEVELOP ISOCYANATE SENSITIZATION WHICH WILL CAUSE THEM TO REACT TO A LATER EXPOSURE OF ISOCYANATE LEVELS WELL BELOW THE TLV VALUE OF ISOCYANATES. Effects of Overexposure:INHALATION: IRRITATION OF THE RESPIRATORY TRACT& ACUTE NERVOUS SYSTEM DEPRESSION CHARATERIZED BY THE FOLLOWING PROGRESSIVE STEPS: HEADACHE, DIZZINESS, STAGGERING GAIT, CONFUSION, UNCONSCIOUSNESS OR CO MA. SKIN: CONTACT WITH THE SKIN CAN CAUSE IRRITATION. SYMPTOMS MAY BE SWELLING, REDNESS, AND RASH.EYES: LIQUID, AREOSOLS, OR VAPORS ARE IRRITATING AND MAY CAUSE TEARING, REDNESS, AND SWELLING ACCOMP ANIED BY A STINGING SENSATION. INGESTION: CAN RESULT IN IRRITATION AND POSSIBLE CORROSIVE ACTION IN THE MOUTH, STOMACH TISSUE AND DIGESTIVE TRACT. ======================= First Aid Measures ======================= First Aid:INHALATION: MOVE TO AN AREA FREE FROM RISK OF FUTHER EXPOSURE. RESTORE BREATHING.ASTHMATIC TYPE SYMPTOMS MAY DEVELOP AND MAY BE IMMEDIATE OR DELAYED BY SEVERAL HOURS. OBTAIN MEDICAL ATTENTION. SKIN: W ASH AFFECTED AREAS THOROUGHLY WITH SOAP AND WATER.WASH CONTAMINATED CLOTHING THOROUGHLY BEFORE REUSE. EYES: FLUSH WITH CLEAN LUKEWARM WATER (LOW PRESSURE) FOR 15 MINUTES, OCCASIONALLY LIFTING EYELIDS. OBTAIN MEDICAL ATTENTION. INGESTION: DO NOT INDUCE VOMITING. DO NOT GIVE ANYTHING TO AN UNCONSCIOUS PERSON. OBTAIN MEDICAL ATTENTION. ===================== Fire Fighting Measures ===================== Flash Point Method:TCC Flash Point:=24.4C, 76.F Lower Limits:1.00% Upper Limits:7.60% Extinguishing Media:FOAM, ALCOHOL FOAM, CO2, DRY CHEMICAL, WATER FOG, WATER SPRAY. Fire Fighting Procedures:FULL FIRE FIGHTING EQUIPMENT WITH SELF-CONTAINED BREATHING APPARATUS AND FULL PROTECTIVE CLOTHING SHOULD BE WORN BY FIRE FIGHTERS. WATER MAY BE USED TO COOL CLOSED CONTAINER TO PREVENT PRESSURE BUIL D UP. AUTO IGNITION OR EXPLOSION. Unusual Fire/Explosion Hazard:KEEP CONTAINERS TIGHTLY CLOSED. ISOLATE FROM HEAT, SPARKS, ELECTRICAL EQUIPMENT AND OPEN FLAME. CLOSED CONTAINERS MAY EXPLODE WHEN EXPOSED TO EXTREME HEAT. APPLICATION TO HOT SURFACES REQUIRES SPECIAL PRECAUTIONS. DURING EMERGENCY CONDITIONS OVERXEPOSURE TO DECOMPOSITION PRODUCTS MAY CAUSE A HEALTH HAZARD. ================== Accidental Release Measures ================== Spill Release Procedures:EVACUATE ALL NON-ESSENTIAL PERSONNEL. REMOVE ALL SOURCES OF IGNITION (FLAME, SPARK SOURCES, HOT SURFACES).VENTILATE AREA CONTAIN AND REMOVE WITH INERT ABSORBENT AND NON-SPARKING TOOLS. ======================Handling and Storage ====================== Handling and Storage Precautions:STORE IN TIGHTLY CLOSED CONTAINERS. STORE IN WELL VENTILATED AREAS. Other Precautions:KEEP CONTAINERS TIGHT AND UPRIGHT TO PREVENT LEAKAGE. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:A RESPIRATOR THAT IS RECOMMENDED OR APPROVED FOR USE IN AN ORGANIC VAPOR ENVIRONMENT (AIR PURIFYING OR FRESH AIR SUPPLIED)IS NECESSARY. OBSERVE OSHA REGULATIONS FOR RESPIRATOR USE. Ventilation:EXHAUST VENTILATION SUFFICIENT TO KEEP THE AIRBORNE CONCENTRATIONS OF SOLVENT VAPORS OR MISTS BELOW THEIR RESPECTIVE TLV?S MUST BE UTILIZED. REMOVE ALL IGNITION RUBBER POLYETHYLENE) Other Protective Equipment:THE USE OF LONG SLEEVE AND LONG LEG CLOTHING IS RECOMMENDED. Supplemental Safety and Health ================== Physical/Chemical Properties ================== Boiling Pt:B.P. Text:260-428 DEG F Vapor Density:HEAVIER Spec Gravity:1.08163 VOC Pounds/Gallon:279 Viscosity:THIN LIQUID TO HEAVY Evaporation Rate & Reference:0.16 X N-BUTYL ACETATE Solubility in Water:INSOLUBLE Appearance and Odor:AMBER LIQUID WITH SOLVENT ODOR Percent Volatiles by Volume:29.9% ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES STRONG OXIDIZING AGENTS. Stability Condition to Avoid:HIGH TEMPERATURES, SPARKS, OR OPEN FLAMES. Hazardous Decomposition Products:CARBON MONOXIDE, CARBON DIOXIDE, AND OXIDES OF NITROGEN. Conditions to Avoid Polymerization:WILL NOT OCCUR. ==================== Disposal Considerations ==================== Waste Disposal Methods:WASTE MUST BE DISPOSED OF IN ACCORDANCE WITH FEDERAL, STATE, AND LOCAL ENVIRONMENTAL CONTROL REGULATIONS.
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:FORMTECH N CAGE:0DTP3 CAGE:0DTP3 ============= Composition/Information on Ingredients ============= Ingred Name:MEDIUM ALIPHATIC NAPHTHA (AROMATIC 100), PARAFFIN-NAPTHANES MINERAL SPIRITS CAS:64742-88-7 Other REC Limits:100 PPM OSHA PEL:500 PPM ACGIH TLV:100 PPM Ingred Name:PETROLEUM HYDROCARBONS, SOLVENT DEWAXED RESIDUAL OIL (PETROLEUM) *94-2* CAS:64742-62-7 ===================== Hazards Identification ===================== Routes of Entry: Inhalation:YES Skin:NO Ingestion:NO Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:EYES: IRRITATION, TEARING & REDNESS. SKIN: MODERATE IRRITATION. INHALATION: DROWSINESS, COLLAPSE & RESPIRATORY IRRITATION. Explanation of Carcinogenicity:NONE Effects of Overexposure:EYES: IRRITATION, TEARING & REDNESS. SKIN: MODERATE IRRITATION. INHALATION: DROWSINESS, COLLAPSE & RESPIRATORY IRRITATION. ======================= First Aid Measures ======================= First Aid:EYES: FLUSH FOR 20 MINS. SKIN: WASH W/SOAP & PLENTY OF WATER. INHALATION: REMOVE TO FRESH AIR. INGESTION: DON'T INDUCE VOMITING. OBTAIN MEDICAL ATTENTION IN ALL CASES. ===================== Fire Fighting Measures ===================== Flash Point Method:TCC Flash Point:260F Lower Limits:1 Upper Limits:6 Extinguishing Media:DRY CHEMICAL, FOAM/CO2 Fire Fighting Procedures:USE SELF CONTAINED BREATHING APPARATUS. WATER IS UNSUITABLE AS EXTINGUISHING MEDIA, BUT CAN BE USED TO KEEP ADJACENT CONTAINERS COOL. Unusual Fire/Explosion Hazard:KEEP WORK AREAS FREE OF HOT METAL SURFACES & OTHER IGNITION SOURCES. ================== Accidental Release Measures ================== Spill Release Procedures:KEEP IGNITION SOURCES & HOT METAL SURFACES ISOLATED FROM THE AREA. FLUSH MATERIAL INTO SUITABLE RETAINING AREAS/CONTAINERS W/PLENTY OF WATER. MATERIAL MAY BE ABSORBED INTO AN APPROPRIATE ABSORBANT. ======================Handling and Storage ====================== Handling and Storage Precautions:WARNINGS & PLACARDS REQUIRED ONLY WHEN PACKAGED IN CONTAINERS HOLDING 110 GALLONS/MORE. NA 1993 Other Precautions:USE ONLY IN WELL VENTILATED AREAS UNLESS RECOMMENDED RESPIRATORY PROTECTION IS USED. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:IF TLV OF THE PRODUCT IS EXCEEDED IN UNVENTILATED AREA, NIOSH/MSHA JOINTLY APPROVED AIR SUPPLIED RESPIRATOR IS ADVISED. Ventilation:SUFFICIENT MECHANICAL TO MAINTAIN EXPOSURE BELOW TLV. Other Protective Equipment:IMPERVIOUS CLOTHING/BOOTS. Work Hygienic Practices:KEEP BODY CONTACT & SPLASH TO A MINIMUM. Supplemental Safety and Health ================== Physical/Chemical Properties ================== Boiling Pt:B.P. Text:470F Vapor Pres:0.01 Vapor Density:8 Spec Gravity:0.813 Evaporation Rate & Reference:(BU AC=1): 0.1 Solubility in Water:NEGLIGIBLE Appearance and Odor:PALE, TRANSPARENT BLUEGREEN W/LIGHT, MILD OILY ODOR ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES STRONG OXIDIZING AGENTS Stability Condition to Avoid:NONE Hazardous Decomposition Products:CO/CO2 ==================== Disposal Considerations ==================== Waste Disposal Methods:DISPOSE OF IN ACCORDANCE W/LOCAL, STATE & FEDERAL REGULATIONS. COMBUSTIBLE LIQUID WHEN PACKAGED IN CONTAINERS HOLDING 110 GALLONS/MORE.
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:7B161 CAGE:00213 CAGE:00213 ============= Composition/Information on Ingredients ============= Ingred Name:POLYCHLORINATED BIPHENYLS (PCBS) (SARA III) CAS:1336-36-3 RTECS #:TQ1350000 EPA Rpt Qty:1 LB DOT Rpt Qty:1 LB ===================== Hazards Identification ===================== Effects of Overexposure:ABSORBED THRU SKIN,LUNGS,INTESTINE.CAUSES CANCER,LIVER,KIDNEY,STOMACH,EYE,HEARING DISORDER(SUP DATA) ======================= First Aid Measures ======================= First Aid:EYES:FLUSH W/WATER IMMEDIATELY.SKIN:WASH W/SOAP IMMEDIATELY.INHAL:REMOVE TO FRESH AIR,GIVE ART.RESPIR.AS NEEDED.INGEST:GET MEDICAL ATTN.GIVE LARGE QTY OF SALT WATER,INDUCE VOMITING,BUT DO NOT MAKE UNC ONSCIOUS PERSON VOMIT. ================== Accidental Release Measures ================== Spill Release Procedures:USE ABSORBENT & DIKES TO PREVENT RUNOFF.ISOLATE & NOTIFY PROPER AUTHORITIES. ======================Handling and Storage ====================== Handling and Storage Precautions:STORAGE MUST FOLLOW RCRA REQUIREMENTS. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:SUPPLIED AIR W/FULL FACEPIECE,HELMET OR HOOD Ventilation:LOCAL EXHAUST Other Protective Equipment:FULL CLOTHING TO PREVENT SKIN CONTACT Supplemental Safety and Health OVEREXPOS:CAN CAUSE FORMATION OF CYSTS,CAUSES STILLBIRTHS.IRRITATES EYES,NOSE THROAT. ================== Physical/Chemical Properties ================== HCC:Z3 Appearance and Odor:LIGHT STRAW-COLORED LIQUID,AROMATIC ODOR ================= Stability and Reactivity Data ================= STRONG OXIDIZERS ==================== Disposal Considerations ==================== Waste Disposal Methods:CONTROLLED DISPOSAL REQUIRED-GENERALLY HIGH TEMPERATURE INCINERATION.ONLY APPROVED DISPOSAL OPERATOR PERMITTED.
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:ZINC ALLOYS - ZAMAK 2 CAGE:9C162 CAGE:9C162 ============= Composition/Information on Ingredients ============= Ingred Name:ZINC CAS:7440-66-6 RTECS #:ZG8600000 ACGIH TLV:10 MG/CUM EPA Rpt Qty:1000 LBS DOT Rpt Qty:1000 LBS Ingred Name:ALUMINUM (POWDER) CAS:7429-90-5 RTECS #:BD0330000 Fraction by Wt: 3.5-4.3% OSHA PEL:15 MG/CUM ACGIH TLV:10 MG/CUM (DUST) Ingred Name:COPPER (DUST & MIST), BRONZE POWDER CAS:7440-50-8 RTECS #:GL5325000 Fraction by Wt: 2.5-3% Other REC Limits:1 MG(CU)/M3 (DUST) OSHA PEL:0.1 MG(CU)/M3 (FUME) ACGIH TLV:0.2 MG/M3 (FUME) EPA Rpt Qty:5000 LBS DOT Rpt Qty:5000 LBS Ingred Name:ZINC OXIDE CAS:1314-13-2 RTECS #:ZH4810000 OSHA PEL:5 MG/CUM ACGIH TLV:5 MG/CUM FUME Ingred Name:ALUMINUM OXIDE, BAUXITE, ALUMINA, DIALUMINUM TRIOXIDE CAS:1344-28-1 RTECS #:BD1200000 OSHA PEL:15 MG/CUM ACGIH TLV:10 MG/CUM Ingred Name:COPPER OXIDE, FERRITE CAS:1317-38-0 RTECS #:GL7900000 Ingred Name:COPPER OXIDE CAS:1317-39-1 RTECS #:GL8050000 ACGIH TLV:1 MG/CUM ===================== Hazards Identification ===================== Routes of Entry: Inhalation:YES Skin:NO Ingestion:NO Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:INHALATION: NOSE IRRITATION & LUNG CHANGES, METAL FUME FEVER, & PULMONARY FIBROSIS/DISEASES. SKIN & EYE IRRITATION. Explanation of Carcinogenicity:NONE Effects of Overexposure:INHALATION: FLULIKE SYMPTOMS, SWEET TASTE IN MOUTH, DRYNESS, COUGH, GENERALIZED ACHING, NAUSEA, VOMITING, CHILLS, FEVER, PROFUSE SWEATING, WEAKNESS. SKIN/HAIR DISCOLORATION. Medical Cond Aggravated by Exposure:PULMONARY & CARDIAC DISEASES FOR ZINC OXIDE. WILSON'S DISEASE FOR COPPER. ======================= First Aid Measures ======================= First Aid:EYES: FLUSH W/WATER. SKIN: VACUUM OFF EXCESS DUST. WASH W/PLENTY OF SOAP & WATER. IF MATERIAL IS MOLTEN, TREAT AS A BURN. INHALATION: REMOVE TO FRESH AIR. INGESTION: FOR LARGE QUANTITIES, INDUCE VOMIT ING IF CONSCIOUS. OBTAIN MEDICAL ATTENTION IN ALL CASES. ===================== Fire Fighting Measures ===================== Flash Point:NON-FLAMMABLE Extinguishing Media:CO2, DRY CHEMICAL OR DRY SAND. DON'T USE WATER OR MOIST SAND. ZINC ALLOYS WILL NOT BURN IN THE SOLID STATE. Fire Fighting Procedures:WEAR FULL BODY PROTECTIVE CLOTHING & FULL FACEPIECE INCLUDING SELF-CONTAINED BREATHING APPARATUS OPERATED IN POSITIVE-PRESSURE MODE. Unusual Fire/Explosion Hazard:NEVER PUT WATER ON MOLTEN METAL; IT WILL EXPLODE. IF POWDER/DUST IS EXPOSED TO IGNITION SOURCE/CONTACTS POWERFUL OXIDIZERS, CAN LIBERATE EXPLOSIVE HYDROGEN GAS. ================== Accidental Release Measures ================== VACUUMING/WET SWEEPING TO PREVENT HEAVY CONCENTRATIONS OF AIRBORNE DUST. DON'T USE COMPRESSED AIR FOR CLEANING. WEAR RESPIRATORY PROTECTION & PROTECTIVE CL OTHING. PLACE COLLECTED METAL IN LABELED CONTAINER ======================Handling and Storage ====================== Handling and Storage Precautions:STORE METAL IN DRY AREA AWAY FROM INCOMPATIBLE MATERIALS. AVOID STORAGE NEAR HYDROGEN PEROXIDE. KEEP DUST AWAY FROM IGNITION SOURCES. Other Precautions:PREHEAT METAL WHEN REQUIRED TO EVAPORATE SURFACES MOISTURE PRIOR TO MELTING. ICE/SNOW/GREASE/OIL/MOISTURE CAN CAUSE EXPLOSIONS. REMOVE THESE CONTAMINANTS BEFORE CHARGING INGOT TO MELTING FURNACE. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:USE NIOSH/MSHA APPROVED RESPIRATORS FOR AIRBORNE DUSTS/FUMES Ventilation:LOCAL EXHAUST OR GENERAL TO KEEP AIRBORNE CONCENTRATIONS OF DUST/FUME BELOW PEL/TLV Other Protective Equipment:FACE SHIELDS, BARRIER CREAM Work Hygienic Practices:REMOVE/LAUNDER CONTAMINATED BEFORE REUSE. WASH SKIN BEFORE EATING, DRINKING, USE TOBACCO PRODUCTS OR USING RESTROOMS. Supplemental Safety and Health TAKE A SHOWER & CHANGE CLOTHES AT THE END OF THE SHIFT. ALL PROTECTIVE & CONTAMINATED CLOTHING MUST BE LEFT AT THE PLANT. DON'T USE COMPRESSED AIR FOR BLOWING DUST OFF CLOTHING. CUTTING, WELDING, MECH ANICAL PROCESSING, ETC. MAY PRODUCE DUSTS OR FUMES WHICH PRESENT POTENTIALLY SIGNIFICANT HEALTH HAZARDS. ================== Physical/Chemical Properties ================== Boiling Pt:B.P. Text:1663F/906C Melt/Freeze Pt:M.P/F.P Text:715-718F Spec Gravity:6.6-6.7 Solubility in Water:INSOLUBLE Appearance and Odor:SHINY SILVER-GRAY, ODORLESS W/METALLIC SOLID ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES ACIDS, BASES, OXIDIZING AGENTS, NITRATES, PEROXIDES, SELENIUM, SULFUR, TELLURIUM, WATER, SULFURIC & HYDROCHLORIC ACID Stability Condition to Avoid:IGNITION SOURCES Hazardous Decomposition Products:OXIDE FUMES OF THE COMPONENT METALS, HYDROGEN GAS, HIGHLY TOXIC ARSINE GAS & OTHER FUMES/VAPORS. ==================== Disposal Considerations ==================== Waste Disposal Methods:MOLTEN METAL SPILLS CAN CAUSE CONCRETE TO EXPLODE. SPILLED MOLTEN METAL CAN BE RECLAIMED FOR REUSE. SELL WASTE MATERIAL FOR SCRAP. DISPOSE OF IN ACCORDANCE W/FEDERAL, STATE & LOCAL REGULATIONS.
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:COL-ERASE WHITE BOARD MARKERS, PWR-4M CAGE:07103 CAGE:32988 CAGE:07103 ============= Composition/Information on Ingredients ============= Ingred Name:NON HAZARDOUS INGREDIENTS OSHA PEL:N/K ACGIH TLV:N/K Ingred Name:ETHYL ALCOHOL CAS:64-17-5 RTECS #:KQ6300000 Fraction by Wt: 80% OSHA PEL:1000 PPM ACGIH TLV:1000 PPM ===================== Hazards Identification ===================== LD50 LC50 Mixture:NONE SPECIFIED BY MANUFACTURER. Routes of Entry: Inhalation:YES Skin:NO Ingestion:YES Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:INTOXICATION. Explanation of Carcinogenicity:NOT RELEVANT Effects of Overexposure:DROWSINESS & HEADACHE. Medical Cond Aggravated by Exposure:ALCOHOLISM. ======================= First Aid Measures ======================= First Aid:INHAL: VENITLATION. EYE: WASH WITH WATER FOR AT LEAST 15 MIN. SKIN: WASH WITH SOAP AND WATER. INGEST: IF LARGE QUANTITIES INGESTED, SEE PHYSICIAN. ===================== Fire Fighting Measures ===================== Flash Point Method:OC Flash Point:60F,15.6C Lower Limits:3.3% Upper Limits:19% Extinguishing Media:WATER SPRAY, CO*2, OR CHEMICAL FOAM. Fire Fighting Procedures:WEAR NIOSH/MSHA APPROVED SCBA AND FULL PROTECTIVE EQUIPMENT . Unusual Fire/Explosion Hazard:NONE ================== Accidental Release Measures ================== Spill Release Procedures:FLUSH WITH WATER - AVOID OPEN FLAME. Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER. ======================Handling and Storage ====================== Handling and Storage Precautions:INK IS FLAMMABLE. DO NOT STORE NEAR OPEN FLAME. Other Precautions:NONE. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:NIOSH/MSHA APPROVED RESPIRATOR APPROPRIATE FOR EXPOSURE OF CONCERN . Ventilation:LOCAL: DESIRED. MECHANICAL: DESIRED. Work Hygienic Practices:WASH WITH SOAP AND WATER. Supplemental Safety and Health NONE SPECIFIED BY MANUFACTURER. ================== Physical/Chemical Properties ================== Boiling Pt:B.P. Text:174F,79C Spec Gravity:0.8-0.9(H*2O=1) Solubility in Water:DISPERSABLE Appearance and Odor:MILD ALCOHOL ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES NONE Stability Condition to Avoid:NONE Hazardous Decomposition Products:NONE ==================== Disposal Considerations ==================== Waste Disposal Methods:ACCORDING TO FEDERAL, STATE AND LOCAL REGULATIONS.
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:6604654 CD3-ECD/T4-RD1/T8-FITC Preparer's Name:S HEALY CAGE:FO645 CAGE:FO645 CAGE:6Z677 ============= Composition/Information on Ingredients ============= Ingred Name:SODIUM AZIDE, AZIDE *96-4* CAS:26628-22-8 RTECS #:VY8050000 Other REC Limits:0.1 PPM ACGIH TLV:C 0.29 MG/CUM EPA Rpt Qty:1000 LBS DOT Rpt Qty:1000 LBS ===================== Hazards Identification ===================== Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:INHALATION: NASAL IRRITATION. SKIN: IRRITATION, ABSORPTION, ALLERGIC REACTION. EYES: IRRITATIONS, CONJUNCTIVITIS. INGESTION: BRONCHIAL IRRITATION, RESPIRATORY IRRITATION, RESPIRATORY FAILURE. Explanation of Carcinogenicity:NONE Effects of Overexposure:IRRITATION, HEADACHE, DIZZINESS, FAINTNESS, NAUSEA, LOW BLOOD PRESSURE, BLURRED VISION, SHORTNESS OF BREATH, COLLAPSE, BRONCHITIS, PALPITATION, WEAKNESS & UNSTEADINESS, COMA, CONVULSIONS. ======================= First Aid Measures ======================= First Aid:INHALATION: REMOVE TO FRESH AIR. IF NOT BREATHING, GIVE CPR. IF BREATHING IS DIFFICULT GIVE OXYGEN. SKIN: WASH OFF THOROUGHLY FOR 15 MINS. EYES: RINSE THOROUGHLY W/WATER & GIVE PLENTY OF WATER TO DRIN K. INDUCE VOMITING. OBTAIN MEDICAL ATTENTION IN ALL CASES. ===================== Fire Fighting Measures ===================== Extinguishing Media:DRY CHEMICALS SUCH AS AN SODIUM CARBONATE/SAND. Fire Fighting Procedures:BURNING SODIUM AZIDE WILL EXPLODE IF WATER IS USED AS AN EXTINGUISHING MEDIA. SCBA MUST BE WORN. Unusual Fire/Explosion Hazard:MAY EXPLODE & RELEASE TOXIC FUMES UPON HEATING. DON'T ALLOW TO CONTACT METALS AT HIGH TEMPS. (SUPP) ================== Accidental Release Measures ================== Spill Release Procedures:DILUTE W/RUNNING WATER BEFORE DISCHARGE. DISPOSE OF IAW/FEDERAL, STATE & LOCAL REGULATIONS. ======================Handling and Storage ====================== Handling and Storage Precautions:STORE AWAY FROM METALS & ACIDS. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:NONE REQUIRED Ventilation:GENERAL/LOCAL EXHAUST TO MEET TLV REQUIREMENTS Other Protective Equipment:ADEQUATE LABORATORY ATTIRE Work Hygienic Practices:REMOVE/LAUNDER CONTAMINATED CLOTHING BEFORE REUSE. Supplemental Safety and Health UNUSUAL FIRE CONT'D: FORMS HIGHLY SENSITIVE EXPLOSIVE COMPOUNDS W/HEAVY METALS SUCH AS LEAD, SILVER & COPPER. WHEN HEATED TO 662F IT DECOMPOSES EXOTHERMICALLY, BURNING W/A VERY HOT FLAME & PRODUCING N ITROGEN & MOLTEN SODIUM. ================== Physical/Chemical Properties ================== Melt/Freeze Pt:M.P/F.P Text:527F Spec Gravity:1.85 Solubility in Water:40.16 Appearance and Odor:WHITE-COLORLESS CRYSTALS/POWDER, ODORLESS ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES METALS, ACIDS, ACID CHLORIDES & STRONG OXIDIZING AGENTS Stability Condition to Avoid:HEAT Hazardous Decomposition Products:NITROGEN OXIDES, HYDRAZOIC ACID ==================== Disposal Considerations ==================== Waste Disposal Methods:DISPOSE OF IAW/FEDERAL, STATE & LOCAL REGULATIONS.
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:TROPICAL BLEND ODOR DIGESTANT COUNTERACTANT CAGE:CANBE CAGE:CANBE ============= Composition/Information on Ingredients ============= Ingred Name:ISOPROPYL ALCOHOL; (2-PROPANOL) CAS:67-63-0 RTECS #:NT8050000 Fraction by Wt: 1-5% OSHA PEL:400 PPM;500 STEL ACGIH TLV:400 PPM;500 STEL ===================== Hazards Identification ===================== LD50 LC50 Mixture:NONE SPECIFIED BY MANUFACTURER. Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:ACUTE: MAY CAUSE SKIN/EYE IRRITATION. CHRONIC: NO CHRONIC DATA IS AVAILABLE AT THIS TIME. Explanation of Carcinogenicity:NOT RELEVANT Effects of Overexposure:REDNESS, IRRITATION OF EYES, SKIN OR MUCOUS MEMBRANES. Medical Cond Aggravated by Exposure:MAY AGGRAVATE PRE-EXISTING DERMATITIS OR RESPIRATORY AILMENTS. ======================= First Aid Measures ======================= First Aid:GOOD HYGIENE PRACTICES APPLY. EYE: FLUSH WITH WATER FOR AT LEAST 15 MINUTES. GET MED ATTN. INGEST: GIVE 1-2 GLASSES OF WATER AND GET IMMED MED ATTN. INHAL: MOVE TO FRESH AIR. SKIN: WASH WITH SOAP AND WATER. ===================== Fire Fighting Measures ===================== Flash Point:NONE Extinguishing Media:WATER SPRAY, FOAM, CO*2. Fire Fighting Procedures:WEAR NIOSH/MSHA APPROVED SCBA AND FULL PROTECTIVE EQUIPMENT . Unusual Fire/Explosion Hazard:NONE. ================== Accidental Release Measures ================== Spill Release Procedures:CONTAIN SPILL AND COLLECT IN APPROVED CONTAINER. FLUSH RESIDUE TO NEAREST DRAIN. Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER. ======================Handling and Storage ====================== Handling and Storage Precautions:KEEP CONTAINER CLOSED WHEN NOT IN USE. STORE AT TEMPS BETWEEN 40-155F. Other Precautions:KEEP OUT OF REACH OF CHILDREN. AVOID CONT W/SKIN/EYES. KEEP AWAY FROM HEAT, SPARKS/OPEN FLAMES. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:NOT REQUIRED UNDER NORMAL CONDITIONS OF USE. USE NIOSH/MSHA APPROVED RESPIRATOR APPROPRIATE FOR EXPOSURE OF CONCERN . Ventilation:NO. Other Protective Equipment:NOT REQUIRED. Work Hygienic Practices:GOOD HOUSEKEEPING PRACTICES APPLY. Supplemental Safety and Health NONE SPECIFIED BY MANUFACTURER. ================== Physical/Chemical Properties ================== Boiling Pt:B.P. Text:212F,100C Spec Gravity:1(H*2O=1) Evaporation Rate & Reference:1(H*2O=1) Solubility in Water:COMPLETE Appearance and Odor:LT PURPLE COLOR/VANILLA FRAGRANCE Percent Volatiles by Volume:>95 ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES DO NOT MIX WITH OTHER CHEMICALS. Stability Condition to Avoid:EXCESSIVE HOT/COLD TEMPERATURES. Hazardous Decomposition Products:PRODUCTS OF COMBUSTION ARE TOXIC. ==================== Disposal Considerations ==================== Waste Disposal Methods:MATERIAL IS CONSIDERED NON-HAZARDOUS. MAY BE DISPOSED OF IN SANITARY SEWER OR SEPTIC SYSTEM.
1
eyes_protection_mandatory
======================================================= Product ID: TANDEM-E HCG Kit Part: Y Cage: FO596 Box: 269006 ======================================================= Preparer Co. when other than Responsible Party Co. ======================================================= Cage: FO596 Assigned Ind: Y Box: 269006 ======================================================= Contractor Summary ======================================================= Cage: 63493 Box: 269006 Cage: FO596 Box: 269006 ======================================================= Ingredients ======================================================= Cas: 26628-22-8 RTECS #: VY8050000 % Wt: 0.1 Other REC Limits: 0.1 PPM ACGIH TLV: C 0.29 MG/CUM EPA Rpt Qty: 1000 LBS DOT Rpt Qty: 1000 LBS ======================================================= Health Hazards Data ======================================================= Route Of Entry Inds - Inhalation: NO Skin: NO Ingestion: NO Carcinogenicity Inds - NTP: NO IARC: NO OSHA: NO Explanation Of Carcinogenicity: NONE First Aid: EYES/SKIN: IMMEDIATELY FLUSH W/COPIOUS AMOUNTS OF WATER. OBTAIN MEDICAL ATTENTION IN ALL CASES. ======================================================= Handling and Disposal ======================================================= Spill Release Procedures: FLUSH DRAINS W/COPIOUS AMOUNTS OF WATER TO PREVENT AZIDE ACCUMULATION. Waste Disposal Methods: DISPOSE OF IN ACCORDANCE W/LOCAL, STATE & FEDERAL REGULATIONS. Handling And Storage Precautions: STORE IN A COOL, DRY PLACE. REFRIGERATE, UNLESS OTHERWISE SPECIFIED IN KIT INSERT. Other Precautions: AZIDE REACTS W/MANY HEAVY METALS SUCH AS LEAD, COPPER, MERCURY, SILVER & GOLD TO FORM EXPLOSIVE COMPOUNDS. ======================================================= Fire and Explosion Hazard Information ======================================================= Extinguishing Media: DRY CHEMICAL Unusual Fire/Explosion Hazard: CONTACT W/COPPER/LEAD DRAIN PIPES MAY RESULT IN THE FORMATION OF POTENTIALLY EXPLOSIVE AZIDE DEPOSITS. ======================================================= Control Measures ======================================================= Other Protective Equipment: LAB COAT Work Hygienic Practices: REMOVE/LAUNDER CONTAMINATED CLOTHING BEFORE REUSE. ======================================================= Physical/Chemical Properties ======================================================= Spec Gravity: 1.85 ======================================================= Reactivity Data ======================================================= Stability Indicator: YES Materials To Avoid: ACIDS, HEAVY METALS; LEAD, COPPER, BROMINE, CARBON DISULFIDE, CHROMYCHLORIDE, DIBROMO MALONITRILE, DIMETHYL SULFATE Hazardous Decomposition Products: SODIUM & OXIDES OF NITROGEN Hazardous Polymerization Indicator: NO ======================================================= Toxicological Information ======================================================= ======================================================= Ecological Information ======================================================= ======================================================= ======================================================= ======================================================= Regulatory Information ======================================================= ======================================================= Other Information ======================================================= ======================================================= HAZCOM Label ======================================================= Product ID: TANDEM-E HCG Cage: FO596 Assigned IND: Y Company Name: HYBRITECH INCORPORATED Street: 11095 TORREYANA ROAD PO Box: 269006 Zipcode: 92126 Label Required IND: Y Date Of Label Review: 12/16/1998 Status Code: C Label Date: 12/16/1998 Origination Code: G Hazard And Precautions: N/K N/K =======================================================
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:03028, MIR-A-SAF Preparer's Name:W. J. CORBETT CAGE:DUBOI CAGE:72008 CAGE:DUBOI ============= Composition/Information on Ingredients ============= Ingred Name:POTASSIUM HYDROXIDE (SARA III) CAS:1310-58-3 RTECS #:TT2100000 Fraction by Wt: <5% OSHA PEL:2 MG/M3, C ACGIH TLV:2 MG/M3, C EPA Rpt Qty:1000 LBS DOT Rpt Qty:1000 LBS ===================== Hazards Identification ===================== LD50 LC50 Mixture:NONE SPECIFIED BY MANUFACTURER. Routes of Entry: Inhalation:YES Skin:NO Ingestion:YES Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:ACUTE: CORROSIVE TO SKIN AND EYES. CHRONIC: SAME AS ACUTE. Explanation of Carcinogenicity:NOT RELEVANT Effects of Overexposure:SEE HEALTH HAZARDS. Medical Cond Aggravated by Exposure:SENSITIVE SKIN. ======================= First Aid Measures ======================= First Aid:INHAL: NOT APPLICABLE IN NORMAL OPERATION. REMOVE TO FRESH AIR. SUPPORT BRTHG (GIVE O2/ARTF RESP) . EYES: FLUSH THORO WITH FRESH WATER FOR A MINIMUM OF 15 MINUTES, GET MEDICAL ATTN. SKIN: FLUSH W/FRESH WATER, WASH W/SOAP & WATER. REMOVE CONTAMINATED CLOTHES AND SHOES. INGEST: GIVE MILK, WATER OR EGG WHITES. DO NOT INDUCE VOMITING, GET MEDICAL ATTENTION. ===================== Fire Fighting Measures ===================== Flash Point:NONE Lower Limits:NONE Upper Limits:NONE Extinguishing Media:MEDIA SUITABLE FOR SURROUNDING FIRE . Fire Fighting Procedures:WEAR NIOSH/MSHA APPROVED SCBA & FULL PROTECTIVE EQUIPMENT . Unusual Fire/Explosion Hazard:NONE. DOES NOT BURN. ================== Accidental Release Measures ================== Spill Release Procedures:FLUSH SMALL AMOUNTS TO DRAIN; COLLECT AND RETURN LARGE AMOUNTS TO CONTAINER. Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER. ======================Handling and Storage ====================== Handling and Storage Precautions:KEEP CONTAINER CLOSED. IF FROZEN, THAW AND MIX TO MAKE USABLE. DO NOT PRESSURE CONTAINER TO EMPTY. Other Precautions:VOLUNTARY; CAUTIONS ON CONTAINER LABEL. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:NIOSH/MSHA APPROVED RESPIRATOR APPROPRIATE FOR EXPOSURE OF CONCERN . Ventilation:LOCAL VENTILATION. Other Protective Equipment:EMERGENCY EYE WASH AND DELUGE SHOWER . Work Hygienic Practices:NONE SPECIFIED BY MANUFACTURER. Supplemental Safety and Health NONE SPECIFIED BY MANUFACTURER. ================== Physical/Chemical Properties ================== HCC:C2 Boiling Pt:B.P. Text:215F,102C Vapor Pres:17.5 @ 20C Spec Gravity:1.243 Evaporation Rate & Reference:>1 (N-BUTYL ACETATE=1) Solubility in Water:100% Appearance and Odor:CLEAR LIQUID; NO ODOR. Percent Volatiles by Volume:70 ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES INCOMPATIBLE WITH CONCENTRATED MINERAL ACIDS. Stability Condition to Avoid:NONE SPECIFIED BY MANUFACTURER. Hazardous Decomposition Products:CO WITH INCOMPLETE COMBUSTION. ==================== Disposal Considerations ==================== Waste Disposal Methods:PH ADJUSTMENT; CNTNS PHOSPHATES. USE UNTIL <1" REMAINS IN CONTR. EMPTY CONTR, TRIPLE RINSE W/WATER, DISPOSE TO INDUSTRIAL/ SANITARY SEWER. REMOVE/DEFACE LBL BEFORE SELLING CONTR OR DISPOSAL. DISPOSAL MUST BE I/A/W FEDERAL, STATE, & LOCAL REGS .
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:ACTIVATOR A Kit Part:Y CAGE:0JVX9 CAGE:98911 CAGE:0JVX9 ============= Composition/Information on Ingredients ============= Ingred Name:DIETHYLENETRIAMINE CAS:111-40-0 RTECS #:IE1225000 Fraction by Wt: 100% Other REC Limits:NONE RECOMMENDED OSHA PEL:1 PPM ACGIH TLV:S, 1 PPM; 9596 ===================== Hazards Identification ===================== LD50 LC50 Mixture:NONE SPECIFIED BY MANUFACTURER. Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:CORROSIVE! CONTACT MAY CAUSE SEVERE IRRITATION/BURNS TO SKIN & EYES; MAY CAUSE HYPERSENSITIVITY IN SOME INDIVIDUALS. INHALATION MAY CAUSE IRRITATION OF RESPIRATORY SYSTEM; MAY CAUSE HYPERSENSITIVITY I N SOME. INGESTION MAY CAUSE SEVERE IRRITATION/BURNS TO MOUTH/THROAT/GI TRACT. MAY ALSO AFFECT LIVER, KIDNEY, IMMUNE SYS. Explanation of Carcinogenicity:NO INGREDIENT OF A CONCENTRATION OF 0.1% OR GREATER IS LISTED AS A CARCINOGEN OR SUSPECTED CARCINOGEN. Effects of Overexposure:EYES-SEVERE IRRITATION, BURNS. SKIN-BURNS, TISSUE DAMAGE, HYPERSENSITIVITY. INHALED-IRRITATION OF UPPER RESPIRATORY SYSTE, COUGHING, SHORTNESS OF BREATH, TIGHTNESS IN CHEST. INGESTED-SEVERE BURNS TO M OUTH/THROAT/DIGESTIVE TRACT, NAUSEA, VOMITING, GI TRACT UPSET. Medical Cond Aggravated by Exposure:PRE-EXISTING LIVER, KIDNEY, RESPIRATORY, IMMUNE SYSTEM DISORDERS. ======================= First Aid Measures ======================= First Aid:IN ALL CASES GET MEDICAL ATTENTION. EYES-FLUSH WITH WATER FOR 15 MINUTES. SKIN-REMOVE CONTAMINATED CLOTHES. WASH WITH MILD SOAP & WATER. INHALED-REMOVE TO FRESH AIR. ADMINISTER OXYGEN OR ARTIFICIAL RE SPIRATION AS NEEDED. INGESTED-CONTACT POISON CONTROL CENTER AND OBTAIN IMMEDIATE MEDICAL ATTENTION. DO NOT INDUCE VOMITING! IF CONSCIOUS, GIVE 2 CUPS WATER. NO CARBONATED BEVERAGES! ===================== Fire Fighting Measures ===================== Flash Point Method:SCC Flash Point:>200F,>93C Extinguishing Media:SMALL FIRES: HALON, WATER FOG, CARBON DIOXIDE, DRY CHEMICAL, FOAM. LARGE FIRES: WATER SPRAY/FOG, ALCOHOL FOAM. Fire Fighting Procedures:WEAR SELF-CONTAINED BREATHING APPARATUS AND FULL FIRE FIGHTER'S PROTECTIVE GEAR. WATER MAY CAUSE FROTHING. Unusual Fire/Explosion Hazard:NONE SPECIFIED BY MANUFACTURER. ================== Accidental Release Measures ================== Spill Release Procedures:VENTILATE AREA. EVACUATE IF EXPOSURE EXCEEDS TLV. CONTAIN SPILL. IF LARGE AMOUNT SPILLED, USE PUMP OR VACUUM TO PICK-UP. OTHERWISE, ABSORB WITH INERT MATERIAL. SCOOP UP & PLACE IN A CONTAINER FOR LATE R DISPSOAL. REPORT SPILL IF REQUIRED BYLAW. Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER. ======================Handling and Storage ====================== Handling and Storage Precautions:STORE IN A COOL, DRY, WELL-VENTILATED PLACE. DO NOT STORE ABOVE 86F. AVOID CONTACT WITH EYES, SKIN, CLOTHES. USE APPROPRIATE VENTILATION/RESPIRATORS. Other Precautions:NONE SPECIFIED BY MANUFACTURER. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:IF ENGINEERING CONTROLS FAIL OR NON-ROUTINE USE OR AN EMERGENCY OCCURS; WEAR AN MSHA/NIOSH APPROVED RESPIRATOR WITH ORGANIC VAPOR CARTRIDGE OR AN AIR-SUPPLIED RESPIRATOR OR SCBA, AS REQUIRED. USE IAW 29 CFR 1910.134. Ventilation:USE ADEQUATE MECHANICAL VENTILATION OR LOCAL EXHAUST TO MAINTAIN EXPOSURE BELOW TLV(S). Other Protective Equipment:RUBBER APRON. EYE WASH STATION & SAFETY SHOWER. DO NOT WEAR CONTACT LENSES. Work Hygienic Practices:WASH HANDS AFTER HANDLING AND BEFORE EATING, DRINKING, OR SMOKING. LAUNDER CONTAMINATED CLOTHES BEFORE REUSE. Supplemental Safety and Health KEY1=C4. PART B OF 81 PART KIT. ONLY PNI A, B & C ARE HAZARDOUS-AS BEST AS DLA-HMIS CAN FIGURE OUT. ================== Physical/Chemical Properties ================== HCC:B2 Boiling Pt:=203.3C, 398.F B.P. Text:398F,203C Vapor Pres:1 Vapor Density:3.56 Spec Gravity:0.95 Solubility in Water:COMPLETE Appearance and Odor:AMBER, VISCOUS LIQUID; AMINE ODOR. Percent Volatiles by Volume:1.0 ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES STRONG OXIDIZING AGENTS, ACIDS, WATER, CHEMICALLY ACTIVE METAS; EG NICKEL, COBALT, COPPER, IRON. Stability Condition to Avoid:AVOID CONTACT WITH INCOMPATIBLE MATERIALS. Hazardous Decomposition Products:AMINES, OXIDES OF NITROGEN, SMOKE, SOOT, CARBON DIOXIDE, CARBON MONOXIDE. Conditions to Avoid Polymerization:WILL NOT OCCUR. ==================== Disposal Considerations ==================== Waste Disposal Methods:DISPOSE OF IN ACCORDANCE WITH LOCAL, STATE AND FEDERAL ENVIRONMENTAL REGULATIONS.
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:K-52 CAGE:9U500 CAGE:9U500 CAGE:63728 ============= Composition/Information on Ingredients ============= Ingred Name:ASBESTOS, CHRYSOTILE CAS:12001-29-5 RTECS #:CI6478500 Fraction by Wt: >65% Other REC Limits:NONE RECOMMENDED OSHA PEL:0.2 FIBERS/CC ACGIH TLV:2 FIBERS/CC; A1;9293 Ingred Name:BARIUM SULFATE CAS:7727-43-7 RTECS #:CR0600000 Other REC Limits:NONE RECOMMENDED OSHA PEL:15 MG/M3 TDUST ACGIH TLV:10 MG/M3 TDUST; 9293 Ingred Name:CARBON BLACK CAS:1333-86-4 RTECS #:FF5800000 Other REC Limits:NONE RECOMMENDED OSHA PEL:3.5 MG/M3 ACGIH TLV:3.5 MG/M3; 9293 Ingred Name:KAOLIN CAS:1332-58-7 RTECS #:GF1670500 Other REC Limits:NONE RECOMMENDED OSHA PEL:15 MG/M3 TDUST ACGIH TLV:2 MG/M3 TDUST; 9293 Ingred Name:NATURAL RUBBER CAS:9003-31-0 Other REC Limits:NONE RECOMMENDED Ingred Name:NEOPRENE RUBBER Other REC Limits:NONE RECOMMENDED ===================== Hazards Identification ===================== Routes of Entry: Inhalation:YES Skin:NO Ingestion:NO Reports of Carcinogenicity:NTP:YES IARC:YES OSHA:YES Health Hazards Acute and Chronic:ACUTE:MINOR EYS/SKIN IRRITATION. INGESTION- IRRITATION OF GI TRACT. INHALATION-IRRITATION OF RESPIRATORY TRACT. CHRONIC: ASBESTOSIS, LUNG CANCER, & MESOTHELIOMA, ALL OF WHICH ARE DISABLING AND FATAL D ISEASES OF THE LUNG. INHALATION AND INGESTION OF ASBESTOS FIBERS MAY CAUSE CANCER OF THE BOWEL. Explanation of Carcinogenicity:ASBESTOS IS A KNOWN HUMAN CARCINOGEN. Effects of Overexposure:INHALATION: FATIGUE AND SHORTNESS OF BREATH THAT GETS WORSE WITH TIME AND EVENTUALLY BECOMES DISABLING. EYES: IRRITATION. SKIN: IRRITATION. INGESTION: MILD STOMACH DISTRESS. DIARRHEA, VOMITING, AND NA USEA. Medical Cond Aggravated by Exposure:ASTHMA, EMPHYSEMA, AND TUBERCULOSIS ARE ALL GENERALLY AGGRAVATED BY EXPOSURE TO ASBESTOS FIBERS. ======================= First Aid Measures ======================= First Aid:INHALATION: REMOVE TO FRESH AIR. SEE DOCTOR. EYES: RINSE THOROUGHLY WITH WATER FOR 15 MINUTES. SEE DOCTOR. SKIN: WASH THOROUGHLY WITH SOAP AND WATER. IF IRRITATION PERSISTS, SEE DOCTOR. INGESTION: DIL UTE WITH WATER. DO NOT INDUCE VOMITING.SEE DOCTOR. ===================== Fire Fighting Measures ===================== Flash Point:NOT REQUIRED Extinguishing Media:USE WATER FOG, CARBON DIOXIDE, FOAM, OR DRY CHEMICAL. Fire Fighting Procedures:WEAR FIRE FIGHTING PROTECTIVE EQUIPMENT AND A FULL FACED SELF CONTAINED BREATHING APPARATUS. Unusual Fire/Explosion Hazard:COMBUSTION OR HEAT OF FIRE MAY PRODUCE HAZARDOUS DECOMPOSITION PRODUCTS AND VAPORS. ================== Accidental Release Measures ================== Spill Release Procedures:VACUUM THE MATERIAL WITH A HEPA FILTERED VACUUM. THE EQUIPMENT SHALL BE USED & EMPTIED SO AS TO MINIMIZE THE RE-ENTRY OF ASBESTOS INTO THE WORKPLACE. OTHERWISE, WET THE MATERIAL WITH WATER & SURFACTAN T AND THEN SHOVEL OR MOP UP CONTAMINATION. ======================Handling and Storage ====================== Handling and Storage Precautions:GASKET IS NONFRIABLE & WILL NOT SHED FIBERS IN NORMAL USE AND STORAGE. USED GASKETS SHALL BE WETTED BEFORE, DURING & AFTER DISASSEMBLY FROM AN ENGINE. Other Precautions:IF IT IS NECESSARY TO CUT OR IMPACT THE GASKET WHILE INSTALLING IT, WEAR A RESPIRATOR AND PROTECTIVE CLOTHING. USED GASKETS SHALL BE IDENTIFIED AND DISPOSED OF IN ACCORDANCE WITH ALL LOCAL, STATE AND FEDERAL REGULATIONS. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:WEAR A NIOSH/MSHA APPROVED HEPA RESPIRATOR IF REQUIRED. WEAR SELF-CONTAINED BREATHING APPARATUS IF REQUIRED FOR HIGH LEVELS OF CONTAMINATES. Ventilation:LOCAL EXHAUST SUFFICIENT TO ENTRAIN ALL PARTICULATE EMISSIONS. HEPA FILTER REQUIRED. NO LEAKS ON PRESSURE SIDE OF FAN. Other Protective Equipment:USE COVERALLS OR DISPOSABLE CLOTHING. Work Hygienic Practices:WET WORK TO THE DEGREE POSSIBLE. WASH HANDS AFTER HANDLING GASKET. LAUNDER CONTAMINATED CLOTHING BEFORE REUSE. Supplemental Safety and Health ================== Physical/Chemical Properties ================== HCC:T6 Spec Gravity:1.75 Solubility in Water:INSOLUBLE Appearance and Odor:COMPOSITE MATERIAL, BLACK SHEETS Percent Volatiles by Volume:0 ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES STRONG OXIDIZING AGENTS, STRONG MINERAL ACIDS, AND STRONG ALKALIS Stability Condition to Avoid:ACCUMULATIONS OF DUST Hazardous Decomposition Products:ASBESTOS DUST ==================== Disposal Considerations ==================== Waste Disposal Methods:WET THE MATERIAL WITH WATER AND SURFACTANT. PLACE IN 6 MIL THICK POLYETHYLENE PLASTIC BAG. PLACE THESE BAGS INTO ANOTHER POLY BAG OR A SAFE PLACE UNTIL IT CAN BE SHIPPED TO AN APPROVED DISPOSAL SITE. IDENTIFY WITH ASBESTOS CANCER WARNING LABEL.
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:STYRENE Preparer's Name:C. A. EISENHARD CAGE:0AN91 CAGE:60777 CAGE:0AN91 ============= Composition/Information on Ingredients ============= Ingred Name:STYRENE, MONOMER (SARA III) CAS:100-42-5 RTECS #:WL3675000 Fraction by Wt: 99% % Other REC Limits:NONE SPECIFIED OSHA PEL:100 PPM ACGIH TLV:S,50PPM/100STEL;9293 EPA Rpt Qty:1000 LBS DOT Rpt Qty:1000 LBS ===================== Hazards Identification ===================== LD50 LC50 Mixture:ORAL LD50 (RAT) IS 316 MG/KG Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:VAPORS AND MIST MAY IRRITATE THE NOSE & THROAT. INHALATION OF VERY HIGH CONCENTRATIONS OR PROLONGED EXPOSURE MAY CAUSE UNCONSCIOUSNESS. EYE-IRRITATION. LIQUID & MIST MAY DAMAGE THE EYES. Explanation of Carcinogenicity:NOT LISTED BY THESE ORGANIZATIONS AS A CARCINOGEN. IARC HAS PROPOSED TO RECLASSIFY STYRENE AS "POSSIBLY" CARCINOGENIC. Effects of Overexposure:INHALATION OF HIGHER CONCENTRATIONS MAY CAUSE MAY CAUSE DRUNKENESS, ANESTHETIC OR NARCOTIC EFFECTS WITH NAUSEA, HEADACHE, VOMITING AND COMA. SKIN: MAY DRY THE SKIN, DERMATITIS, CRACKING, BLISTERING, B URN. Medical Cond Aggravated by Exposure:NONE REPORTED. ======================= First Aid Measures ======================= First Aid:INHALED: REMOVE TO FRESH AIR. GIVE CPR IF NOT BREATHING. GET IMMEDIATE MEDICAL ATTENTION. EYE: IMMEDIATELY FLUSH EYES WITH LOTS OF WATER FOR 15 MINUTES. GET IMMEDIATE MEDICAL ATTENTION. SKIN: FLUSH SK IN WITH LOTS OF WATER FOR 15 MINUTES. REMOVE CONTAMINATED CLOTHING & SHOES. GET IMMEDIATE MEDICAL ATTENTION. INGESTION: DO NOT INDUCE VOMITING. GET IMMEDIATE MEDICAL ATTENTION. ===================== Fire Fighting Measures ===================== Flash Point Method:TCC Flash Point:88.0F,31.1C Lower Limits:1.1 Upper Limits:6.1 Extinguishing Media:USE WATER SPRAY, DRY CHEMICAL OR CARBON DIOXIDE. DO NOT USE A DIRECT WATER STREAM. Fire Fighting Procedures:FIRE FIGHTERS SHOULD USE NIOSH APPROVED SCBA & FULL PROTECTIVE EQUIPMENT WHEN FIGHTING CHEMICAL FIRE. USE WATER SPRAY TO COOL NEARBY CONTAINERS EXPOSED TO FIRE. Unusual Fire/Explosion Hazard:STYRENE VAPORS ARE UNINHIBITED AND MAY FORM POLYMERS IN VENTS OR FLAME ARRESTERS OR STORAGE TANKS RESULTING IN STOPPAGE OF VENTS. ================== Accidental Release Measures ================== Spill Release Procedures:WEAR PROTECTIVE EQUIPMENT (RUBBER BOOTS, PRESSURE DEMAND MODE OR A SUPPLIED AIR RESPIRATOR. EXTINGUISH ALL IGNITION SOURCES. MOP OR WIPE UP & DISPOSE OF IN D.O.T CONTAINER. Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER. ======================Handling and Storage ====================== Handling and Storage Precautions:KEEP AWAY FROM HEAT, SPARKS, AND FLAMES. STORE IN WELL VENTILATED PLACE AWAY FROM INCOMPATIBLE MATERIALS. Other Precautions:VENT CONTAINER MORE OFTEN IN WARM WEATHER TO RELIEVE PRESSURE. ELECTRICALLY GROUND ALL EQUIPMENT WHEN HANDLING PRODUCT AND USE ONLY NON-SPARKING TOOLS. DO NOT USE PRESSURE TO EMPTY CONTAINER. DO NOT C UT, GRIND, OR WELD IN AREA. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:WEAR A NIOSH-APPROVED RESPIRATOR APPROPRIATE FOR THE VAPOR OR MIST CONCENTRATION AT THE POINT OF USE. FOR EXAMPLE A SUPPLIED AIR RESPIRATOR. Ventilation:LOCAL MECHANICAL EXHAUST VENTILATION. Other Protective Equipment:RUBBER APRON. EYE WASH STATION & SAFETY SHOWER. Work Hygienic Practices:WASH THOROUGHLY AFTER HANDLING. DO NOT GET IN EYES, ON SKIN OR ON CLOTHING. LAUNDER CONTAMINATED CLOTHING BEFORE REUSE. Supplemental Safety and Health "EMPTY" CONTAINERS WILL RETAIN PRODUCT RESIDUE AND VAPORS. ALWAYS OBEY HAZARD WARNINGS AND HANDLE EMPTY CONTAINERS AS IF THEY WERE FULL. ================== Physical/Chemical Properties ================== HCC:F3 Boiling Pt:B.P. Text:293F,145C Vapor Pres:4.5 Vapor Density:3.6 Spec Gravity:0.90 Solubility in Water:NIL Appearance and Odor:CLEAR, COLORLESS LIQUID, SWEET ODOR ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES ACIDS, OXIDIZING MATERIALS, ALKALIS, METALLIC HALIDES AND PEROXIDES. Stability Condition to Avoid:MAINTAIN INHIBITOR LEVEL AND KEEP BELOW 90 F/32 C HEAT. Hazardous Decomposition Products:MAY LIBERATE CARBON MONOXIDE OR CARBON DIOXIDE. Conditions to Avoid Polymerization:HEAT, CONTACT WITH METAL HALIDES OR PEROXIDES OR OXYGEN ALSO CONTRIBUTE TO POLYMERIZATION. ==================== Disposal Considerations ==================== Waste Disposal Methods:CONSULT APPROPIATE FEDERAL, STATE, AND LOCAL REGULATORY AGENCIES FOR PROPER DISPOSAL INFORMATION. KEEP OUT OF SEWERS, STORM DRAINS, SURFACE WATERS AND SOIL.
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:DYE,SOLVENT GREEN 3 CAGE:4A611 CAGE:4A611 ============= Composition/Information on Ingredients ============= Ingred Name:ANTHRAQUINONE,BIS(1-4-P-TOLYAMINO) CAS:128-80-3 RTECS #:CB5775000 ===================== Hazards Identification ===================== Effects of Overexposure:NONE EXPECTED ======================= First Aid Measures ======================= First Aid:NONE REQUIRED;ORDINARY MEASURES OF PERSONAL HYGIENE SHOULD BE ADEQUATE,E.G.WASH CONTAMINATED BOLY,EYES WELL W/WATER. ===================== Fire Fighting Measures ===================== Extinguishing Media:CO*2,DRY CHEM.OR WATER. Fire Fighting Procedures:DO NOT USE HIGH PRESS.H*2O STREAM.AIR BORNE DUST MAKE EXPLOS Unusual Fire/Explosion Hazard:DUST MAY BE EXPLOSIVE IF MIXED W/AIR IN CRITICAL PROPORTIONS & IN PRESENCE OF SOURCE OF IGNITION. ================== Accidental Release Measures ================== Spill Release Procedures:SWEEP UP & PLACE IN A WASTE DISPOSAL CONTAINER ======================Handling and Storage ====================== Handling and Storage Precautions:VENTILATION RECOMMENDED FOR POTENTIALLY DUSTY TRANSFER OPERATIONS. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:DISPOSABLE DUST MASK RECOMMENDED Ventilation:LOCAL EXHAUST RECOMMENDED FOR POTENTIALLY DUST TRANSFER OPN Supplemental Safety and Health ================== Physical/Chemical Properties ================== HCC:N1 Solubility in Water:NEGLIGIBLE Appearance and Odor:BLUISH BLACK POWDER;SLIGHT ODOR. Percent Volatiles by Volume:0.0. ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES NO SPECIFIC INCOMPATABILITY Stability Condition to Avoid:NONE Hazardous Decomposition Products:NONE ==================== Disposal Considerations ==================== Waste Disposal Methods:DISPOSAL MUST BE MAKE IN ACCORDANCE W/FED.,STATE & LOCAL REGULATIONS.
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:ZP-9E ZYGLO DEVELOPER (NSN CANCELLED) Preparer's Name:BRUCE C.GRAHAM CAGE:37676 CAGE:37676 ============= Composition/Information on Ingredients ============= Ingred Name:METHYL CHLOROFORM (1,1,1-TRICHLOROEHANE) (SARA III) CAS:71-55-6 RTECS #:KJ2975000 Fraction by Wt: 90.0% OSHA PEL:350 PPM/450 STEL ACGIH TLV:350 PPM/450STEL;9192 EPA Rpt Qty:1000 LBS DOT Rpt Qty:1000 LBS Ozone Depleting Chemical:1 Ingred Name:PER MFR,CONTAINS NO OTHER INGREDIENT SUSPECTED OF BEING HAZARDOUS. RTECS #:9999999ZZ ===================== Hazards Identification ===================== Routes of Entry: Inhalation:YES Skin:NO Ingestion:YES Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:IRRITATES EYES BY SOLVENT ACTION;CAUSES NAUSEA,DROWSINESS IF INHALED MORE THAN TLV LIMITS. Explanation of Carcinogenicity:1,1,1-TRICHLOROETHANE IS CURRENTLY UNDER TEST TO DETERMINE THE POSSIBLE CARCINOGENITY. Effects of Overexposure:INHALATION:CAUSES DIZZINESS,DROWSINESS,NAUSEA.CAUSES UNCONSCIOUSNESS AT HIGH EXPOSURE; SKIN:NOT ABSORBED THROUGH SKIN IN SIGNIFICANT AMOUNTS.HOWEVER,IRRITATES BY DISSOLVING SKIN OILS; EYES:IRRITATING DUE TO STRONG SOLVENT ACTION; INGESTION:LOW SINGLE DOSE TOXICITY IN TEST ANIMALS. Medical Cond Aggravated by Exposure:NONE KNOWN TO MANUFACTURER. ======================= First Aid Measures ======================= First Aid:INHALATION:REMOVE TO FRESH AIR.IF NOT BREATHING,GIVE CPR.IF BREATHING IS DIFFICULT,GIVE OXYGEN; SKIN:WASH OFF IN FLOWING WATER OR SHOWER.RMV CONTAMINATED CLOTHING AND WASH BEFORE RE-USE.USE SOOTHING L OTION; EYES:FLUSH EYES WITH A STEADY,GENTLE FLOW OF WATER.GET MEDICAL ASST; INGESTION:DO NOT INDUCE VOMITING.IF VOMIT IS INHALED,IT MAY CAUSE ASPHYXIATION.GET MED ATTN IMMEDIATELY;IN EMERGENCY CALL MD ===================== Fire Fighting Measures ===================== Flash Point:NONE Extinguishing Media:CARBON DIOXIDE,FOAM Fire Fighting Procedures:KEEP CONTAINERS COOL WITH WATER SPRAY. Unusual Fire/Explosion Hazard:WHEN INVOLVE IN COMBUSTION,MAY EMIT TOXIC GASES AT OR ABOVE DECOMPOSITION TEMPERATURE. ================== Accidental Release Measures ================== Spill Release Procedures:SM QTY(LESS THAN QUART):WIPE UP W/RAGS BUT DO NOT BREATHE VAPORS.PLACE RAGS IN CLOSED DRUM;LG QTY(MORE THAN QUART):EVACUATE UNPROTECTED PERSONS.ELIMINATE IGNITION SOURCES.WEAR PERSONAL SAFETY EQUIP.DI KE AREA.ABSORB W/ABSORBENT.PLACE WASTE IN COVRD DR ======================Handling and Storage ====================== Handling and Storage Precautions:STORE AWAY FROM HEAT SOURCES TO MINIMIZE THE DANGER FROM EXPOSURE TO FIRES.STORE IN DRY,COOL,WELL VENTILATED AREA. Other Precautions:DO NOT USE AROUND FLAMES/RED HOT SURFACES.DO NOT HEAT ABOVE 130F.AVOID FREQUENT/PROLONGED EXPOSURE TO SKIN.AVOID BREATHING VAPORS. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:WEAR A RESPIRATOR WITH CHEMICAL CARTRIDGE IN POORLY VENTILATED AREAS.IN CONFINED,UNVENTILATED SPACES,WEAR FULL MASK WITH AIR SUPPLY. Ventilation:GENERAL VENTILATION TO KEEP BELOW TLV LIMITS. Work Hygienic Practices:WASH HANDS WITH SOAP/WATER AFTER HANDLING/USE. Supplemental Safety and Health ITEM IS TYPE II,FORM D OF MIL-I-25135D;THE NSN WAS GROUP III UNDER MIL-I-25135C; THE MFR MAY HAVE SUPPLIED ONE OF THE FOLLOWING DEVELOPERS: SKD-NF/ZP-9B,SKD-S,ZP-9E,OR ZP-9F; SKD-S & ZP-9F ARE FLAMMAB LE DEVELOPER,OTHERS NON-FLAMMABLE. NSN HAS BEEN CANCELLED AS DUPLICATE OF 6850-01-264-8680. THIS ENTRY IS OF:ZP-9F. ================== Physical/Chemical Properties ================== HCC:T4 Boiling Pt:B.P. Text:162F/72.2C Vapor Pres:230MM@100F Vapor Density:4.0 Spec Gravity:1.3 Evaporation Rate & Reference:0.7 (ETHER=1) Solubility in Water:PARTIAL Appearance and Odor:CLOUDY,COLORLESS LIQUID Percent Volatiles by Volume:94 ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES ALKALI METALS Stability Condition to Avoid:HEAT,HIGH TEMPERATURES Hazardous Decomposition Products:EMITS OXIDES OF CARBON;PHOSGENE & HYDROCHLORIC ACID ==================== Disposal Considerations ==================== Waste Disposal Methods:DISPOSE OF AS EPA HAZARDOUS WASTE #F002;LIQUID MAY BE SENT TO SOLVENT RECLAIMER.DISPOSE OF IN FULL COMPLIANCE OF FEDERAL,STATE,AND LOCAL REGULATORY STATUES.
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:AMMONIUM HYDROXIDE, 9721 CAGE:DO803 CAGE:DO803 CAGE:70829 ============= Composition/Information on Ingredients ============= Ingred Name:AMMONIUM HYDROXIDE (CERCLA). LD50:(ORAL,RAT)350 MG/KG CAS:1336-21-6 RTECS #:BQ9625000 Fraction by Wt: 20-30% OSHA PEL:35 PPM (MFR) ACGIH TLV:25 PPM (MFR) EPA Rpt Qty:1000 LBS DOT Rpt Qty:1000 LBS Ingred Name:WATER CAS:7732-18-5 RTECS #:ZC0110000 Fraction by Wt: 70-80% OSHA PEL:N/K ACGIH TLV:N/K Ingred Name:SUPDAT:SPRAY. IN CASE OF SPILL, CAREFULLY NEUT SPILL W/DILUTE HCL. FLUSH SPILL AREA W/WATER. INTERNATIONAL LBLG: (ING 4) RTECS #:9999999ZZ Ingred Name:ING 3:IRRITATING TO EYES, RESP SYS & SKIN. KEEP OUT OF REACH OF CHILDREN. IN CASE OF CONT W/EYES, RINSE IMMED (ING 5) RTECS #:9999999ZZ Ingred Name:ING 4:WITH PLENTY OF WATER & SEEK MEDICAL ADVICE. RTECS #:9999999ZZ Ingred Name:EYE PROT:FULL FACESHIELD . RTECS #:9999999ZZ ===================== Hazards Identification ===================== LD50 LC50 Mixture:SEE INGREDIENT 1 Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:ACUTE:INHALATION:SEVERE IRRITATION OR BURNS OF RESPIRATORY SYSTEM, PULMONARY EDEMA, LUNG INFLAMMATION. SKIN:SEVERE IRRITATION OR BURNS. EYE:SEVERE IRRITATION OR BURNS, PROLONGED CONTACT MAY CAUSE PERM ANENT CORNEAL DAMAGE, BLINDNESS. INGESTION:IS HARMFUL AND MAY BE FATAL, SEVERE BURNS TO MOUTH, THROAT, (EFTS OF OVEREXP) Explanation of Carcinogenicity:NOT RELEVANT. Effects of Overexposure:HLTH HAZ:AND STOMACH, NAUSEA, VOMITING, DIARRHEA. TARGET ORGANS:RESPIRATORY SYSTEM, LUNGS, EYES, SKIN, MUCOUS MEMBRANES. Medical Cond Aggravated by Exposure:SKIN DISORDERS, RESPIRATORY SYSTEM DISEASE. ======================= First Aid Measures ======================= First Aid:INGEST:CALL PHYS. IF SWALLOWED, DO NOT INDUCE VOMIT. IF CONSCIOUS, GIVE LG AMTS OF WATER. FOLLOW W/DILUTED VINEGAR, FRUIT JUICE/WHITES OF EGGS, BEATEN W/WATER. INHAL:REMOVE TO FRESH AIR. IF NOT BRTHG,GIVE ARTF RESP. IF BRTHG IS DFCLT, GIVE OXYG. SKIN:IMMED FLUSH W/PLENTY OF WATER FOR @ LEAST 15 MINS WHILE REMOVING CONTAMD CLTHG & SHOES. WASH CLTHG BEFORE RE-USE. EYE:IMMED FLUSH W/PLENTY (SUPDAT) ===================== Fire Fighting Measures ===================== Extinguishing Media:USE WATER SPRAY. Fire Fighting Procedures:NIOSH/MSHA APPRVD SCBA W/FULL FACEPIECE OPERATED IN POS PRESS MODE. MOVE EXPOS CNTNRS FROM FIRE AREA IF IT CAN BE DONE W/OUT RISK. USE WATER TO KEEP (SUPDAT) Unusual Fire/Explosion Hazard:GIVES OFF FLAM VAPS. VAPS MAY FORM EXPLO MIX W/AIR. CLSD CNTNRS EXPOS TO HEAT MAY EXPLODE. ANHYDROUS AMMONIA HAS FOLLOWING FLAM LIMS:UPPER-25% & LOWER- (SUPDAT) ================== Accidental Release Measures ================== Spill Release Procedures:WEAR NIOSH/MSHA APPRVD SCBA & FULL PROT CLTHG. STOP LEAK IF YOU CAN DO SO W/OUT RISK. VENTILATE AREA. CAREFULLY NEUTRALIZE SPILL W/DILUTE HCL. FLUSH AREA W/FLOODING AMTS OF WATER. (USE CAUTION). Neutralizing Agent:J T BAKER NEUTRACIT(R)-2 OR BUCAIM CAUSTIC NEUTRALIZERS. ======================Handling and Storage ====================== Handling and Storage Precautions:KEEP CNTNR TIGHTLY CLSD. STORE IN CORR-PROOF AREA. STORE BELOW 25C. DO NOT STORE IN DIRECT SUNLIGHT. ISOLATE FROM INCOMPATIBLE MATERIALS. Other Precautions:U.S. PRECAUT LBL:POISON DANGER:CAUSES BURNS. HARMFUL IF INHAL. MAY BE FATAL IF SWALLOWED. EXCEPTIONAL HLTH & CONT HAZ:READ MATL SFTY DATA SHEET. DO NOT GET IN EYES, ON SKIN, ON CLTHG. DO NOT BREATHE V AP. KEEP IN TIGHTLY CLSD CNTNR. (SUPDAT) ============= Exposure Controls/Personal Protection ============= Respiratory Protection:AT CONC UP TO 300 PPM, NIOSH/MSHA APPRVD CHEM CARTRIDGE RESP W/AMMONIA/AMINE CARTRIDGE & DUST/MIST FILTER IS REC. ABOVE THIS LEVEL, NIOSH/MSHA APPRVD SCBA IS ADVISED. Ventilation:GENERAL OR LOCAL EXHAUST VENT TO MEET TLV REQUIREMENTS. Other Protective Equipment:UNIFORM, PROT SUIT, LAB COAT & APRON; VENT HOOD. ANSI APPRVD EMER EYE BATH, AND DELUGE SHOWER . Work Hygienic Practices:WASH HANDS THOROUGHLY AFTER HANDLING. Supplemental Safety and Health FIRE FIGHT PROC:FIRE-EXPOS CNTNRS COOL; DO NOT GET WATER INSIDE CNTNRS. EXPLO HAZ:16%. AUTOIGNIT TEMP FOR AMMONIA GAS IS 1204F. MATLS TO AVOID:MERCURY, DIMETHYL SULFATE. FIRST AID PROC:OF WATER FOR @ LEAST 15 MINS. OTHER PRECAUT:USE W/ADEQVENT. KEEP CNTNR OUT OF SUN & AWAY FROM HEAT. IN CASE OF FIRE, USE WATER (ING 3) ================== Physical/Chemical Properties ================== Melt/Freeze Pt:M.P/F.P Text:-108F,-78C Vapor Pres:570 @ 20C Vapor Density:0.60 Spec Gravity:0.90 (H*2O=1) pH:14 Solubility in Water:COMPLETE (100%) Appearance and Odor:CLEAR, COLORESS LIQUID, PUNGENT ODOR Percent Volatiles by Volume:100 ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES STRONG ACIDS, MOST COMMON METALS, STRONG OXIDIZING AGENTS, BROMINE, CHLORINE, ALUMINUM, COPPER, BRASS, BRONZE, (SUPDAT) Stability Condition to Avoid:HEAT, SUNLIGHT. Hazardous Decomposition Products:AMMONIA, OXIDES OF NITROGEN. ==================== Disposal Considerations ==================== Waste Disposal Methods:DISPOSE IN ACCORDANCE WITH ALL APPLICABLE FEDERAL, STATE, AND LOCAL ENVIRONMENTAL REGULATIONS.
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:5500 SERIES FLAT POSTER INK,SILKSREEN KIT 348-6040(SUPPLE) CAGE:76708 CAGE:76708 CAGE:26290 ============= Composition/Information on Ingredients ============= Ingred Name:PETROLEUM DISTILLATE; ALIPHATIC HYDROCARBON, CAS:64742-88-7 Fraction by Wt: 15-80% Other REC Limits:NONE RECOMMENDED Ingred Name:COPPER (SARA 313) (CERCLA) CMPDS CAS:7440-50-8 RTECS #:GL5325000 Fraction by Wt: 0-20% Other REC Limits:NONE RECOMMENDED OSHA PEL:0.1MG/M3 FUME/1 DUST ACGIH TLV:0.2 MG/M3 FUME; 9596 EPA Rpt Qty:5000 LBS DOT Rpt Qty:5000 LBS Ingred Name:NAPHTHA, LIGHT AROMATIC (SOLVENT NAPHTHA); (PETROLEUM DISTILLATE;AROMATIC HYDROCARBON,) CAS:64742-95-6 RTECS #:WF3400000 Fraction by Wt: 0-15% Other REC Limits:NONE RECOMMENDED Ingred Name:SILICA, CRYSTALLINE - CRISTOBALITE CAS:14464-46-1 RTECS #:VV7325000 Fraction by Wt: 0-15% Other REC Limits:NONE RECOMMENDED OSHA PEL:SEE TABLE Z-3 ACGIH TLV:0.05 MG/M3 RDUST9596 Ingred Name:PETROLEUM HYDROCARBON,ALIPHATIC HDYROCARBON CAS:64742-47-8 RTECS #:OA5504000 Fraction by Wt: 0-7% Other REC Limits:NONE RECOMMENDED Ingred Name:1,2,4-TRIMETHYLBENZENE (SARA 313) CAS:95-63-6 RTECS #:DC3325000 Fraction by Wt: 0-5% Other REC Limits:NONE RECOMMENDED OSHA PEL:25 PPM ACGIH TLV:25 PPM; 9596 Ingred Name:ZINC (SARA 313) (CERCLA) CMPDS CAS:7440-66-6 RTECS #:ZG8600000 Fraction by Wt: 0-5% Other REC Limits:NONE RECOMMENDED EPA Rpt Qty:1000 LBS DOT Rpt Qty:1000 LBS Ingred Name:MANGANESE (SARA 313) CMPDS CAS:7439-96-5 RTECS #:OO9275000 Fraction by Wt: 0-4% Other REC Limits:NONE RECOMMENDED OSHA PEL:C, 5 MG/M3 (FUME) ACGIH TLV:0.2 MG/M3; 9596 Ingred Name:HEAVY AROMATIC NAPHTHA (SOLVENT NAPHTHA); (PETROLEUM DISTILLATE;AROMATIC HYDROCARBON,) CAS:64742-94-5 RTECS #:WF3100000 Fraction by Wt: 0-3% Other REC Limits:NONE RECOMMENDED Ingred Name:XYLENES (O-,M-,P- ISOMERS) (SARA 313) (CERCLA) CAS:1330-20-7 RTECS #:ZE2100000 Fraction by Wt: <3% Other REC Limits:NONE RECOMMENDED OSHA PEL:100 PPM ACGIH TLV:100 PPM/150STEL;9596 EPA Rpt Qty:1000 LBS DOT Rpt Qty:1000 LBS Ingred Name:ETHYL ALCOHOL (ETHANOL) CAS:64-17-5 RTECS #:KQ6300000 Fraction by Wt: <2% Other REC Limits:NONE RECOMMENDED OSHA PEL:1000 PPM ACGIH TLV:1000 PPM; 9596 Ingred Name:VOLITILE ORGANIC CONTENT AS LISTED ON MSDS., 8.4 WT/GAL, 402 G/L; 3.4 LB/GAL, 49% VOC. RTECS #:9999999VC Fraction by Wt: NA Other REC Limits:NONE RECOMMENDED ===================== Hazards Identification ===================== LD50 LC50 Mixture:NONE SPECIFIED BY MANUFACTURER. Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES Reports of Carcinogenicity:NTP:YES IARC:YES OSHA:NO Health Hazards Acute and Chronic:EYE:MAY CAUSE MODERATE-SEVERE IRRIT.SKIN:REP/PROL CONTACT MAY CAUSE SLIGHT IRRIT OR MILD DERM,MAY CAUSE BURNS.INHAL:OVEREXPO MAY CAUSE RESP TRACT IRRIT OR NERVOUS SYST DISORDERS.INGEST:MAY CAUSE ABDOM INAL PAIN,NAU,DIARR,VOMIT.ASPIRATION OFMATL INTO LUNGS MAY CAUSE CHEM PNEUMONITIS-FATAL.REPORTS HAVE ASSOC (SUPPLEM) Explanation of Carcinogenicity:PER MSDS:CRYSTALLINE SILICA CLASSIFIED AS PROBABLE CARC BY NPT/IARC(2A).CONTAINS CHEM KNOWN TO CA STATE AS CARC/REPRO TX Effects of Overexposure:EYE:BURNING,TEARING,SWELLING,REDNESS. SKIN:MILD DERMATITIS CHARACTERIZED BY DRYNESS, CHAPPING,REDNESS. CNS DISORDERS SUCH AS HEADACHES,DIZZ,WEAKNESS,FATIGUE. INGEST:ABD PAIN,NAU,DIARRHEA,VOMIT,ASPIRAT ION INTO LUNGS-CHEM PNEUMONITIS-FATAL. Medical Cond Aggravated by Exposure:PERSONS W/PRE-EXISTING SKIN/LUNG DISORDERS MAY BE MORE SUSCEPTIBLE TO EFFECTS OF MATL.REP/PROL OVEREXPO &/OR INDIVIDUAL SENSITIVITY MAY INCR POTENTIAL FOR & DEGREE OF ADVERSE HEALTH EFFECTS. ======================= First Aid Measures ======================= First Aid:SKIN:WASH W/SOAP/WATER.IRRIT PERSISTS CONTACT PHYSICIAN.EYE:FLUSH WELL W/RUNNING WATER FOR MIN OF 15MINS.IRRIT PERSISTS CONTACT PHYSICIAN.INHAL:REMOVE TO FRESH AIR.RESTORE BREATH.CONTACT PHYSICIAN.ING EST:CONTACT PHYSICIAN OR POISON CONTROLCENTER IMMED.OTHER COMMENTS:POTENTIAL HEALTH EFFECTS OF THIS PRODUCT ARE BASED ON HAZARDS OF ITS COMPONENTS. ===================== Fire Fighting Measures ===================== Flash Point Method:SCC Flash Point:100F,38C Autoignition Temp:Autoignition Temp Text:NP Lower Limits:1.0 Upper Limits:NP Extinguishing Media:FOA, CO2, DRY CHEMICAL, WATER SPRAY. Fire Fighting Procedures:WATER MAY BE INERFFECTIVE BUT MAY BE USED TO COOL CNTNRS.THE USE OF SELF-CONTAINED BREATHING APPARATUS IS RECOMMENDED FOR FIRE FIGHTERS. Unusual Fire/Explosion Hazard:ISOLATE FROM HEAT/ELECTRICAL EQPMT/SPARKS/OPN FLAME.CLSD CNTNRS MAY EXPLODE WHEN EXPO TO EXTREME HEAT.CLASS II COMBUSTILBLE LIQ;DOT:COMBUSTIBLE LIQ. ================== Accidental Release Measures ================== Spill Release Procedures:REMOVE ALL IGN SOURCES.VENTILATE AREA.AVOID BREATH VAPORS.CONTAIN RELEASE & REMOVE W/INERT ABSORBENT.AVOID CONTACT.USE NON-SPARKING TOOLS TO PLACE MATERIAL IN APPROPRPIATE CONTAINER FOR DISPOSAL. Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER. ======================Handling and Storage ====================== Handling and Storage Precautions:STORE IN CLSD CNTNRS IN COOL DRY WELL VENTILATED AREA AWAY FROM SOURCES OF IGNITION.KEEP CNTNRS CLSD WHEN NOT IN USE.AVOID PROL/REP OVEREXPO TO PROD. Other Precautions:INTENTIONAL MISUE BY DELIBERATELY CONC/INHAL CONTENTS MAY BE HARMFUL/FATAL. OTHER PROTECTION:SOLVT RESISTANT APRONS & AVAILABILITY OF EYEWASH RECOMMENDED. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:VAP CONC EXCEEDS TLV USE NIOSH APPROVED RESP W/ORG CHEM CARTRIDGE.COTNACT REUPTABLE SAFETY SUPPLY COMPANY FOR APPROPRIATE RESPIRATOR. Ventilation:USE APPLICABLE ENGINEERING CNTRLS,WORK PRACTICES,PERSONAL PROTE EQPMT TO KEEP VAP CONC BELOW TLV. Other Protective Equipment:USE OF CONTACT LENSES NOT RECOMMENDED.CONTACT REPUTABLE SAF SUPPLY CO FOR APPROPRIATE EYE Work Hygienic Practices:WASH W/SOAP/WATER BEF EAT/SMOKE/TOILET USAGE.REMOVE CONTAMIN CLOTH TO PREVENT PROL SKIN CONTACT.SMOKE IN DESIGNATED AREA Supplemental Safety and Health PRODUCT:5547 PURPLE. HEALTH HAZ:REP/PROL OCCUPATIONAL OVEREXPO TO SOLVTS W/PERM BRAIN/CNS DMG.EXCESSIVE EXPO TO CRYSTALLINE SILICA CAUSE SILICOSIS(NONCAN LUNG DISEASE).OVEREXPO SHOULDN'T OCCUR DURING NORMAL USE.XYLENE CAUSES HARM TO FETUS IN LAB ANIMAL STUDIES. ================== Physical/Chemical Properties ================== HCC:F4 Boiling Pt:B.P. Text:>300F,>149C Melt/Freeze Pt:M.P/F.P Text:NP Decomp Temp:Decomp Text:NP Vapor Pres:NP Vapor Density:>AIR Spec Gravity:NP pH:NP Viscosity:NP Evaporation Rate & Reference:SLOWER THAN ETHER. Solubility in Water:NP Appearance and Odor:PURPLE COLOR. Percent Volatiles by Volume:NP Corrosion Rate:NP ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES STRONG OXIDIZING AGENTS. Stability Condition to Avoid:HEAT, SPARKS, OPEN FLAME. Hazardous Decomposition Products:CARBON MONOXIDE, CARBON DIOXIDE, OTHER NOXIOUS GASES. ==================== Disposal Considerations ==================== Waste Disposal Methods:DISPO OF IAW APPLICABLE LOCAL, STATE, COUNTY AND FEDERAL REGULATIONS.EMPTY CNTNRS SHOULD BE DISPOSED OF IN ENVIRONMENTALLY SAFE MANNER IAW APPLICABLE REGULATIONS.COTNAINS CHEMS SUBJ TO REPORTING REQMT S OF SARA TITLE III SEC 313/40CFR372.
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:163 8238 RA 2000 AUTOMIX DEVELOPER AND REPLENISHER, W.S. CAGE:19139 CAGE:19139 CAGE:5K871 ============= Composition/Information on Ingredients ============= Ingred Name:WATER CAS:7732-18-5 RTECS #:ZC0110000 Fraction by Wt: 80-95% Other REC Limits:NONE RECOMMENDED Ingred Name:POTASSIUM SULFITE CAS:10117-38-1 RTECS #:WT3530000 Fraction by Wt: 1-5% Other REC Limits:NONE RECOMMENDED Ingred Name:DIETHYLENE GLYCOL CAS:111-46-6 RTECS #:ID5950000 Fraction by Wt: 1-5% Other REC Limits:NONE RECOMMENDED Ingred Name:HYDROQUINONE (SARA 302/313) (CERCLA) CAS:123-31-9 RTECS #:MX3500000 Fraction by Wt: 1-5% Other REC Limits:NONE RECOMMENDED OSHA PEL:2 MG/M3 ACGIH TLV:2 MG/M3; 9596 EPA Rpt Qty:1 LB DOT Rpt Qty:1 LB Ingred Name:SODIUM SULFITE CAS:7757-83-7 RTECS #:WE2150000 Fraction by Wt: < 1% Other REC Limits:NONE RECOMMENDED ===================== Hazards Identification ===================== LD50 LC50 Mixture:ORAL LD50 (RAT): NOT GIVEN Routes of Entry: Inhalation:NOSkin:YES Ingestion:YES Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:EXPECTED TO BE A LOW INHALATION HAZARD FOR RECOMMENDED HANDLING. EYE CONTACT CAUSES IRRITATION. SKIN CONTACT CAUSES IRRITATION. MAY CAUSE ALLERGIC SKIN REACTION. HARMFUL IF SWALLOWED. CAN CAUSE KIDNEY DAMAGE. MAY CAUSE IRRITATION OF THE GASTROINTESTINAL TRACT. Explanation of Carcinogenicity:THIS COMPOUND CONTAINS NO INGREDIENTS AT CONCENTRATIONS OF 0.1% OR GREATER THAT ARE CARCINOGENS OR SUSPECT CARCINOGENS. Effects of Overexposure:EYE IRRITATION, SKIN IRRITATION, ALLERGIC SKIN REACTION, KIDNEY DAMAGE, GI TRACT IRRITATION. Medical Cond Aggravated by Exposure:NONE SPECIFIED BY MANUFACTURER. ======================= First Aid Measures ======================= First Aid:INHALATION: IF SYMPTOMATIC, MOVE TO FRESH AIR. GET MEDICAL ATTENTION IF SYMPTOMS PERSIST. EYES: WASH OUT IMMEDIATELY WITH WATER. GET MEDICAL ATTENTION IF SYMPTOMS OCCUR. SKIN: WASH WITH SOAP AND WATER . GET MEDICAL ATTENTION IF SYMPTOMS OCCUR. INGESTION: INDUCE VOMITING AS DIRECTED BY MEDICAL PERSONNEL. NEVER GIVE ANYTHING BY MOUTH TO AN UNCONSCIOUS PERSON. CALL PHYSICIAN OR POISON CONTROL ASAP. ===================== Fire Fighting Measures ===================== Flash Point:NONFLAMMABLE Lower Limits:NOT GIVEN Upper Limits:NOT GIVEN Extinguishing Media:NONFLAMMABLE. USE EXTINGUISHING MEDIA SUITABLE FOR SURROUNDING FIRE. Fire Fighting Procedures:WEAR SELF-CONTAINED BREATHING APPARATUS AND PROTECTIVE CLOTHING. Unusual Fire/Explosion Hazard:NONE SPECIFIED BY MANUFACTURER. ================== Accidental Release Measures ================== Spill Release Procedures:FLUSH TO SEWER IF ALLOWABLE WITH LARGE AMOUNTS OF WATER. OTHERWISE, ABSORB SPILL WITH VERMICULITE OR OTHER INERT MATERIAL, THEN PLACE IN A CONTAINER FOR CHEMICAL WASTE. CLEAN SURFACE TO REMOVE RESIDUA L CONTAMINATION. Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER. ======================Handling and Storage ====================== Handling and Storage Precautions:AVOID CONTACT WITH EYE, SKIN AND CLOTHING. USE WITH ADEQUATE VENTILATION. KEEP CONTAINER TIGHTLY CLOSED. Other Precautions:THE ROUTINE USE OF A NONALKALINE (ACID) TYPE OF HAND CLEANER AND REGULAR CLEANING OF WORKING SURFACES WILL HELP MINIMIZE THE POSSIBILITY OF A SKIN REACTION. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:NONE SHOULD BE NEEDED. Ventilation:GOOD GENERAL VENTILATION, TYPICALLY 10 AIR CHANGES PER HOUR, SHOULD BE USED. RATES SHOULD MATCH CONDITIONS. Other Protective Equipment:CHEMICAL RESISTANT CLOTHING AS NECESSARY TO PREVENT SKIN CONTACT. AN EMERGENCY EYEWASH AND SHOWER SHOULD BE AVAILABLE. Work Hygienic Practices:WASH HANDS THOROUGHLY WITH SOAP AND WATER BEFORE EATING, DRINKING, SMOKING OR USING TOILET FACILITIES. Supplemental Safety and Health REMOVE AND WASH CONTAMINATED CLOTHING BEFORE REUSE. ================== Physical/Chemical Properties ================== HCC:B3 Boiling Pt:B.P. Text:>212F,>100C Melt/Freeze Pt:M.P/F.P Text:NOT GIVEN Vapor Pres:18 Vapor Density:0.6 Spec Gravity:1.02-1.09 pH:10.4 Evaporation Rate & Reference:NOT GIVEN Solubility in Water:COMPLETE Appearance and Odor:LIGHT YELLOW LIQUID, NO ODOR Percent Volatiles by Volume:> 90% ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES NONE WITH COMMON MATERIALS AND CONTAMINANTS WITH WHICH THE MATERIAL MAY REASONABLY COME INTO CONTACT. Stability Condition to Avoid:NONE SPECIFIED BY MANUFACTURER. Hazardous Decomposition Products:NONE SPECIFIED BY MANUFACTURER. ==================== Disposal Considerations ==================== Waste Disposal Methods:DISCHARGE, TREATMENT OR DISPOSAL MAY BE SUBJECT TO NATIONAL, STATE OR LOCAL LAWS. MAY REQUIRE NEUTRALIZATION IF PH < 2.0 OR PH > 12.5. DISPOSE OF IN ACCORDANCE WITH ALL APPLICABLE FEDERAL, STATE ANDLOCAL REGULATIONS.
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:M-50 SUPER SHIELD ALL NLGI GRADES;50-0 CAGE:KO303 CAGE:53955 CAGE:KO303 ============= Composition/Information on Ingredients ============= Ingred Name:MINERAL OIL CAS:8012-95-1 RTECS #:PY8030000 Other REC Limits:NONE RECOMMENDED OSHA PEL:5 MG/M3 ACGIH TLV:5 MG/M3 (MIST); 9495 ===================== Hazards Identification ===================== LD50 LC50 Mixture:TLV FOR OIL MIST IS 5MG/M3 Routes of Entry: Inhalation:NOSkin:YES Ingestion:YES Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:ACUTE: CONTACT WITH EYES MAY CAUSE IRRITATION; PROLONGED CONTACT WITH SKIN MAY CAUSE DERMATITIS. INGESTION MAY CAUSE GI TRACT IRRITATION. NO DATA GIVEN FOR INHALED. CHRONIC: NONE SPECIFIED BY MANUFACT URER. Explanation of Carcinogenicity:NONE OF THE COMPOUNDS IN THIS PRODUCT IS LISTED BY IARC, NTP, OR OSHA AS A CARCINOGEN. Effects of Overexposure:EYES-REDNESS. SKIN-DERMATITIS. INGESTION-NAUSEA, VOMITING, PURGING (CATHARSIS). Medical Cond Aggravated by Exposure:NONE SPECIFIED BY MANUFACTURER. ======================= First Aid Measures ======================= First Aid:SKIN-REMOVE CONTAMINATED CLOTHING. WASH WITH SOAP & WATER. EYES-FLUSH WITH WATER FOR 15 MINUTES. GET MEDICAL ATTENTION IF IRRITATION PERSISTS. INHALED-REMOVE TO FRESH AIR. GIVE OXYGEN OR ARTIFICIAL RE SPIRATION IF NEEDED.INGEST-DO NOT INDUCE VOMITING. GET PROMPT MEDICAL ATTENTION. ===================== Fire Fighting Measures ===================== Flash Point Method:COC Flash Point:600F,316C Extinguishing Media:USE WATER SPRAY OR FOG, CARBON DIOXIDE, FOAM, HALON OR DRY CHEMICAL. Fire Fighting Procedures:USE A SELF-CONTAINED BREATHING APPARATUS AND FULL PROTECTIVE EQUIPMENT. COOL FIRE EXPOSED CONTAINERS WITH WATER FOG. Unusual Fire/Explosion Hazard:NONE SPECIFIED BY MANUFACTURER. ================== Accidental Release Measures ================== Spill Release Procedures:CONTAIN MATERIAL AND TRANSFER TO WASTE CONTAINER. ABSORB RESIDUE WITH AN INERT ABSORBANT. SCOOP UP AND DISPOSE OF IAW ALL APPLICABLE LOCAL, STATE AND FEDERAL REGULATIONS. Neutralizing Agent:NOT APPLICABLE. ======================Handling and Storage ====================== Handling and Storage Precautions:STORE AWAY FROM OPEN FLAMES AND STRONG OXIDIZING AGENTS. Other Precautions:NONE. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:NONE NORMALLY REQUIRED. Ventilation:NONE NORMALLY REQUIRED. Other Protective Equipment:NONE. DLA-HMIS: EYE WASH STATION. Work Hygienic Practices:WASH HANDS AFTER HANDLING AND BEFORE EATING, DRINKING, OR SMOKING. LAUNDER CONTAMINATED CLOTHES BEFORE REUSE. Supplemental Safety and Health MSDS PRESENTED BY CAGE 53933 FOR CONTRACT NUMBER SP0451-96-MP095. ================== Physical/Chemical Properties ================== HCC:V6 Boiling Pt:B.P. Text:600F,316C Spec Gravity:0.93 Solubility in Water:NIL Appearance and Odor:SOLID, DARK GRAY; SLIGHT ODOR. ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES STRONG OXIDIZING AGENTS. Stability Condition to Avoid:NONE SPECIFIED BY MANUFACTURER. Hazardous Decomposition Products:CARBON DIOXIDE, CARBON MONOXIDE, OXIDES OF ANTIMONY, SULFUR AND NITROGEN. Conditions to Avoid Polymerization:WILL NOT OCCUR. ==================== Disposal Considerations ==================== Waste Disposal Methods:DISPOSE OF RECOVERED MATERIAL OR ABSORBENT MATERIAL IN A MANNER ACCEPTABLE TO GOOD WASTE MANAGEMENT PRACTICE AND IN COMPLIANCE WITH APPLICABLE LOCAL, STATE AND FEDERAL REGULATIONS. LANDFILL OR INCINER ATION ACCEPTABLE IF IN COMPLIANCE WITH THE ABOVE. ======================================================================
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:160 8413 VERSAMAT 641 FIXER AND REPLENISHER, PART B CAGE:19139 CAGE:19139 CAGE:5K871 ============= Composition/Information on Ingredients ============= Ingred Name:AMMONIUM SULFATE (SOLUTION) (SARA 313) CAS:7783-20-2 RTECS #:BS4500000 Fraction by Wt: 75-80% Other REC Limits:NONE RECOMMENDED Ingred Name:CITRIC ACID CAS:77-92-9 RTECS #:GE7350000 Fraction by Wt: 1-5% Other REC Limits:NONE RECOMMENDED Ingred Name:AMMONIUM ALUM, DODECAHYDRATE CAS:7784-25-0 Fraction by Wt: 15-20% Other REC Limits:NONE RECOMMENDED ===================== Hazards Identification ===================== LD50 LC50 Mixture:NONE SPECIFIED BY MANUFACTURER. Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:INHAL:EXPECTED TO BE LOW HAZ FOR RECOMMENDED HANDLING.EYE:NO SPECIFIC HAZ KNOWN.MAY CAUSE TRANSIENT IRRIT.SKIN:LOW HAZ FOR RECOMMENDED HNDLG.INGEST:EXPECTED TO BE LOW INGEST HAZ. Explanation of Carcinogenicity:PER MSDS:CARC CLASSIFICATION:IARC/ACGIH/NTP/OSHA:NONE. Effects of Overexposure:TRANSIENT EYE IRRIT. Medical Cond Aggravated by Exposure:NONE SPECIFIED BY MANUFACTURER. ======================= First Aid Measures ======================= First Aid:INHAL:IF SYMPTOMATIC MOVE TO FRESH AIR.TREAT SYMPTOMATICALLY.SYMPTOMS PERSIST GET MED ATTN.EYE:ANY MATL THAT CONTACT EYE SHOULD BE WASHED OUT IMMED W/WATER.SYMPTOMS OCCUR GET MED ATTN.SKIN:WASH W/SOAP /H2O.SYMPTOMS OCCUR GET MED ATTN.INGEST:DRINK 1-2 GLASSES OF H2O.SEEK MED ATTN.NEVER GIVE ANYTHING BY MOUTH TO UNCONSC PERSON. ===================== Fire Fighting Measures ===================== Autoignition Temp:Autoignition Temp Text:NP Lower Limits:NP Upper Limits:NP Extinguishing Media:USE APPROPRIATE AGENT FOR ADJACENT FIRE. Fire Fighting Procedures:WEAR SELF-CONTAINED BREATHING APPARATUS & PROTECTIVE CLOTHING.FIRE OR EXCESSIVE HEAT MAY PRODUCE HAZ DECOMPOSITION PRODUCTS. Unusual Fire/Explosion Hazard:NONE. NON-COMBUSTIBLE SOLID. ================== Accidental Release Measures ================== Spill Release Procedures:FLUSH TO SEWER W/LG AMTS OF WATER.OTHERWISE SWEEP UP & PLACE IN CNTNR FOR CHEM WASTE.CLEAN SURFACE THOROUGHLY TO REMOVE RESIDUAL CONTAMINATION. Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER. ======================Handling and Storage ====================== Handling and Storage Precautions:USE W/ADEQUATE VENTI.KEEP FROM CONTACT W/OXIDIZING MATLS.KEEP CNTNR TIGHTLY CLSD.KEEP AWAY FROM INCOMPATIBLE SUBSTANCES. Other Precautions:PROPERTIES:LOW BIOCHEM OXY DEMAND,LITTLE POT TO CAUSE OXY DEPLETION IN AQU SYS,LOW POT TO AFFECT AQU ORGANISMS,LOW POT TO AFFECT 2ND WASTE TREAT MICROBIAL METABOLISM,HI POT TO AFFECT GERM/EARLY PLANT GROWTH,LOW POT TO BIOCONCEN.AFT (SUPPLE) ============= Exposure Controls/Personal Protection ============= Respiratory Protection:NONE SHOULD BE NEEDED. Ventilation:GOOD GEN VENTI (TYPICALLY 10AIR CHANGES/HR) SHOULD BE USED.VENTI RATES SHOULD BE MATCHED TO CONDITIONS. Other Protective Equipment:EYE BATH,WASHIHG FACILITIES,SAFETY SHOWER. Work Hygienic Practices:WASH WELL AFT HNDLG.GOOD INDUSTRIAL HYG PRA TO MIN EYE & SKIN CONTACT. Supplemental Safety and Health OTHER PRECAU:DIL W/LG AMT OF WATER,MATL RELEASED IDR/INDIR INTO ENVIR NOT EXPECTED TO HAVE SIGNIFICANT IMPACT. ================== Physical/Chemical Properties ================== HCC:N1 Boiling Pt:B.P. Text:NP Melt/Freeze Pt:M.P/F.P Text:N/AVAI Decomp Temp:Decomp Text:NP Vapor Pres:NEGLIGIBLE Vapor Density:NA Spec Gravity:N/AVAI pH:NA Viscosity:NP Evaporation Rate & Reference:NP Solubility in Water:APPRECIABLE Appearance and Odor:SOLID (POWDER), WHITE, ODORLESS Percent Volatiles by Volume:NA Corrosion Rate:NP ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES BASES, SODIUM HYPOCHLORITE(BLEACH),STRONG OXIDIZING AGENTS.CONTACT W/BASE LIBERATES FLAMM MATERIAL. Stability Condition to Avoid:NONE SPECIFIED BY MANUFACTURER. Hazardous Decomposition Products:AMMONIA,SULFUR DIOXIDE,NITOGEN OXIDES(NOX),CHLORAMINE.HAZ COMBUST PROD:NONE (NON-COMBUSTIBLE) ==================== Disposal Considerations ==================== Waste Disposal Methods:DISCHARGE/TREATMENT/DISPO MAY BE SUBJ TO NAT/STATE/LOC LAWS.FLUSH TO SEWER W/LG AMTS OF H2O.CHEM SUBJ TO REPORTING REQMTS OF SEC 313 TITLE III SARA/40CFR372:NONE.
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:304-309 MINERAL OIL Preparer's Name:DICK KARBO CAGE:KMADD CAGE:KMADD ============= Composition/Information on Ingredients ============= Ingred Name:NON-HAZARDOUS FOR INGREDIENTS ===================== Hazards Identification ===================== Routes of Entry: Inhalation:NOSkin:YES Ingestion:NO Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:PROLONGED CONTACT W/SKIN/EYES CAN CAUSE IRRITATION. Explanation of Carcinogenicity:NONE Effects of Overexposure:IRRITATION ======================= First Aid Measures ======================= First Aid:EYES: FLUSH IMMEDIATELY W/WATER. SKIN: WASH AFFECTED AREA W/SOAP & WATER. OBTAIN MEDICAL ATTENTION IN ALL CASES. ===================== Fire Fighting Measures ===================== Flash Point Method:CC Flash Point:>200F Extinguishing Media:FOAM, CO2, DRY CHEMICAL ================== Accidental Release Measures ================== Spill Release Procedures:SMALL: WIPE UP & STORE WIPERS IN UNDERWRITERS APPROVED CONTAINERS. LARGE: SCOOP MATERIAL INTO SEALABLE CONTAINERS. WIPE UP REMAINDER & STORE WIPERS IN UNDERWRITERS APPROVED CONTAINERS. ======================Handling and Storage ====================== Handling and Storage Precautions:STORE IN CLOSED CONTAINERS. Other Precautions:AVOID CONTACT W/SKIN, EYES & CLOTHING. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:AS REQUIRED Ventilation:LOCAL EXHAUST Work Hygienic Practices:WASH AFTER USE. REMOVE/LAUNDER CONTAMINATED CLOTHING BEFORE REUSE. DON'T CONSUME FOOD/BEVERAGE WHERE PRODUCT IS USED. Supplemental Safety and Health ================== Physical/Chemical Properties ================== Boiling Pt:B.P. Text:470-610F Evaporation Rate & Reference:SLOWER THAN WATER Solubility in Water:INSOLUBLE Appearance and Odor:OILY ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES ==================== Disposal Considerations ==================== Waste Disposal Methods:DISPOSE OF IN ACCORDANCE W/FEDERAL, STATE & LOCAL REGULATIONS.
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:3-4221 PANTONE RUBBER BASE INK Preparer's Name:KENNETH W. PINTER CAGE:17638 CAGE:17638 ============= Composition/Information on Ingredients ============= Ingred Name:PETROLEUM HYDROCARBON (SEVERLY HYDROTREATED) CAS:64742-46-7 Fraction by Wt: 7-12% OSHA PEL:5 MG/M3 ACGIH TLV:5 MG/M3 ===================== Hazards Identification ===================== Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES Health Hazards Acute and Chronic:PROLONGED OR REPEATED SKIN CONTACT MAY LEAD TO IRRITATION AND DERMATITIS. Explanation of Carcinogenicity:CONTAINS NO MATERIALS THAT ARE CONSIDERED TO BE CARCINOGENS BY NTP,IARC OR OSHA. Effects of Overexposure:ORAL INGESTION MAY CAUSE IRRITATION OR GASTRIC DISTURBANCE. MAY BE SLIGHT IRRITATING UPON DIRECT EYE CONTACT. MAY CAUSE IRRITATION AND DERMATITIS-DERMATITIS CHARACTERIZED BY DRYNESS,CHAPPING AND REDDE NING. OIL MISTS MAY CAUSE IRRITATION OFTHE THROAT AND LUNGS. ======================= First Aid Measures ======================= First Aid:INGESTION-DO NOT INDUCE VOMITING. CONSULT A PHYSICIAN. EYES-RINSE THOROUGHLY WITH WATER FOR 15 MIN. IF IRRITATION PERSISTS,CONSULT A PHYSICIAN. SKIN-WASH WITH SOAP AND WATER. IF IRRITATION PERSISTS, C ONSULT A PHYSICIAN. INHALATION-REMOVE TO FRESH AIR. APPLY OXYGEN IF NEEDED. CONSULT A PHYSICIAN. ===================== Fire Fighting Measures ===================== Extinguishing Media:FOAM,CO2,DRY CHEMICAL,WATER FOG. Fire Fighting Procedures:WATER MAY BE INEFFECTIVE,BUT CAN BE USED TO COOL CONTAINERS EXPOSED TO HEAT AND FLAME. Unusual Fire/Explosion Hazard:DENSE SMOKE MAY BE GENERATED WHILE BURNING. ================== Accidental Release Measures ================== Spill Release Procedures:WIPE UP AND DISPOSE OF WITH SOLID WASTE.IF SOLVENT WETTED WIPES WERE USED,DISPOSE OF IN APPROVED CONTAINERS. ======================Handling and Storage ====================== Handling and Storage Precautions:KEEP CONTAINERS CLOSED WHEN NOT IN USE.KEEP CONTAINERS AWAY FROM EXCESSIVE HEAT,SPARKS AND OPEN FLAME. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:NOT NORMALLY REQUIRED. Ventilation:MECHANICAL VENTILATION ACCEPTABLE. CLEANING PRESSES. Work Hygienic Practices:WASH HANDS AND FACE WITH SOAP AND WATER BEFORE EATING OR SMOKING. Supplemental Safety and Health FOR INDUSTRIAL USE ONLY. ================== Physical/Chemical Properties ================== Vapor Density:>AIR Spec Gravity:1.02-1.11 Solubility in Water:INSOLUBLE Appearance and Odor:INK VARNISH ODOR,PASTE. ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES OXIDIZING MATERIAL. Stability Condition to Avoid:NONE Hazardous Decomposition Products:CO,CO2 AND SMOKE. Conditions to Avoid Polymerization:WILL NOT OCCUR. ==================== Disposal Considerations ==================== Waste Disposal Methods:IN ACCORDANCE WITH LOCAL,STATE AND FEDERAL REGULATION FOR NON-FLAMMABLE OILY WASTE.
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:ACETIC ACID, GLACIAL, 5355 CAGE:4W981 CAGE:4W981 CAGE:70829 ============= Composition/Information on Ingredients ============= Ingred Name:ACETIC ACID (CERCLA) CAS:64-19-7 RTECS #:AF1225000 Fraction by Wt: 99-100% OSHA PEL:10 PPM ACGIH TLV:10 PPM; 15 STEL EPA Rpt Qty:5000 LBS DOT Rpt Qty:5000 LBS Ingred Name:SUP DAT:BY SEPARATING W/FINGERS. OBTAIN MED ATTN W/OUT DELAY, PREFERABLY FROM AN OPTHALMOLOGIST. RTECS #:9999999ZZ Ingred Name:SPILL PROC:FROM SPILL AREA. FLUSH AREA WITH WATER. PREVENT RUN-OFF FROM ENTERING DRAINS, SEWERS, OR STREAMS. RTECS #:9999999ZZ Ingred Name:EYE PROT: FULL LENGTH FACESHIELD . RTECS #:9999999ZZ ===================== Hazards Identification ===================== LD50 LC50 Mixture:LD50 (ORAL, RAT): 3310 MG/KG Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:ACUTE: INHAL: SEV IRRIT/BURNS OF RESP SYS, PULM EDEMA, LUNG INFLAMM, HEADACHE, COUGHING, DFCLT BREATHING, DIZZINESS, CHEST PAINS, TEETH DAMAGE, RESP FAILURE. SKIN CONT: SEV BURNS, MAY OCCUR, DERMATITI S. EYE CONT: SEV BURNS, PERMANENT EYE DAMAGE. SKIN ABSORPTION: NONE IDENTIFIED. INGEST: BURNS TO MOUTH (EFTS OF OVEREXP) Explanation of Carcinogenicity:NOT RELEVANT Effects of Overexposure:HLTH HAZ:AND THROAT, NAUSEA, VOMITING, GASTROINTESTINAL IRRIATION, DIARRHEA, SHOCK, MAY BE FATAL. CHRONIC EFFECTS: LUNG DAMAGE, TEETH DAMAGE. TARGET ORGANS: RESPIRATORY TRACT, EYES, SKIN, TEETH. Medical Cond Aggravated by Exposure:RESPIRATORY SYSTEM DISEASE, SKIN DISORDERS. ======================= First Aid Measures ======================= First Aid:INGEST: CALL MD. DO NOT INDUCE VOMIT. IF CONSCIOUS, GIVE H*2O, MILK, OR MILK OF MAGNESIA. INHAL: REMOVE TO FRESH AIR. IF NOT BRTHG, GIVE ARTIFICIAL RESP. IF BRTHG IS DFCLT, GIVE OXYG. PROMPT ACTION IS ESSENTIAL. SKIN CONT: IMMED FLUSH W/PLENTY OF H*2O FOR @ LST 15 MINS WHILE REMOVING CONTAMD CLTHG AND SHOES. WASH CLTHG BEFORE RE-USE. EYE CONT: IMMED FLUSH, INCLUDING UNDER EYELIDS W/LRG (SUP DAT) ===================== Fire Fighting Measures ===================== Flash Point Method:CC Flash Point:103F,39C Lower Limits:4.0% Upper Limits:19.9% Extinguishing Media:USE WATER SPRAY, ALCOHOL FOAM, DRY CHEMICAL OR CARBON DIOXIDE. Fire Fighting Procedures:USE NIOSH APPROVED SCBA AND FULL PROTECTIVE EQUIPMENT . MOVE CNTNRS FROM FIRE AREA IF IT CAN BE DONE W/OUT RISK. USE H*2O TO KEEP FIRE-EXPOSED CNTRS COOL. Unusual Fire/Explosion Hazard:VAPORS MAY FLOW ALONG SURFACES TO DISTANT IGNIT SOURCES & FLASH BACK. CLSD CNTNRS EXPOSED TO HEAT MAY EXPLODE. CONT W/STRONG OXIDIZERS MAY CAUSE FIRE. (SUP DAT) ================== Accidental Release Measures ================== Spill Release Procedures:WEAR NIOSH APPRVD SCBA & FULL PROT CLTHG. SHUT OFF IGNIT SOURCES; NO FLARES, SMKNG/FLAMES IN AREA. STOP LEAK IF YOU CAN DO W/OUT RISK. NEUT SPILL W/SODA ASH/LIME. W/CLEAN SHOVEL, CAREFULLY PLACE MATL INTO CLEAN, DRY CNTNR & COVER. REMOVE (ING 3) Neutralizing Agent:SODA ASH OR LIME. ======================Handling and Storage ====================== Handling and Storage Precautions:KEEP CNTNR TIGHTLY CLSD. STORE IN COOL, DRY, WELL-VENT, FLAM LIQ STOR AREA/CABINET. STORE >17C. AVOID BRTHG VAPORS. Other Precautions:KEEP AWAY FROM HEAT, SPKS, FLAME. DO NOT GET IN EYES, ON SKIN, ON CLTHG. USE W/ADEQ VENT. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:RESP PROTECTION REQ IF AIRBORNE CONC EXCEEDS TLV. AT CONCS UP TO 500 PPM, A NIOSH APPRVD CHEM CARTRIDGE RESP W/ACID/ORGANIC CARTRIDGE TYPE IS RECOMMENDED. ABOVE THIS LEVEL, A NIOSH APPRVD SELF-CONTAIN ED BREATHING APPARATUS IS ADVISED. Ventilation:USE GENERAL OR LOCAL EXHAUST VENTILATION TO MEET TLV REQUIREMENTS. Other Protective Equipment:ANSI APPROVED EYE WASH & DELUGE SHOWER . UNIFORM, PROTECTIVE SUIT. Work Hygienic Practices:WASH THROUGHLY AFTER HANDLING. Supplemental Safety and Health PH:2.4 (1.0M SOLN). EXPLO HAZ:REACTS W/MOST METALS TO PRDCE HYDROGEN GAS, WHICH CAN FORM AN EXPLO MIX W/AIR. MATL TO AVOID:HYDROGEN PEROXIDE, ALKALIES, CARBONATES, STRONG BASES, AMINES, PHOSPHORUS TRI CHLORIDE, PHOSPHORUS PENTACHLORIDE. FIRST AID:AMTS OF H*2O FOR @ LST 15 MINS. ASSURE ADEQ FLUSHING OF THE EYES (ING 2) ================== Physical/Chemical Properties ================== Boiling Pt:B.P. Text:244F,118C Melt/Freeze Pt:M.P/F.P Text:62.0F,16.7C Vapor Pres:11 @ 20C Vapor Density:2.1 Spec Gravity:1.05 (H*2O=1) pH:SUPDAT Evaporation Rate & Reference:0.97 (BUTYL ACETATE = 1) Solubility in Water:COMPLETE (100%) Appearance and Odor:COLORLESS LIQUID. VINEGAR-LIKE ODOR. Percent Volatiles by Volume:100% ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES STRONG OXIDIZING AGENTS, MOST COMMON METALS (EXCEPT ALUMINUM), CHROMIC ACID, NITRIC ACID, SULFURIC ACID, (SUPDAT) Stability Condition to Avoid:HEAT, FLAME, OTHER SOURCES OF IGNITION. Hazardous Decomposition Products:CARBON MONOXIDE, CARBON DIOXIDE, ACETIC ACID. ==================== Disposal Considerations ==================== Waste Disposal Methods:DISPOSE IN ACCORDANCE WITH ALL APPLICABLE FEDERAL, STATE AND LOCAL ENVIRONMENTAL REGULATIONS.
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:SILICONE FUSER OIL,S-20,S-400;KF8-0005 Resp. Party Other MSDS Num.:CPY-0201-003 Preparer's Name:JOSEPH PALMERI CAGE:EO160 CAGE:EO160 CAGE:UO424 ============= Composition/Information on Ingredients ============= Ingred Name:SILICONE. (MANUFACTURER STATES ALL OTHER INFORMATION IS PROPRIETARY) CAS:63148-62-9 RTECS #:JT6484500 = Wt:100. ===================== Hazards Identification ===================== LD50 LC50 Mixture:LD50 > 5 G/KG (ESTIMATED) Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:NO KNOWN CHRONIC HEALTH EFFECTS, BUT UNNECESSARY EXPOSURE TO ANY CHEMICAL SHOULD BE AVOIDED. EFFECTS OF OVEREXPOSURE: INHALATION: EXPECTED TO BE A LOW HAZARD FOR RECOMMENDED HANDLING. EYE: NO SPECIF IC HAZARDS KNOWN. MAY CAUSE TRANSIENT IRRITATION. SKIN: EXPECTED TO BE LOW HAZARD FOR RECOMMENDED HANDLING. INGESTION: EXPECTED TO BE LOW INGESTION HAZARD. Explanation of Carcinogenicity:CARCINOGENICITY CLASSIFICATION (COMPONENTS PRESENT AT 0.1% OR MORE): NONE. IARC: NONE.ACGIH: NONE. NTP: NONE. OSHA: NONE. Medical Cond Aggravated by Exposure:THIS PRODUCT AS WITH ANY CHEMICAL, MAY ENHANCE CONDITIONS ON CERTAIN PEOPLE. CANNON DOES NOT KNOW OF ANY MEDICAL CONDITION THAT MIGHT BE AGGRAVATED BY EXPOSURE TO THIS PRODUCT. ======================= First Aid Measures ======================= First Aid:INHALATION: IF SYMPTOMATIC, MOVE TO FRESH AIR. GET MEDICAL ATTENTION IF SYMPTOMS PERSIST. EYES: ANY MATERIAL THAT CONTACTS THE EYE SHOULD BE WASHED OUT IMMEDIATELY WITH WATER. GET MEDICAL ATTENTION I F SYMPTOMS OCCUR. SKIN: WASH WITH SOAP AND WATER. GET MEDICAL ATTENTION IF SYMPTOMS OCCUR. INGESTION: DRINK 1-2 GLASSES OF WATER. SEEK MEDICAL ATTENTION. ===================== Fire Fighting Measures ===================== Flash Point:=321.C, 609.8F Extinguishing Media:WATER SPRAY, CARBON DIOXIDE (CO*2), DRY CHEMICAL. Fire Fighting Procedures:SELF-CONTAINED BREATHING APPARATUS (NIOSH APPROVED; ) AND PROTECTIVE CLOTHING SHOULD BE WORN IN FIGHTING FIRES INVOLVING CHEMICALS. Unusual Fire/Explosion Hazard:NONE. IGNITION TEMPERATURE: N/A. FLAMMABILITY: NON-FLAMMABLE SOLID (ACCORDING TO TEST METHOD OF 16 CFR 1500.44). HAZARDOUS COMBUSTION PRODUCTS: CARBON DIOXIDE, CARBON MONOXIDE. ================== Accidental Release Measures ================== Spill Release Procedures:USE ABSORBENT MATERIAL TO COLLECT AN CONTAIN FOR SALVAGE OR DISPOSAL. THIS OIL IF SPILLED MAY PRESENT A SKIDDING OR SLIPPING HAZARD. FOLLOWING A SPILL OR LEAK, USE ABSOBENT MATERIAL TO CONTAIN AND COL LECT EXCESS OIL FOR SALVAGE OR DISPOSAL. THOROUGHLY CLEAN THE FLOOR OR OTHER CONTAMINATED SURFACE (SUCH AS A LADDER) AND DO NOT LEAVE ANY TRACES OF OIL. USE AN ALL PURPOSE ALKALINE (ECOLOGICAL INFO) ======================Handling and Storage ====================== Handling and Storage Precautions:PERSONAL PRECAUTIONARY MEASURES: USE WITH ADEQUATE VENTILATION. WASH THOROUGHLY AFTER HANDLING. PREVENTION FROM FIRE EXPLOSION: KEEP FROM CONTACT WITH OXIDIZING MATERIALS.STORAGE: KEEP CONTAINER C LOSED. Other Precautions:AT ELEVATED TEMPERATURES THIS PRODUCT IS SENSITIVE TO CONTAMINATION. IF THIS PRODUCT BECOMES CONTAMINATED WITH STRONG ACIDS, BASES, SOME METALLIC COMPOUNDS OR OXIDIZING AGENTS, THE FLASH POINT VISCOSI TY MAY CHANGE AND SHOULD BE REDETERMINED. CONTAMINATED OIL MAY GENERATE FORMALDEHYDE AT TEMPERATURESOF (TRANSPORT INFO) ============= Exposure Controls/Personal Protection ============= Respiratory Protection:NONE SHOULD BE NEEDED.WEAR A NIOSH APPROVED RESPIRATOR APPROPRIATE FOR THE EXPOSURE OF CONCERN . Ventilation:GOOD VENTILATION (TYPICALLY 4-6 ROOM VOLUMES PER HOUR) SHOULD BE USED. VENTILATION RATES SHOULD BE MATCHED TO CONDITIONS. USE WITH ADEQUATE VENTILATION. REPEATED SKIN CONTACT Other Protective Equipment:RECOMMENDED DECONTAMINATION FACILITIES: WASHING FACILITIES. EYEWASH AND DELUGE SHOWER MEETING ANSI DESIGN CRITERIA . Work Hygienic Practices:IT IS GOOD INDUSTRIAL HYGIENE PRACTICE TO MINIMIZE EYE CONTACT. GOOD INDUSTRIAL HYGIENE PRACTICE SHOULD BE FOLLOWED WHICH INCLUDES PREVENTING EYE CONTACT, MINIMIZING SKIN CONTACT, INHALATION. Supplemental Safety and Health COMPLETE PRODUCT IDENTITY: PRODUCT NAME: SILICONE FUSER OIL, S-20, S-400. ITEM NO(S): FG2-5962, KF3-9376-000, KF8-0002, KF8-0005, FG2-2928, FG2-6031, FG5-3918 (WEIGHT 400 ML TO 1400 ML). DESCRIPTIO N: SILICONE OIL FOR CANNON COLOR LASER COPIERS. ================== Physical/Chemical Properties ================== Melt/Freeze Pt:M.P/F.P Text:N/A (MELTING POINT) Vapor Pres:LESS THAN 5 MM Spec Gravity:0.98 (WATER=1) Evaporation Rate & Reference:LESS THAN 1 (ETHER = 1) Solubility in Water:NEGLIGIBLE Appearance and Odor:CLEAR, TRANSPARENT LIQUID . ODORLESS. ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES STRONG OXIDIZING AGENTS. Stability Condition to Avoid:STABLE. Hazardous Decomposition Products:COMBUSTION WILL PRODUCE CARBON DIOXIDE AND POSSIBLY TOXIC CHEMICALS SUCH AS CARBON MONOXIDE AND SILICON DIOXIDE. =================== Toxicological Information=================== Toxicological Information:MUTAGENICITY: SALMONELLA TYPHIMURIUM ASSAY (AMES TEST): NEGATIVE. HAZARDS IDENTIFICATION: * EMERGENCY OVERVIEW *LOW HAZARD FOR RECOMMENDED HANDLING. NFPA RATING: HEALTH = 1, FLAMMABILITY = 1 , REACTIVITY = 0. NOTE: HMIS AND NFPA RATINGS INVOLVE DATA AND INTERPRETATIONS THAT MAY VARY FROM COMPANY TO COMPANY. THEY ARE INTENDED ONLY FOR RAPID, GENERAL IDENTIFICATION OF THE MAGNITUDE OF THE SPECIFIC HAZARD. TO DEAL ADEQUATELY WITH THE SAFE HANDLING OF THIS MATERIAL, ALL OF THE INFORMATION CONTAINED IN THIS MSDS MUST BE CONSIDERED. ===================== Ecological Information ===================== Ecological:THIS MATERIAL HAS NOT BEEN TESTED FOR ENVIRONMENTAL EFFECTS. IN A SPILL SITUATION, MATERIAL MAY BE VISUALLY UNPLEASANT; HOWEVER, IT IS NOT EXPECTED TO CAUSE ANY ADVERSE ENVIRONMENTAL EFFECTS. SPILL RELEASE PROCEDURES (CONT): CLEANER, OR HAVE THE SURFACE (INCLUDING CARPETING) CLEANED COMMERCIALLY. PETROLEUM DISTILLATES MAY BE USED, EXCEPT ON PLASTIC OR VINYL SURFACES. DISPOSE OF ABSORBEN T MATERIAL IN ACCORDANCE WITH APPLICABLE FEDERAL, STATE AND LOCAL REQUIREMENTS. ==================== Disposal Considerations ==================== Waste Disposal Methods:INCINERATE OR LANDFILL, CAN BE INCINERATED WHEN IN COMPLIANCE WITH LOCAL, REGULATIONS. DISCHARGE, TREATMENT, OR DISPOSAL MAY BE SUBJECT TO FEDERAL, STATE OR LOCAL LAWS. =================== MSDS Transport Information =================== Transport Information:DOT SHIPPING NAME: NOT REGULATED. DOT HAZARD CLASS: N/A. UN NO: N/A. OTHER PRECAUTIONS (CONT): 150 DEGREES CENTIGRADE AND ABOVE IN THE PRESENCE OF AIR. FORMALDEHYDE IS A SKIN AND RESPIRATOR Y SENSITIZER EYE AND THROAT IRRITANT, AN ACUTE TOXICANT AND POTENTIAL CARCINOGEN. ===================== Regulatory Information ===================== SARA Title III Information:CHEMICALS SUBJECT TO THE REPORTING REQUIREMENTS OF SECTION 313 OR TITLE III OF THE SUPERFUND AMENDMENTS AND REAUTHORIZATION ACT (SARA) OF 1986 AND 40 CFR PART 372: NONE. PHYSICAL / CHEMICAL PRO PERTIES (CONT): SOLUBILITY IN ORGANIC SOLVENTS: SOLUBLE IN ESTERS, KETONES, AROMATIC SOLVENTS AND OTHER ORGANIC SOLVENTS. Federal Regulatory Information:TSCA STATUS: ALL CHEMICAL INGREDIENTS FOUND ON TSCA INVENTORY. RCRA STATUS: IF DISCARDED IN ITS PURCHASED FORM, THIS PRODUCT WOULD NOT BE A HAZARDOUS WASTE EITHER BY LISTING OR CHARACTERISTIC. HOWEVE R, THE RCRA, IT IS THE RESPONSIBILITY OF THE END-USER TO DETERMINE AT THE TIME OF DISPOSAL, WHETHER A MATERIAL CONTAINING THE PRODUCT OR DERIVED FROM THE PRODUCT SHOULD BE CLASSIFIED AS HAZARDOUS WAST E. 40 CFR 261.20-24. US / CANADA LABEL STATEMENTS: LOW HAZARD FOR RECOMMENDED HANDLING. USE WITH ADEQUATE VENTILATION. IN CASE OF FIRE: USE WATER SPRAY, CARBON DIOXIDE (CO2), OR DRY CHEMICAL. IN CASE OF A SPILL: (OTHER INFORMATION) State Regulatory Information:MATERIAL(S) KNOWN TO THE STATE OF CALIFORNIA TO CAUSE CANCER: NONE. MATERIAL(S) KNOWN TO THE STATE OF CALIFORNIA TO CAUSE ADVERSE REPRODUCTIVE EFFECTS: NONE. MSDS PREPARER (CONT): PREPARED BY:JOSEPH PALMERI. TITLE: REGULATORY COMPLIANCE SPECIALIST, QUALITY MANAGEMENT DEPARTMENT. ======================= Other Information =======================
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:ATOMIC SPECTROSCOPY STANDARD, N930-0136 CAGE:34682 CAGE:34682 ============= Composition/Information on Ingredients ============= Ingred Name:NICKEL (SARA III) CAS:7440-02-0 RTECS #:QR5950000 Fraction by Wt: 0.1% OSHA PEL:1 MG/M3 ACGIH TLV:1 MG/M3 Ingred Name:SUPDAT:SOLN CAUSES DEEP ULCERS & STAIN SKIN BRIGHT YELLOW/YELLOWISH BROWN COLOR. VAP & MIST MAY ERODE EXPOS TEETH(ING 4) RTECS #:9999999ZZ Ingred Name:ING 3:W/PRLNG EXPOS. INGEST:OF LIQ WILL CAUSE IMMED PAIN & BURNS OF MOUTH, ESOPHAGUS & GI TRACT. INHAL:MAY BE (ING 5) RTECS #:9999999ZZ Ingred Name:ING 4:FATAL CAUSING SPASM, INFLAMM & EDEMA OF LARYNX & BRONCHI, CHEM PNEUM & PULM EDEMA. SYMP INCL BURNING (ING 6) RTECS #:9999999ZZ Ingred Name:ING 5:SENSATION, COUGHING, WHEEZING, LARYNGITIS, SHORTNESS OF BREATH, HDCH, NAUS & VOMIT. NICKEL SALTS ARE ALL (ING 7) RTECS #:9999999ZZ Ingred Name:ING 6:CONSIDERED CARCINOGENIC & AS DUST/FUME PROBABLY PRDCE CANCER OF PARANASAL SINUSES & LUNGS. RTECS #:9999999ZZ Ingred Name:FIRST AID PROC:CONTINUES, GET MED ATTN IMMED. RTECS #:9999999ZZ Ingred Name:NITRIC ACID (SARA III) CAS:7697-37-2 RTECS #:QU5775000 Fraction by Wt: 2% OSHA PEL:2 PPM; 4 STEL ACGIH TLV:2 PPM; 4 STEL EPA Rpt Qty:1000 LBS DOT Rpt Qty:1000 LBS ===================== Hazards Identification ===================== LD50 LC50 Mixture:NONE SPECIFIED BY MANUFACTURER. Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES Reports of Carcinogenicity:NTP:YES IARC:YES OSHA:NO Health Hazards Acute and Chronic:THIS SOLN MAY CAUSE IRRIT IF INHAL/INGEST/ ABSORBED THRU SKIN. WILL CAUSE IRRIT IF IT COMES INTO CNTCT W/EYES. NICKEL SALTS AS DUST/FUME CAUSE SENSIT DERM. IN HIGH CONC IT IS RESP IRRIT. "NICKEL ITCH" IS DERM RSLTG FROM SENSIT TO NICKEL. FIRST SYMP IS ITCHING, WHICH OCCURS UP TO 7 DAYS BEFORE SKIN (EFTS OF OVEREXP) Explanation of Carcinogenicity:NICKEL:GROUP 2B(IARC) IARC MONOGRAPHS, SUPPLEMENT. VOL 7, PG 264, 1987. ANTIC TO BE CARCIN(NTP), NTP 6TH ANNUAL (SUPDAT) Effects of Overexposure:HLTH HAZ:ERUPTION. THIS MAY FOLLOW BY ULCERS, ECZEMA, PIGMENTED/DEPIGMENTED PLAQUES W/THE LUNG, ASTHMA, ALSO DECR PULM FUNC, DYSPNEA & POSSIBILITY OF DEVELOPING HYPERSENS PNEUM. CONC NITRIC ACID MAY B E FATAL IF TOO MUCH INHAL/ABSORBED THRUSKIN. CONC NITRIC ACID VAP/MIST IS IRRIT OF EYES, MUC MEMB & SKIN. EYES:(SUPDAT) Medical Cond Aggravated by Exposure:NONE SPECIFIED BY MANUFACTURER. ======================= First Aid Measures ======================= First Aid:SKIN:FLUSH W/COPIOUS AMTS OF H2O (DELUGE SHOWER) FOR @ LEAST 15 MIN. REMOVE CONTAMD GARMENTS UNDER SHOWER. CALL MD . WASH CLTHG THORO BEFORE REUSE. EYES:FLUSH W/H2O FOR @ LEAST 15 MIN OCCASNLY L IFTING UPPER & LOWER EYELIDS. INHAL:MOVE TO FRESH AIR. INGEST:DO NOT INDUCE VOMIT. IMMED OBTAIN MED HELP. SEND TO HOSPITAL. ONLY IF PATIENT CONSCIOUS, GIVE LG QTYS H2O/MILK. IF IRRIT (ING 8) ===================== Fire Fighting Measures ===================== Extinguishing Media:APPROPRIATE TO SURROUNDING FIRE CONDITIONS. Fire Fighting Procedures:USE NIOSH/MSHA APPROVED SCBA & FULL PROTECTIVE EQUIPMENT . Unusual Fire/Explosion Hazard:CONCENTRATED NITRIC ACID REACTS EXPLO W/ COMBUST ORGANIC OR READILY OXIDIZABLE MATLS SUCH AS ALCOHOL, WOOD, TURPENTINE, METAL POWDERS, HYDROGEN SULFIDE, ETC. ================== Accidental Release Measures ================== Spill Release Procedures:VENT AREA. DILUTE SPILL W/H2O & NEUTRALIZE W/SODA ASH, LIMESTONE, ETC. WIPE UP & PUT INTO SEALED CNTNR FOR PROPER DISP. WASH SPILL SITE OFF W/H2O AFTER MATL PICK UP IS NIOSH/MSHA APPRVD RESP. Neutralizing Agent:SODA ASH, LIMESTONE. ======================Handling and Storage ====================== Handling and Storage Precautions:CONCENTRATED NITRIC ACID WILL ATTACK SOME FORMS OF PLASTIC, RUBBER & COATINGS. STORE AT ROOM TEMP. KEEP TIGHTLY SEALED WHEN NOT IN USE. Other Precautions:HAVE IMMEDIATE AVAILABILITY OF AN EYE WASH IN CASE OF EMERGENCY. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:USE NIOSH/MSHA APPROVED RESPIRATOR. Ventilation:CHEMICAL FUME HOOD. Other Protective Equipment:EMERGENCY EYE WASH & DELUGE SHOWER . LAB COAT. Work Hygienic Practices:WASH CAREFULLY AFTER USE. Supplemental Safety and Health MATLS TO AVOID:ALCOHOL, WOOD, TURPENTINE, METAL PWDRS, HYDROGEN SULFIDE, ETC. CNTCT W/STRONG BASES WILL CAUSE VIOLENT SPLATTERING. EXPLAN OF CARCIN:RPT ON CARCIN, 1992. EFTS OF OVEREXP:PRDCE SEV BURNS WHICH MAY RSLT IN PERM DMG & VISUAL IMPAIRMENT. SKIN:LIQ/CONC VAP PRDCE IMMED, SEV & PENETRATING BURNS; CONC (ING 3) ================== Physical/Chemical Properties ================== HCC:C1 Spec Gravity:APPROX 1 Solubility in Water:SOLUBLE Appearance and Odor:TRANSPARENT WITH AN ACRID ODOR. ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES CONC NITRIC ACID IS POWERFUL OXIDIZING AGENT. REACTS EXPLO W/COMBUST ORG/READILY OXIDIZABLE MATLS SUCH AS (SUPDAT) Stability Condition to Avoid:ELEVATED TEMPERATURES MAY CAUSE CONTAINERS TO BURST & LIBERATE TOXIC OXIDES OF NITROGEN. Hazardous Decomposition Products:WILL RELEASE TOXIC NITROGREN OXIDE FUMES & VAPORS. ==================== Disposal Considerations ==================== Waste Disposal Methods:DISPOSAL MUST BE IN ACCORDANCE WITH FEDERAL, STATE & LOCAL REGULATIONS . CONTACT LOCAL HAZARDOUS OR CHEMICAL WASTE DISPOSAL AGENCY FOR REGULATIONS.
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:308 LIME CAGE:HO829 CAGE:84021 CAGE:HO829 ============= Composition/Information on Ingredients ============= Ingred Name:MANGANESE (SARA 313) CAS:7439-96-5 RTECS #:OO9275000 Fraction by Wt: 2% OSHA PEL:C 5 MG/M3 DUST ACGIH TLV:5 MG/M3 DUST Ingred Name:NICKEL (SARA 313) (CERCLA) CAS:7440-02-0 RTECS #:QR5950000 Fraction by Wt: 7-9% OSHA PEL:1 MG/M3 ACGIH TLV:1 MG/M3 Ingred Name:CHROMIUM (SARA 313) (CERCLA) CAS:7440-47-3 RTECS #:GB4200000 Fraction by Wt: 15-17% OSHA PEL:1 MG/M3 ACGIH TLV:0.5 MG/M3 EPA Rpt Qty:1 LB DOT Rpt Qty:1 LB Ingred Name:CALCIUM FLUORIDE (AS F); (CAF2) CAS:7789-75-5 RTECS #:EW1760000 OSHA PEL:2.5 MG/M3 (MFR) ACGIH TLV:2.5 MG/M3 (MFR) Ingred Name:CALCIUM CARBONATE; (CACO3) CAS:1317-65-3 RTECS #:EV9580000 OSHA PEL:15 MG/M3 TDUST ACGIH TLV:10 MG/M3 TDUST Ingred Name:SILICA, CRYSTALLINE - QUARTZ; (SIO2) CAS:14808-60-7 RTECS #:VV7330000 OSHA PEL:SEE TABLE Z-3 ACGIH TLV:0.1 MG/M3 RDUST Ingred Name:SILICON; (SI) CAS:7440-21-3 RTECS #:VW0400000 OSHA PEL:15 MG/M3 TDUST ACGIH TLV:10 MG/M3 TDUST Ingred Name:SILICIC ACID (H2SIO3), DISODIUM SALT CAS:6834-92-0 RTECS #:VV9275000 OSHA PEL:5 MG/M3 (MFR) ACGIH TLV:10 MG/M3 (MFR) Ingred Name:SILICATE BINDERS CAS:10006-28-7 OSHA PEL:5 MG/M3 (MFR) ACGIH TLV:10 MG/M3 (MFR) Ingred Name:IRON CAS:7439-89-6 RTECS #:NO4565500 OSHA PEL:10 MG/M3 (MFR) ACGIH TLV:5 MG/M3 (MFR) Ingred Name:HAZ DECOMP PROD: VOLAT, RXN/OXIDATION OF INGS, PLUS THOSE FROM MATL BEING WORKED & COATINGS ETC, NOTED ABOVE. (ING 12) RTECS #:9999999ZZ Ingred Name:ING 11: REASONABLY EXPECTED DECOMP PRODS FROM NORM USE OF THESE PRODS INCL COMPLEX OF OXIDES & FLUORIDES OF (ING 13) RTECS #:9999999ZZ Ingred Name:ING 12: MATLS LISTED IN INGS SECTION, AS WELL AS CARBON MONOXIDE & DIOXIDE, OZONE & NITROGEN OXIDES. THE ONLY (ING 14) RTECS #:9999999ZZ Ingred Name:ING 13: WAY TO DETERMINE TRUE IDENTITY OF DECOMP PRODS IS BY SAMPLING & ANALYSIS. CONT NEHC FOR MORE INFO . RTECS #:9999999ZZ Ingred Name:EXPLAN OF CARCIN: SILICA, CRYSTALLINE-QUARTZ: IARC MONOGRAPHS, VOLUME 68, 1997: GROUP 1. NTP 7TH ANNUAL REPORT (ING 16) RTECS #:9999999ZZ Ingred Name:ING 15: ON CARCINOGENS, 1994: ANTICIPATED TO BE CARCINOGEN. HUMAN: LUNG. RTECS #:9999999ZZ Ingred Name:EFTS OF OVEREXP: CHEST PAIN. CHROMIUM/CHROMATE IN FUME CAN CAUSE IRRIT OF NASAL MEMB & SKIN. NICKEL CMPDS IN (ING 18) RTECS #:9999999ZZ Ingred Name:ING 17: FUME CAN CAUSE METALLIC TASTE, NAUS, TIGHTNESS OF CHEST, FEVER & ALLERGIC RXN. CHRONIC OVEREXP TO AIR (ING 19) RTECS #:9999999ZZ Ingred Name:ING 18: CONTAMINANTS MAY LEAD TO THEIR ACCUM IN LUNGS, A CNDTN WHICH MAY BE SEEN AS DENSE AREAS ON CHEST X-RAYS.(ING 20) RTECS #:9999999ZZ Ingred Name:ING 19: SEV OF CHANGES IS PROPORTIONAL TO LENGTH OF EXPOS. CHANGES SEEN ARE NOT NEC ASSOC W/SYMPS/SIGNS OF (ING 21) RTECS #:9999999ZZ Ingred Name:ING 20: REDUCED LUNG FUNC/DISEASE. IN ADDN, CHANGES ON X-RAYS MAY BE CAUSED BY NON-WORK FACTORS SUCH AS SMKNG, (ING 22) RTECS #:9999999ZZ Ingred Name:ING 21: ETC. NICKEL & CHROMIUM ARE CONSIDERED CARCIN. LONG TERM OVEREXP TO NICKEL FUMES MAY ALSO CAUSE PULM (ING 23) RTECS #:9999999ZZ Ingred Name:ING 22: FIBROSIS & EDEMA. OVEREXP TO MANGANESE CMPDS MAY AFFECT CNS, SYMPS OF WHICH ARE LANGUOR, SLEEPINESS, (ING 24) RTECS #:9999999ZZ Ingred Name:ING 23: MUSCULAR WEAKNESS, EMOTIONAL DISTURBANCES AND SPASTIC GAIT. RTECS #:9999999ZZ Ingred Name:FIRST AID PROC: INGEST: CALL MD IMMED . SKIN: FLUSH WITH COPIOUS AMOUNTS OF WATER. SEE MD . RTECS #:9999999ZZ ===================== Hazards Identification ===================== LD50 LC50 Mixture:NONE SPECIFIED BY MANUFACTURER. Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES Reports of Carcinogenicity:NTP:YES IARC:YES OSHA:NO Health Hazards Acute and Chronic:ELEC ARC WORKING MAY CREATE ONE/MORE OF THE FOLLOWING HLTH/PHYSICAL HAZS. FUMES & GASES CAN BE DANGEROUS TO YOUR HLTH. ELEC SHOCK CAN KILL. ARC RAYS CAN INJURE EYES & BURN SKIN. NOISE CAN DMG HEARING. WHEN THESE PRODS ARE USED AS REC BY MFR, & VENT MAINTAINS EXPOS TO DECOMP PRODS BELOW LIMITS REC, (EFTS OF OVEREXP) Explanation of Carcinogenicity:NICKEL: IARC MONO, VOL 49, PG 257, 1990: GROUP 2B. NTP 7TH ANNUAL RPT ON CARCINS, 1994: ANTIC TO BE CARCIN. (ING 15) Effects of Overexposure:HLTH HAZ: OVEREXP IS UNLIKELY. ACUTE OVEREXP TO GASES, FUMES & DUSTS MAY INCL IRRIT OF EYES, LUNGS, NOSE & THROAT. SOME TOX GASES ASSOC W/WELDING MAY CAUSE PULM EDEMA, ASPHY & DEATH. ACUTE OVEREXP MAY INCL SIGNS & SYMPS SUCH AS WATERY EYES, NOSE & THROAT IRRIT, HDCH, DIZZ, DFCLTY IN BRTHG, FREQUENT COUGHING, OR(ING 17) Medical Cond Aggravated by Exposure:PERS W/ALLERGIES/IMPAIRED RESP FUNCTION MAY HAVE SYMPS WORSENED BY EXPOS TO WELDING FUMES. HOWEVER, SUCH REACTION CANNOT BE PREDICTED DUE TO VARIATION IN COMPOSITION & QUANTITY OF DECOMPOSITION PRODS. ======================= First Aid Measures ======================= First Aid:IN CASE OF EMER, CALL FOR MED AID. EMPLOY FIRST AID TECHNIQUES REC BY RED CROSS. INHAL: IF BRTHG IS DFCLT, GIVE OXYGEN & CALL FOR MD. ELEC SHOCK: DISCONNECT & TURN OFF POWER. IF NOT BRTHG, BEGIN ARTF RESP, PREF MOUTH-TO-MOUTH. IF NO DETECTABLE PULSE, BEGIN CPR. IMMED CALL MD. ARC BURN: APPLY COLD, CLEAN COMPRESSES & CALL MD. EYES: FLUSH W/POTABLE WATER FOR AT LEAST 15 MIN. SEE MD . (ING 25) ===================== Fire Fighting Measures ===================== Extinguishing Media:PROD WILL NOT BURN. HOWEVER, WELDING ARCS & SPKS CAN IGNITE COMBUST & FLAM MATLS. USE EXTING MEDIA REC FOR (SUP DAT) Fire Fighting Procedures:WEAR NIOSH APPROVED SCBA AND FULL PROTECTIVE EQUIPMENT . Unusual Fire/Explosion Hazard:AS SHIPPED, THESE PRODUCTS ARE NON-FLAMMABLE, NON-EXPLOSIVE, NON-REACTIVE, AND NON-HAZARDOUS. ONLY THE PACKAGING FOR THIS PRODUCT WILL BURN. ================== Accidental Release Measures ================== Spill Release Procedures:NOT APPLICABLE. Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER. ======================Handling and Storage ====================== Handling and Storage Precautions:TRAIN THE WELDER NOT TO TOUCH LIVE ELECTRICAL PARTS, TO INSULATE HIMSELF FROM WORK AND GROUND, AND TO KEEP HIS HEAD OUT OF FUMES. Other Precautions:READ & UNDERSTAND MFR'S INSTRUCTIONS & PREC LABEL ON PROD. SEE AMERICAN NATL STD Z-49.1, "SFTY IN WELDING & CUTTING", PUBLISHED BY AMERICAN WELDING SOCIETY, & OSHA PUBLICATION 2206 (29CFR 1910). CONTNEHC FOR MORE SPECIFIC INFO . ============= Exposure Controls/Personal Protection ============= Respiratory Protection:USE NIOSH APPROVED RESPIRABLE FUME RESPIRATOR OR AIR SUPPLIED RESPIRATOR WHEN WELDING IN CONFINED SPACE OR WHERE LOCAL EXHAUST OR VENTILATION DOES NOT KEEP EXPOSURE BELOW TLV. Ventilation:USE ENOUGH VENT, LOCAL EXHAUST AT ARC/BOTH, TO KEEP FUMES & GASES BELOW TLV IN WORKER'S BREATHING ZONE & GEN ARC AREA. Other Protective Equipment:ANSI APPROVED EMERGENCY EYEWASH AND DELUGE SHOWER . ARM PROTECTORS, APRONS, HATS, DARK CLOTHING. Work Hygienic Practices:NONE SPECIFIED BY MANUFACTURER. Supplemental Safety and Health EXTING MEDIA: BURNING MATLS & FIRE SITUATION. SEE ANSI Z49.1 "SFTY IN WELDING & CUTTING" & "SAFE PRACT" CODE: SP, PUBLISHED BY AMERICAN WELDING SOCIETY, P.O. BOX 351040, MIAMI, FL 33135, & NFPA 51B "C UTTING & WELDING PROCESSES", PUBLISHED BY NATL FIRE PROT ASSOC, BATTERYMARCH PARK, QUINCY, MA 02269 FOR ADDNL INFO. ================== Physical/Chemical Properties ================== HCC:T6 Appearance and Odor:SOLID STAINLESS STEEL CORE WIRE WITH FLUX COATING, ODORLESS ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES NONE CURRENTLY KNOWN. Stability Condition to Avoid:NONE SPECIFIED BY MANUFACTURER. Hazardous Decomposition Products:WELDING FUMES & GASES CANNOT BE CLASSIFIED SIMPLY. DECOMP PRODS OF NORM OPERATION INCL THOSE ORIGINATING FROM (ING 11) ==================== Disposal Considerations ==================== Waste Disposal Methods:PREVENT WASTE FROM CONTAMINATING SURROUNDING ENVIRONMENT. DISCARD ANY PRODUCT, RESIDUE, DISPOSABLE CONTAINER, OR LINER IN AN ENVIRONMENTALLY ACCEPTABLE MANNER, IN FULL COMPLIANCE WITH FEDERAL, STATE A ND LOCAL REGULATIONS.
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:10950 H303 SS30 HEXANE OPTIMA HPLC PESTICIDE SPECTRANALYZED CAGE:1B464 CAGE:1B464 ============= Composition/Information on Ingredients ============= Ingred Name:3-METHYL PENTANE *97-1* CAS:96-14-0 RTECS #:SA2995500 Fraction by Wt: 4.2% Ingred Name:METHYL CYCLOPENTANE CAS:96-37-7 RTECS #:GY4640000 Fraction by Wt: 9.7% Ingred Name:HEXANE, N-HEXANE *97-1* CAS:110-54-3 RTECS #:MN9275000 Fraction by Wt: 86.1% Other REC Limits:50 PPM OSHA PEL:1800 MG/CUM ACGIH TLV:176 MG/CUM EPA Rpt Qty:1 LB DOT Rpt Qty:1 LB Ingred Name:N-(P-PHENYLAZOPHENYL)MALEIMIDE CAS:16201-96-0 ===================== Hazards Identification ===================== Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:EYES: IRRITATION. SKIN: MAY BE ABSORBED IN HARMFUL AMOUNTS. INGESTION: ASPIRATION CAUSES ASPHYXIA, BRAIN DAMAGE & CARDIAC ARREST. MAY ALSO CAUSE GI IRRITATION & CARDIAC SENSITIZATION. INHALATION: CNS DEPRESSION. PROLONGED/REPEATED EXPOSUREMAY CAUSE ADVERSE REPRODUCTIVE EFFECTS. MAY ALSO CAUSE MUSCLE DAMAGE. Explanation of Carcinogenicity:NONE Effects of Overexposure:IRRITATION, TEARING, BURNING PAIN, REDNESS, BLISTERING, NAUSEA, VOMITING, DIARRHEA, VERTIGO, HALLUCINATIONS, FATIGUE, MUSCLE WEAKNESS, VISUAL DISTURBANCES & ABNORMALITIES, NERVOUS SYSTEM DISTURBANCES, MOTOR INCOORDINATION, SENSATION DISTURBANCES. ======================= First Aid Measures ======================= First Aid:EYES: FLUSH W/PLENTY OF WATER FOR 15 MINS. DON'T ALLOW VICTIM TO RUB/KEEP EYES CLOSED. SKIN: RINSE AREA W/LARGE AMOUNTS OF WATER FOR 15 MINS. INGESTION: DON'T INDUCE VOMITING. ASPIRATION HAZARD. IF CO NSCIOUS, GIVE 2-4 CUPFULLS OF MILK/WATER. INHALATION: REMOVE TO FRESH AIR. GIVE CPR/OXYGEN IF NEEDED. OBTAIN MEDICAL ATTENTION IN ALL CASES. NOTES TO PHYSICIAN: NO SPECIFIC ANTIDOTE EXISTS. (SUPP) ===================== Fire Fighting Measures ===================== Lower Limits:1.2 Upper Limits:7.7 Extinguishing Media:SMALL: WATER SPRAY, DRY CHEMICAL, CO2, CHEMICAL FOAM. Fire Fighting Procedures:WEAR A NIOSH/MSHA APPROVED SCBA IN PRESSURE-DEMAND & FULL PROTECTIVE GEAR. USE WATER SPRAY TO KEEP FIRE-EXPOSED CONTAINERS COOL. Unusual Fire/Explosion Hazard:VAPORS MAY TRAVEL TO IGNITION SOURCE & FLASH BACK. MATERIAL WILL READILY IGNITE AT ROOM TEMP. CONTAINERS MAY EXPLODE IN HEAT OF A FIRE. ================== Accidental Release Measures ================== Spill Release Procedures:WEAR A SCBA & APPROPRIATE PERSONAL PROTECTION. SCOOP UP W/A NON-SPARKING TOOL, THEN PLACE INTO A SUITABLE CONTAINER FOR DISPOSAL. REMOVE IGNITION SOURCES. ABSORB W/ABSORBENT, NON-COMBUSTIBLE MATERIAL SUCH AS EARTH, SAND/VERMICULITE. ======================Handling and Storage ====================== Handling and Storage Precautions:KEEP AWAY FROM IGNITION SOURCES. STORE IN A COOL, DRY, WELL VENTILATED AREA AWAY FROM INCOMPATIBLE SUBSTANCES. USE ONLY IN WELL VENTILATED AREA. Other Precautions:GROUND & BOND CONTAINERS WHEN TRANSFERRING MATERIAL. USE SPARK-PROOF TOOLS & EXPLOSION PROOF EQUIPMENT. EMPTY CONTAINERS RETAIN PRODUCT RESIDUE & CAN BE DANGEROUS. DON'T PRESSURIZE, CUT, WELD, BRAZE, SOLDER, DRILL, GRIND/EXPOSE (SUPP) ============= Exposure Controls/Personal Protection ============= Respiratory Protection:ALWAYS USE A NIOSH APPROVED RESPIRATOR WHEN NECESSARY. Ventilation:USE EXPLOSION-PROOF EQUIPMENT. USE ADEQUATE GENERAL/LOCAL EXHAUST TO KEEP AIRBORNE CONCENTRATIONS <PELS. Other Protective Equipment:IMPERVIOUS APRON, APPROPRIATE PROTECTIVE CLOTHING Work Hygienic Practices:REMOVE/LAUNDER CONTAMINATED CLOTHING & SHOES BEFORE REUSE. WASH THOROUGHLY AFTER HANDLING. Supplemental Safety and Health FIRST AID: TREAT SYMPTOMATICALLY & SUPPORTIVELY. OTHER PRECAUTIONS: SUCH CONTAINERS TO HEAT, SPARKS/OPEN FLAMES. AVOID CONTACT W/HEAT, SPARKS & FLAME. DON'T GET ON SKIN/IN EYES. DON'T INGEST/INHALE. ================== Physical/Chemical Properties ================== Vapor Pres:5.2 Vapor Density:3 pH:7 Evaporation Rate & Reference:(N-BU AC =1): 0.3 Appearance and Odor:LIQUID W/MILD GASOLINE TYPE ODOR. ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES OXYGEN & STRONG OXIDIZING AGENTS. Stability Condition to Avoid:EXCESS HEAT, FIRE & OTHER IGNITION SOURCES. Hazardous Decomposition Products:OXIDES OF CARBON. ==================== Disposal Considerations ==================== Waste Disposal Methods:DISPOSE OF IAW/FEDERAL, STATE & LOCAL REGULATIONS. UN1208.
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:MODERN PINK Preparer's Name:CHERYL ZIMMERMAN CAGE:GO327 CAGE:95551 CAGE:GO327 ============= Composition/Information on Ingredients ============= Ingred Name:NON-HAZARDOUS INGREDIENTS ===================== Hazards Identification ===================== Routes of Entry: Inhalation:NOSkin:NO Ingestion:NO Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:NONE Explanation of Carcinogenicity:NONE Effects of Overexposure:NONE Medical Cond Aggravated by Exposure:NONE ======================= First Aid Measures ======================= First Aid:SKIN: TREAT AS A MINOR BURN. OBTAIN MEDICAL ATTENTION IN ALL CASES. ===================== Fire Fighting Measures ===================== Flash Point Method:COC Flash Point:>400F Extinguishing Media:FOAM, DRY CHEMICAL, WATER, CO2, SAND Fire Fighting Procedures:DON'T USE WATER. WEAR SCBA. Unusual Fire/Explosion Hazard:WHEN HEATING WAX, PARAFFIN WAX FUMES MAY BE PRESENT. ======================Handling and Storage ====================== Handling and Storage Precautions:STORE IN COOL TEMP. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:NONE REQUIRED Ventilation:NONE Other Protective Equipment:NONE Work Hygienic Practices:NONE Supplemental Safety and Health ================== Physical/Chemical Properties ================== Vapor Pres:NONE Vapor Density:NONE Spec Gravity:0.9 Evaporation Rate & Reference:NONE Solubility in Water:NONE Appearance and Odor:WAX OF VARIOUS COLOR & SHAPES ODORLESS/SLIGHT SPEARMINT FLAVOR Percent Volatiles by Volume:NONE ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES NONE Stability Condition to Avoid:NONE Hazardous Decomposition Products:NONE Conditions to Avoid Polymerization:HIGH TEMPS ==================== Disposal Considerations ==================== Waste Disposal Methods:DISPOSE OF AS NORMAL SOLID WASTE IAW/FEDERAL, STATE & LOCAL REGULATIONS.
0
eyes_protection_not_mandatory
===================== Product Identification ===================== Product ID:METHYL ALCOHOL 14280, A412SS-11 CAGE:1B464 CAGE:1B464 ============= Composition/Information on Ingredients ============= Ingred Name:METHANOL; (METHYL ALCOHOL) (SARA 313) (CERCLA). LD50:(ORAL,RAT) 5628 MG/KG. CAS:67-56-1 RTECS #:PC1400000 Fraction by Wt: >99% OSHA PEL:200 PPM, S ACGIH TLV:200 PPM;250 STEL, S EPA Rpt Qty:5000 LBS DOT Rpt Qty:5000 LBS Ingred Name:SUPDAT:INCOMPAT W/SPECIFIC CHEMS INCL:ACETYL BROMIDE, ALKYL ALUMINUM SALTS, BERYLLIUM DIHYDRIDE, CARBON (ING 3) RTECS #:9999999ZZ Ingred Name:ING 2:TETRACHLORIDE + METALS, CHLOROFORM + HEAT, CHLOROFORM + SODIUM HYDROXIDE, CYANURIC CHLORIDE, DIETHYL ZINC, (ING 4) RTECS #:9999999ZZ Ingred Name:ING 3:NITRIC ACID & POTASSIUM TERTBUTOXIDE. PLEASE REFER TO NFPA FIRE PROTECTION GUIDE FOR ALL SPECIFICS. RTECS #:9999999ZZ Ingred Name:EFTS OF OVEREXP:CHRONIC:PRLNG/RPTD SKIN CONT MAY CAUSE DERM. CHRONIC INHAL & INGEST MAY CAUSE EFTS SIMILAR TO (ING 6) RTECS #:9999999ZZ Ingred Name:ING 5:THOSE OF ACUTE INHAL & INGEST. TARGET ORGS:KIDNEYS, CNS, LIVER, EYES. TOX INFO:EFTS ON NEWBORN:BEHAVIORAL; (ING 7) RTECS #:9999999ZZ Ingred Name:ING 6:EMBRYO/FETUS:FETOTOXICITY; SPECIFIC DEVEL ABNORMS:CVS, MUSCULOSKELETAL, UROGENITAL; PATERNAL EFTS: (ING 8) RTECS #:9999999ZZ Ingred Name:ING 7:SPERMATOGENESIS; DNA DAMAGE; DNA INHIBITOR. RTECS #:9999999ZZ Ingred Name:FIRST AID PROC:TSP OF SYRUP OF IPECAC. INHAL:GET MED AID IMMED. REMOVE FROM EXPOS TO FRESH AIR IMMED. IF NOT (ING 10) RTECS #:9999999ZZ Ingred Name:ING 9:BRTHG, GIVE ARTF RESP. IF BRTHG IS DFCLT, GIVE OXYG. NOTES TO MD:EFTS MAY BE DELAYED. ETHANOL MAY INHIBIT (ING 11) RTECS #:9999999ZZ Ingred Name:ING 10:METABOLISM. ANTIDOTE:NO SPECIFIC ANTIDOTE EXISTS. RTECS #:9999999ZZ Ingred Name:OTHER PREC:STORAGE AREA. HARMFUL IF INHALED. POISON-CANNOT BE MADE NON-POISONOUS. KEEP OUT OF REACH OF CHILDREN.(ING 13) RTECS #:9999999ZZ Ingred Name:ING 12:IN CASE OF ACCIDENT/IF YOU FEEL UNWELL, SEEK MED ADVICE IMMED (SHOW LBL WHERE POSS). KEEP CNTNR TIGHTLY CLOSED. RTECS #:9999999ZZ ===================== Hazards Identification ===================== LD50 LC50 Mixture:SEE INGREDIENT 1. Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:ACUTE:EYE:CAUSES MOD IRRIT. VAPS MAY CAUSE IRRIT. MAY CAUSE PAINFUL SENSIT TO LIGHT. SKIN:MAY CAUSE IRRIT. MAY BE ABSORBED IN HARMFUL AMTS. INGEST:MAY CAUSE IRRIT OF DIGEST TRACT. MAY CAUSE CNS DEPRES S, CHARACT BY EXCITEMENT, FOLLOWED BY HDCH, DIZZ, DROW & NAUS. ADVANCED STAGES MAY CAUSE COLLAPSE, (EFTS OF OVEREXP) Explanation of Carcinogenicity:NOT RELEVANT Effects of Overexposure:HLTH HAZ:UNCON, COMA & POSS DEATH DUE TO RESP FAILURE. MAY CAUSE KIDNEY FAILURE. INHAL:MAY CAUSE RESP TRACT IRRIT. MAY CAUSE LIVER & KIDNEY DMG. MAY CAUSE ADVERSE CNS EFTS INCL HDCH, CONVLS & POSS DEA TH. MAY CAUSE VISUAL IMPAIRMENT & POSS PERM BLINDNESS. MAY CAUSE EFTS SIMILAR TO THOSE DESCRIBED FOR INGEST. (ING 5) Medical Cond Aggravated by Exposure:NONE SPECIFIED BY MANUFACTURER. ======================= First Aid Measures ======================= First Aid:EYES:FLUSH W/PLENTY OF WATER FOR AT LST 15 MINS, OCCAS LIFTING UPPER & LOWER LIDS. GET MED AID IMMED. DO NOT ALLOW VICTIM TO RUB/KEEP EYES CLSD. SKIN:FLUSH W/PLENTY OF SOAP & WATER FOR AT LST 15 MINS WHILE REMOVING CONTAM CLTHG & SHOES. GET MED AID IF IRRIT DEVELS/PERSISTS. INGEST:IF VICTIM IS CONSCIOUS & ALERT, GIVE 2-4 CUPFULS OF MILK/WATER. GET MED AID IMMED. INDUCE VOMIT BY GIVING 1 (ING 9) ===================== Fire Fighting Measures ===================== Flash Point:53.6F,12.0C Lower Limits:6% Upper Limits:31% Extinguishing Media:FOR SMALL FIRES, USE DRY CHEMICAL, CARBON DIOXIDE, WATER SPRAY OR ALCOHOL-RESISTANT FOAM. Fire Fighting Procedures:USE NIOSH APPROVED SCBA & FULL PROTECTIVE EQUIPMENT . USE WATER TO COOL FIRE-EXPOSED CONTAINERS. WATER MAY BE INEFFECTIVE. Unusual Fire/Explosion Hazard:CNTNRS CAN BUILD UP PRESS IF EXPOS TO HEAT &/OR FIRE. VAPS CAN TRAVEL TO SOURCE OF IGNIT & FLASH BACK. DURING FIRE, IRRIT & HIGHLY TOX GASES MAY BE (SUPP DATA) ================== Accidental Release Measures ================== Spill Release Procedures:USE PROPER PPE AS INDICATED IN EXPOS CONTROLS, PERSONAL PROT SECTION. SCOOP UP W/NONSPARKING TOOL, THEN PLACE INTO SUITABLE CNTNR FOR DISP. USE WATER SPRAY TO DISPERSE GAS/VAP. REMOVE ALL SOURCES OF I GNIT. ABSORB SPILL USING ABSORB, NON- (SUPP DATA) Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER. ======================Handling and Storage ====================== Handling and Storage Precautions:USE W/ADEQUATE VENT. EMPTY CONTAINERS RETAIN PRODUCT RESIDUE (LIQUID &/OR VAPOR) & CAN BE DANGEROUS. DO NOT GET ON SKIN/IN EYES. DO NOT INGEST/INHALE. Other Precautions:DO NOT PRESSURIZE, CUT, WELD, BRAZE, SOLDER, DRILL, GRIND/EXPOSE EMPTY CNTNRS TO HEAT, SPKS/OPEN FLAMES. KEEP AWAY FROM SOURCES OF IGNIT-NO SMOKING. STORE IN COOL, DRY, WELL-VENTED AREA AWAY FROM INCO MPAT SUBSTANCES. STORE IN FLAMMS(ING 12) ============= Exposure Controls/Personal Protection ============= Respiratory Protection:FOLLOW OSHA RESPIRATOR REGULATIONS FOUND IN 29 CFR 1910.134. ALWAYS USE A NIOSH APPROVED RESPIRATOR WHEN NECESSARY. Ventilation:USE ADEQUATE GENERAL OR LOCAL EXHAUST VENTILATION TO KEEP AIRBORNE CONCENTRATIONS BELOW PELS. Other Protective Equipment:ANSI APPROVED EYE WASH FOUNTAIN & DELUGE SHOWER . WEAR APPROPRIATE PROTECTIVE CLOTHING TO PREVENT SKIN CONTACT. Work Hygienic Practices:WASH THOROUGHLY AFTER HANDLING. REMOVE CONTAMINATED CLOTHING & WASH BEFORE REUSE. Supplemental Safety and Health EXPLO HAZ:GENERATED BY THERMAL DECOMP/COMBUST. FLAMM LIQ. CAN RELS VAPS THAT FORM EXPLO MIXTS AT TEMPS ABOVE FLASHPOINT. SPILL PROC:COMBUST MATL SUCH AS EARTH, SAND/VERMICULITE. MATLS TO AVOID:SODIUM HYPOCHLORITE), ACTIVE METALS (SUCH AS POTASSIUM & MAGNESIUM). SUBSTANCE IS ALSO (ING 2) ================== Physical/Chemical Properties ================== Boiling Pt:B.P. Text:148F,65C Melt/Freeze Pt:M.P/F.P Text:-144F,-98C Vapor Pres:96 Vapor Density:1.1 Spec Gravity:0.7910 Evaporation Rate & Reference:5.2 (ETHER=1) Solubility in Water:MISCIBLE Appearance and Odor:CLEAR, COLORLESS LIQUID; SLIGHT ALCOHOL-LIKE ODOR. ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES OXIDANTS (SUCH AS BARIUM PERCHLORATE, BROMINE, CHLORINE, HYDROGEN PEROXIDE, LEAD PERCHLORATE, PERCHLORIC ACID, (SUPDAT) Stability Condition to Avoid:HIGH TEMPERATURES, INCOMPATIBLE MATERIALS, IGNITION SOURCES. Hazardous Decomposition Products:CARBON MONOXIDE, CARBON DIOXIDE, FORMALDEHYDE. ==================== Disposal Considerations ==================== Waste Disposal Methods:DISPOSE OF IN A MANNER CONSISTENT W/FEDERAL, STATE & LOCAL REGULATIONS. RCRA WASTE NUMBER:U154 (IGNITABLE WASTE). THIS MATERIAL IS BANNED FROM LAND DISPOSAL ACCORDING TO RCRA.
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:191 9598,MICRO RESIST THINNER CAGE:19139 CAGE:19139 ============= Composition/Information on Ingredients ============= Ingred Name:XYLENES (O-,M-,P- ISOMERS)(SARA III) CAS:1330-20-7 RTECS #:ZE2100000 Fraction by Wt: 92.5% OSHA PEL:100 PPM/150 STEL ACGIH TLV:100 PPM/150STEL;9192 EPA Rpt Qty:1000 LBS DOT Rpt Qty:1000 LBS Ingred Name:NON-AQUEOUS SOLUTION,HAZARD UNKNOWN,UNIDENTIFIED (5-10%) Fraction by Wt: 7.5% ===================== Hazards Identification ===================== Effects of Overexposure:SKIN:REPTD/PROLNGD LIQ CONTCT CAUSES DEFATTNG;EYES:CONTACEW/LIQUID CAUSES IRRITATION*SEE SUPP DATA* ======================= First Aid Measures ======================= First Aid:INH:REMOVE FROM EXPOSURE.GIVE CPR/OXY IF NEEDED & GET MED ATTN;EYES:FLUSH IMMED W/WATER FOR AT LEAST 15 MIN.GET MED HELP;SKIN:FLUSH IMMID W/PLENTY OF WATER FOR 15 MIN.FOR IRRIT GET MED ATTN. ===================== Fire Fighting Measures ===================== Flash Point:84F(29C)-TCC Lower Limits:1.0% Upper Limits:6.0% Extinguishing Media:CO*2,DRY CHEM,DRY FOAM Fire Fighting Procedures:USE SELF-CONTND BRTHG APP;COOL EXPSD CONT W/WATER SPRAY. Unusual Fire/Explosion Hazard:SPILL/RUNOFF MAY CAUSE POLUTION,FIRE/EXPLOSION HAZARD;CONTNRS(EMPTY/FULL)MAY EXPLODE IN HEAT OF FIRE ================== Accidental Release Measures ================== Spill Release Procedures:EVACUATE UNPROTECTED PERSONS.ELIM IGN SOURCES.USE PROTCTV/SAFETY EQUIP.STOP LEAK W/O RISK.PROVIDE VENT.DIKE LG SPILL.PUMP LIQ TOSALVAGE TANK.ABSORB REMAINING LIQ W/ABSRBNG MATL & SHOVEL INTO DRUMS;PER MFR SOAK UP SM SPILL W/ABSRBNT MATL IAWREGS. ======================Handling and Storage ====================== Handling and Storage Precautions:STORE AWAY FROM SOURCE OF IGN.STORE IN COOL,DRY PLACE.KEEP CONTNRS TIGHTLY CLOSED.PROTECT CONTNRS FROM PHYSICALDAMAGE. Other Precautions:AVOID SKIN/EYE CONTACT W/CHEMICAL PRODUCTS.WASH THOROUGHLY AFTER HANDLING. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:AN APRVD ORGANIC VAP RESPIRATOR FOR EMERGENCY USE ONLY Ventilation:LOCAL EXHAUST & MECHANICAL(GENERAL) RECOMMENDED BY MFGR. Other Protective Equipment:AS NECESSARY TO PREVENT SKIN CONTACT. Supplemental Safety and Health *INHALATION EFFECT:PROLONGED EXPOSURE TO HIGH VAP CONC MAY CAUSE ANESTHETIC EFFECT ALONG WITH HEADACHE,DIZZ & NAUSEA;MSDS FM MFR DTD:5/8/78/. ================== Physical/Chemical Properties ================== HCC:F3 Boiling Pt:=140.6C, 285.F Vapor Pres:S Vapor Density:3.6 Spec Gravity:0.890 Solubility in Water:NEGLIGIBLE Appearance and Odor:COLORLESS LIQUID-PETROLEUM ODOR Percent Volatiles by Volume:95% ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES OXIDIZING & CORROSIVE MATERIAL. Stability Condition to Avoid:SOURCE OF IGNITION Hazardous Decomposition Products:BURNING MAY RESULT IN EVOLUTION OF CO & CO*2. ==================== Disposal Considerations ==================== Waste Disposal Methods:KEEP IN COVERED CONTNRS PENDING DISPOSALSHI WASTE MATL IAW DOT TO DISPOSAL/INCINERATING FACILITY.HANDLE/DISPOSE IN FULL COMPLIANCE W/ALL FED,STATE/LOCAL REGS;MFR RECOMMENDS:BURN-TREAT AS ORGANIC SOLVN TS.FED,ST.& LOCAL EFFLUENT TAKE PRECEDENCE.
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:472-091 FILM RINSE ADDITIVE A8015 Preparer's Name:JOHN TAYLOR CAGE:KO389 CAGE:61803 CAGE:6W820 CAGE:KO389 ============= Composition/Information on Ingredients ============= Ingred Name:DIOCTYL SODIUM SULFOSUCCINATE CAS:577-11-7 RTECS #:WN0525000 Fraction by Wt: 7.5% Other REC Limits:NONE SPECIFIED Ingred Name:PROPYLENE GLYCOL CAS:57-55-6 RTECS #:TY2000000 Other REC Limits:NONE SPECIFIED ===================== Hazards Identification ===================== Routes of Entry: Inhalation:NOSkin:YES Ingestion:YES Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:NONE GIVEN BY MANUFACTURER (SUPPLIER). PRODUCT IS A MILD DETERGENT IN AQUEOUS SOLUTION. Explanation of Carcinogenicity:NONE OF THE COMPOUNDS IN THIS PRODUCT IS LISTED BY IARC, NTP, OR OSHA AS A CARCINOGEN. Effects of Overexposure:EYE:MAY CAUSE IRRITATION. SKIN:NONE INHALED:UNLIKELY EXPOSURE.INGESTED: POSSIBLE G/I IRRITATION, NAUSEA. Medical Cond Aggravated by Exposure:NONE GIVEN BY MANUFACTURER (SUPPLIER). ======================= First Aid Measures ======================= First Aid:EYE:FLUSH W/WATER 15 MIN, HOLD LIDS OPEN. SKIN:WASH WITH SOAP & WATER. REMOVE CONTAMINATED CLOTHING AND LAUNDER BEFORE REUSE. INHALED:REMOVE TO FRESH AIR. RESTORE BREATHING IF NECESSARY.INGESTED:D O NOT INDUCE VOMITING. GIVE 2 LARGE GLASSES OF MILK OR WATER AND GET IMMEDIATE MEDICAL CARE. GIVE NOTHING BY MOUTH IF UNCONSCIOUS. IF IRRITATION PERSISTS OR IS SEVERE,SEE A DOCTOR. ===================== Fire Fighting Measures ===================== Flash Point:NON-FLAMMABLE Extinguishing Media:PRODUCT IS NON FLAMMABLE. EXTINGUISH FIRE WITH MEDIA APPROPRIATE FOR SOURCE OF FIRE. Fire Fighting Procedures:WEAR FIRE FIGHTING PROTECTIVE EQUIPMENT AND A FULL FACED SELF CONTAINED BREATHING APPARATUS. COOL FIRE EXPOSED CONTAINERS WITH WATER SPRAY. CONTAIN RUNOFF. Unusual Fire/Explosion Hazard:NONE GIVEN BY MANUFACTURER (SUPPLIER). DGSC-SSH: COMBUSTION OR HEAT OF FIRE MAY PRODUCE HAZARDOUS DECOMPOSITION PRODUCTS AND VAPORS. ================== Accidental Release Measures ================== Spill Release Procedures:WIPE/SOAK UP WITH CLOTH OR PAPER TOWEL OR INERT ABSORBENT. PUT IN DISPOSAL CONTAINER. REMOVE RESIDUE WITH WATER. Neutralizing Agent:NONE ======================Handling and Storage ====================== Handling and Storage Precautions:STORE IN A COOL, DRY, WELL VENTILATED AREA. KEEP CONTAINERS TIGHTLY CLOSED WHEN NOT IN USE. PROTECT CONTAINERS FROM PHYSICAL DAMAGE. Other Precautions:NONE ============= Exposure Controls/Personal Protection ============= Respiratory Protection:RESPIRATOR WILL NOT NORMALLY BE NECESSARY. USE NIOSH/MSHA APPROVED AIR SUPPLIED RESPIRATOR OR RESPIRATOR FOR DUST/MIST IF EXPOSURE IS ABOVE THE TLV/PEL. SEE 29 CFR 1910.134 FOR REGULATIONS PER TAINING TO RESPIRATOR USE. Ventilation:GENERAL ROOM VENTILATION IS NORMALLY ADEQUATE. USE LOCAL EXHAUST IF NECESSARY TO CONTROL EXPOSURE BELOW PEL/TLV. Other Protective Equipment:EYE WASH STATION AND SAFETY SHOWER. INDUSTRIAL-TYPE WORK CLOTHING AND APRON AS REQUIRED. Work Hygienic Practices:USE GOOD CHEMICAL HYGIENE PRACTICE. AVOID UNNECESSARY CONTACT. Supplemental Safety and Health NONE ================== Physical/Chemical Properties ================== HCC:N1 Boiling Pt:B.P. Text:212F,100C Spec Gravity:1.0 pH:UNKNON Solubility in Water:COMPLETE Appearance and Odor:CLEAR COLORLESS LIQUID,NO ODOR ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES NONE GIVEN BY MANUFACTURER (SUPPLIER). Stability Condition to Avoid:NONE GIVEN BY MANUFACTURER (SUPPLIER). Hazardous Decomposition Products:NONE GIVEN BY MANUFACTURER (SUPPLIER). ==================== Disposal Considerations ==================== Waste Disposal Methods:DISPOSE I/A/W ALL FEDERAL, STATE AND LOCAL REGULATIONS. MANUFACTURER SUGGESTS THAT DISPOSAL MAY BE DONE BY
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:L61 S 18 FLAMBOYANT ALUMINUM CAGE:54636 CAGE:54636 ============= Composition/Information on Ingredients ============= Ingred Name:ALIPHATIC NAPHTHA CAS:64742-89-8 Fraction by Wt: 12% Ingred Name:MEDIUM ALIPHATIC NAPHTHA (AROMATIC 100), PARAFFIN-NAPTHANES MINERAL SPIRITS *96-4* CAS:64742-88-7 Fraction by Wt: 2% Other REC Limits:100 PPM OSHA PEL:500 PPM ACGIH TLV:100 PPM Ingred Name:TOLUENE (IARC CARC- GROUP 3) *96-4* CAS:108-88-3 RTECS #:XS5250000 Fraction by Wt: 13% Other REC Limits:375 MG/CUM OSHA PEL:100 PPM ACGIH TLV:100 PPM EPA Rpt Qty:1000 LBS DOT Rpt Qty:1000 LBS Ingred Name:XYLENE, DIMETHYLBENZENE, XYLOL (IARC - GROUP 3) *96-4* CAS:1330-20-7 RTECS #:ZE2100000 Fraction by Wt: 1% Other REC Limits:100 PPM OSHA PEL:100 PPM ACGIH TLV:100 PPM, SKIN EPA Rpt Qty:1000 LBS DOT Rpt Qty:1000 LBS Ingred Name:ISOPROPANOL (ISOPROPYL ALCOHOL), 2-PROPANOL, DIMETHYL CARBINOL(IARC CANCER REVIEW GROUP 3) *96-4* CAS:67-63-0 RTECS #:NT8050000 Fraction by Wt: 12% Other REC Limits:400 PPM OSHA PEL:400 PPM ACGIH TLV:400 PPM Ingred Name:ISOBUTANOL, 2-METHYL-1-PROPANOL, ISOBUTYL ALCOHOL CAS:78-83-1 RTECS #:NP9625000 Fraction by Wt: 5% Other REC Limits:50 PPM OSHA PEL:300 MG/CUM ACGIH TLV:152 MG/CUM EPA Rpt Qty:5000 LBS DOT Rpt Qty:5000 LBS Ingred Name:2-BUTOXYETHANOL (ETHYLENE GLYCOL MONOBUTYL ETHER), BUTYL CELLOSOLVE, BUTYL GLYCOL, GLYCOL ETHER EB *96-4* CAS:111-76-2 RTECS #:KJ8575000 Fraction by Wt: 3% Other REC Limits:25 PPM (SKIN) OSHA PEL:50 PPM (SKIN) ACGIH TLV:25 PPM (SKIN) Ingred Name:METHYL ETHYL KETONE, 2-BUTANONE *96-4* CAS:78-93-3 RTECS #:EL6475000 Fraction by Wt: 11% Other REC Limits:590 MG/CUM OSHA PEL:200 PPM ACGIH TLV:590 MG/CUM EPA Rpt Qty:5000 LBS DOT Rpt Qty:5000 LBS Ingred Name:ISOBUTYL ACETATE CAS:110-19-0 RTECS #:AI4025000 Fraction by Wt: 22% Other REC Limits:150 PPM OSHA PEL:150 PPM ACGIH TLV:713 MG/CUM EPA Rpt Qty:5000 LBS DOT Rpt Qty:5000 LBS ===================== Hazards Identification ===================== Routes of Entry: Inhalation:YES Skin:YES Ingestion:NO Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:IRRITATION OF THE EYES, SKIN & RESPIRATORY SYSTEM. MAY CAUSE NERVOUS SYSTEM DEPRESSION. MAY RESULT IN DEATH. METHYL EHTYL KETONE: MAY INCREASE NERVOUS SYSTEM EFFECTS OF OTHER SOLVENTS. MAY CAUSE ADVER SE EFFECTS TO THE LIVER, URINARY, BLOOD-FORMING, CARDIOVASCULAR & REPRODUCTIVE SYSTEM. Explanation of Carcinogenicity:NONE Effects of Overexposure:IRRITATION, UNCONSCIOUSNESS, HEADACHE, DIZZINESS, NAUSEA, LOSS OF COORDINATION, REDNESS, ITCHING, BURNING, NERVOUS SYSTEM EFFECTS, EFFECTS TO LIVER, URINARY, BLOOD-FORMING, CARDIOVASCULAR & REPRODUCTI VE SYSTEMS. ======================= First Aid Measures ======================= First Aid:INHALATION: REMOVE FROM AREA. REMOVE FROM EXPOSURE. RESTORE BREATHING. KEEP WARM & QUIET. SKIN: WASH THOROUGHLY W/SOAP & WATER. EYES: FLUSH W/LARGE AMOUNTS OF WATER FOR 15 MINS. OBTAIN MEDICAL ATTENTI ON IN ALL CASES. ===================== Fire Fighting Measures ===================== Flash Point Method:PMCC Flash Point:35F Lower Limits:0.9 Upper Limits:12.7 Extinguishing Media:CO2, DRY CHEMICAL, FOAM. Fire Fighting Procedures:FULL PROTECTIVE EQUIPMENT INCLUDING SCBA SHOULD BE USED. WATER SPRAY MAY BE INNEFFECTIVE. IF WATER SPRAY IS USED, FOG NOZZLES ARE PREFFERABLE. (SUPP) Unusual Fire/Explosion Hazard:KEEP CONTAINERS TIGHTLY CLOSED. ISOLATE FROM HEAT, ELECTRICAL EQUIPMENT, SPARKS & OPEN FLAME. CLOSED CONTAINERS DUE TO EXTREME HEAT. (SUPP) ================== Accidental Release Measures ================== Spill Release Procedures:REMOVE ALL SOURCES OF IGNITION. VENTILATE & REMOVE W/INERT ABSORBENT. ======================Handling and Storage ====================== Handling and Storage Precautions:CONTENTS FLAMMABLE.KEEP AWAY FROM HEAT,SPARKS & OPEN FLAME.IF VAPORS STILL EXTIST, KEEP AREA VENTILATED.DON'T SMOKE.EXTINGUISH ALL IGNITION SOURCES. Other Precautions:USE APPROPRIATE BONDING/GROUNDING PROCEDURES. KEEP CONTAINERS CLOSED WHEN NOT IN USE. TRANSFER ONLY TO APPROVED CONTAINERS W/COMPLETE & APPROPRIATE LABELING. DON'T TAKE INTERNALLY. KEEP OUT OF REACH OF CHILDREN. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:IF EXPOSURE CAN'T BE CONTROLLED BELOW APPLICABLE LIMITS BY VENTILATION, WEAR PROPERLY FITTED ORGNAIC VAPOR RESPIRATOR APPROVED BY NIOSH/MSHA. Ventilation:LOCAL EXHAUST PREFERABLE. GENERAL EXHAUST ACCEPTABLE IF EXPOSURE CAN BE MAINTAINED BELOW LIMITS. Work Hygienic Practices:REMOVE/LAUNDER CONTAMINATED CLOTHING BEFORE REUSE. WASH HANDS AFTER USE. Supplemental Safety and Health UNUSUAL FIRE: HOT SURFACES REQUIRE SPECIAL PRECAUTIONS. SPEC FIRE: WATER MAY BE USED TO CLOSED CONTAINERS TO PREVENT PRESSURE BUILDUP & POSSIBLE AUTOIGNITION/EXPLOSION WHEN EXPOSED TO EXTREME HEAT. ================== Physical/Chemical Properties ================== Boiling Pt:B.P. Text:174-395F Vapor Density:>1 Spec Gravity:0.88-1.1 Evaporation Rate & Reference:SLOWER THAN ETHER Percent Volatiles by Volume:64-90 ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES Stability Condition to Avoid:HEAT, SPARKS, OPEN FLAMES Hazardous Decomposition Products:FIRE: CO2, CO, OXIDES OF METAL. ==================== Disposal Considerations ==================== Waste Disposal Methods:MUST BE TESTED FOR IGNITABILITY TO DETERMINE THE APPLICABLE HAZARDOUS WASTE NUMBERS. PRODUCTS CONTAINING LEAD/METHYL ETHYL KETONE MUST BE TESTED FOR EXTRACTABILITY. DISPOSE OF IAW/FEDERAL, STATE & LOC AL REGULATIONS.
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:192 7698 KODAK FLEXICOLOR DEVELOPER, WORKING SOLUTION CAGE:19139 CAGE:19139 CAGE:5K871 ============= Composition/Information on Ingredients ============= Ingred Name:WATER CAS:7732-18-5 RTECS #:ZC0110000 Fraction by Wt: 95 - 99% Other REC Limits:NONE RECOMMENDED OSHA PEL:NOT RELEVANT ACGIH TLV:NOT RELEVANT Ingred Name:POTASSIUM CARBONATE CAS:584-08-7 RTECS #:TS7750000 Fraction by Wt: 1-5% Other REC Limits:NONE RECOMMENDED Ingred Name:POTASSIUM BICARBONATE CAS:298-14-6 Fraction by Wt: <1% Other REC Limits:NONE RECOMMENDED Ingred Name:POTASSIUM SULFITE CAS:10117-38-1 RTECS #:WT3530000 Fraction by Wt: <1% Other REC Limits:NONE RECOMMENDED Ingred Name:4-(N-ETHYL-N-2-HYDROXYETHYL)-2-METHYLPHENYLENEDIAMINE SULFATE CAS:25646-77-9 RTECS #:KJ6477000 Fraction by Wt: <1% Other REC Limits:NONE RECOMMENDED Ingred Name:SODIUM SULFITE CAS:7757-83-7 RTECS #:WE2150000 Fraction by Wt: <1% Other REC Limits:NONE RECOMMENDED ===================== Hazards Identification ===================== Routes of Entry: Inhalation:NOSkin:NO Ingestion:NO Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:INHALATION- EXPECTED TO BE A LOW HAZARD FOR RECOMMENDED HANDLING. EYES- NO SPECIFIC HAZARD KNOWN. MAY CAUSE TRANSIENT IRRITATION. SKIN- MAY CAUSE ALLERGIC SKIN REACTION. INGESTION- EXPECTED TO BE A LO W INGESTION HAZARD. Explanation of Carcinogenicity:NOT CARCINOGENIC. Effects of Overexposure:LOW HAZARD FOR RECOMMENDED HANDLING. Medical Cond Aggravated by Exposure:NONE SPECIFIED BY MANUFACTURER. ======================= First Aid Measures ======================= First Aid:INHALATION- IF SYMPTOMATIC, MOVE TO FRESH AIR. GET MEDICAL ATTENTION IF SYMPTOMS PERSIST. EYES- ANY MATERIAL THAT CONTACTS THE EYE SHOULD BE WASHED OUT IMMEDIATELY WITH WATER. GET MEDICAL ATTENTION IF SYMPTOMS OCCUR. SKIN- REMOVE CONTAMINATED CLOTHING/SHOES. IMMEDIATELY FLUSH WITH PLENTY OF WATER & WASH WITH A NONALKALINE SKIN CLEANER. INGESTION- DRINK 1-2 GLASSES OF WATER. SEEK MEDICAL ATTENTION. ===================== Fire Fighting Measures ===================== Flash Point:NONE Extinguishing Media:USE APPROPRIATE AGENT FOR ADJACENT FIRE. Fire Fighting Procedures:WEAR SELF-CONTAINED BREATHING APPARATUS AND PROTECTIVE CLOTHING. Unusual Fire/Explosion Hazard:NONE ================== Accidental Release Measures ================== Spill Release Procedures:FLUSH TO SEWER WITH LARGE AMOUNTS OF WATER. OTHERWISE, ABSORB SPILL WITH VERMICULITE OR OTHER INERT MATERIAL, THEN PLACE IN A CONTAINER FOR CHEMICAL WASTE. CLEAN SURFACE THOROUGHLY TO REMOVE RESIDUAL CONTAMINATION. Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER. ======================Handling and Storage ====================== Handling and Storage Precautions:KEEP CONTAINER TIGHTLY CLOSED. KEEP AWAY FROM INCOMPATIBLE SUBSTANCES. Other Precautions:NONE SPECIFIED BY MANUFACTURER. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:NONE NORMALLY REQUIRED. Ventilation:GOOD GENERAL VENTILATION (TYPICALLY 10 AIR CHANGES/HR) SHOULD BE USED. VENTILATION RATES SHOULD BE MATCHED TO CONDITIONS Other Protective Equipment:EYE BATH, WASHING FACILITIES, SAFETY SHOWER. Work Hygienic Practices:WASH HANDS THOROUGHLY AFTER HANDLING THIS MATERIAL. Supplemental Safety and Health THIS IS THE WORKING SOLUTION, AND IS NOT HAZARDOUS. ================== Physical/Chemical Properties ================== HCC:N1 Boiling Pt:B.P. Text:>212F,>100C Vapor Pres:18 Vapor Density:0.6 Spec Gravity:1.037 pH:10.0 Solubility in Water:COMPLETE Appearance and Odor:LIQUID, COLORLESS, ODORLESS. Percent Volatiles by Volume:95-100 ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES NONE WITH COMMON MMATERIALS AND CONTAMINANTS WITH WHICH THE MATERIAL MAY REASONABLY COME INTO CONTACT. Stability Condition to Avoid:NONE SPECIFIED BY MANUFACTURER. Hazardous Decomposition Products:NONE. ==================== Disposal Considerations ==================== Waste Disposal Methods:DISCHARGE, TREATMENT, OR DISPOSAL MAY BE SUBJECT TO NATIONAL, STATE OR LOCAL LAWS. FLUSH TO SEWER WITH LARGE AMOUNTS OF WATER.
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:SULFURIC ACID,OIL OF VITRIOL CAGE:NO199 CAGE:84111 CAGE:NO199 ============= Composition/Information on Ingredients ============= Ingred Name:SULFURIC ACID (SARA III) CAS:7664-93-9 RTECS #:WS5600000 Fraction by Wt: 93-99% OSHA PEL:1 MG/M3 ACGIH TLV:1 MG/M3; 9192 EPA Rpt Qty:1000 LBS DOT Rpt Qty:1000 LBS ===================== Hazards Identification ===================== Routes of Entry: Inhalation:YES Skin:NO Ingestion:YES Health Hazards Acute and Chronic:CONTACT MAY CAUSE PERMANENT DAMAGE TO EYES,SEVERE BURNS AND ULCERATION OF SKIN. INHALATION:CAUSES UPPER RESPIRATORY IRRITATION AND POSSIBLE PULMONARY EDEMA; INGESTION:CAUSES SEVERE INJURIES. Effects of Overexposure:SEE HEALTH HAZARDS. Medical Cond Aggravated by Exposure:RESPIRATORY CONDITIONS WILL BE AGGRAVATED BY BREATHING ACID MISTS. ======================= First Aid Measures ======================= First Aid:EYES/SKIN:FLUSH WITH WATER.SEE DOCTOR IMMEDIATELY.REMOVE CONTAMINATED CLOTHING.INGESTION:GIVE MILK OR WATER,FOLLOWED BY 2 OZ MILK OF MAGNESIA (NO CARBONATES),SEE DOCTOR IMMEDIATELY.INHALATION:REMOVE T O FRESH AIR.GIVE CPR/OXYGEN IF NEEDED.SEE DOCTOR. ===================== Fire Fighting Measures ===================== Lower Limits:4(HYDROGEN) Upper Limits:74(HYDROGEN) Extinguishing Media:CLASS ABC EXTINGUISHER,CO*2,HALON Fire Fighting Procedures:WEAR SCBA,FACE SHIELD,FULL PROTECTIVE CLOTHING. COOL EXTERIOR OF BATTERY TO PREVENT RUPTURE. Unusual Fire/Explosion Hazard:BATTERY EMITS HYDROGEN GAS WHICH MAY EXPLODE IF IGNITED. ACID MAY EMIT TOXIC FUMES UNDER FIRE. WATER WILL CAUSE HEAT GENERATION,BOIL OVER & SPLATTER. ================== Accidental Release Measures ================== Spill Release Procedures:COVER WITH SAND & NEUTRALIZE WITH SODA ASH OR QUICKLIME. SCOOP UP & CONTAINERIZE FOR PROPER DISPOSAL. Neutralizing Agent:SODA ASH (SODIUM CARBONATE). QUICKLIME (CALCIUM OXIDE) ======================Handling and Storage ====================== Handling and Storage Precautions:STROE AWAY FROM IGNITION SOURCES & COMBUSTIBLE MATERIAL. AVOID CONTACT WITH ORGANIC MATERIAL. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:NONE NORMALLY REQUIRED. NIOSH APPROVED CARTRIDGE RESPIRATOR FOR ACIDS OR FULL FACE MASK IF REQUIRED. Ventilation:GENERAL (MECHANICAL) VENTILATION. LOCAL EXHAUST IN CONFINED AREAS. Other Protective Equipment:RUBBER APRON & BOOTS. EYE WASH STATION & SAFETY SHOWER. Work Hygienic Practices:WASH THOROUGHLY AFTER HANDLING. Supplemental Safety and Health ================== Physical/Chemical Properties ================== HCC:C1 Boiling Pt:B.P. Text:278F(136C) Vapor Pres:NEGLIGIBLE Spec Gravity:1.84 (96%) pH:0.9 Solubility in Water:COMPLETE Appearance and Odor:OILY,COLORLESS TO SLIGHTLY YELLOW,CLEAR TO TURBID LIQUID. ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES BASES,OXIDIZERS,REDUCING AGENTS,METAL POWDERS,ORGANIC MATERIAL. Stability Condition to Avoid:HEAT. PROLONGED OVERCHARGING IN CONFINED SPACES. Hazardous Decomposition Products:SO*2,SO*3 ==================== Disposal Considerations ==================== Waste Disposal Methods:DISPOSE OF IAW FEDERAL,STATE & LOCAL REGULATIONS.
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:ISOPROPYL ALCOHOL CAGE:IO736 CAGE:0A9L8 CAGE:36131 CAGE:IO736 ============= Composition/Information on Ingredients ============= Ingred Name:ISOPROPYL ALCOHOL (SARA 313) CAS:67-63-0 RTECS #:NT8050000 Fraction by Wt: 100% Other REC Limits:NONE RECOMMENDED OSHA PEL:400 PPM ACGIH TLV:400 PPM/500STEL;9596 ===================== Hazards Identification ===================== LD50 LC50 Mixture:ORAL (LD50, RAT) >4,720 MG/KG Routes of Entry: Inhalation:YES Skin:NO Ingestion:YES Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:TARGET ORGANS: EYES, SKIN, CNS, RESPIRATORY & GI TRACTS. ACUTE- HARMFUL IF INHALED/INGESTED. MAY CAUSE CNS DEPRESSION. MAY CAUSE EYE IRRITATION. PROLONGED/REPEATED SKIN CONTACT MAY CAUSE DEFATTING, IR RITATION & BURNING SENSATION. INGESTIONMAY CAUSE GASTROINTESTINAL TRACT IRRITATION. CHRONIC- MAY CAUSE DERMATITIS. Explanation of Carcinogenicity:NONE Effects of Overexposure:IRRITATION, HEADACHE, DIZZINESS, DROWSINESS, NAUSEA, VOMITING, TEARING, DEFATTING OF SKIN, CRACKING, BURNING SENSATION, PAIN, DERMATITIS, UNCONSCIOUSNESS Medical Cond Aggravated by Exposure:PERSONS WITH PRE-EXISTING SKIN DISORDERS, EYE PROBLEMS OR IMPAIRED RESPIRATORY FUNCTION MAY BE MORE SUSCEPTIBLE TO THE EFFECTS OF THIS PRODUCT. ======================= First Aid Measures ======================= First Aid:GET MEDICAL HELP IF SYMPTOMS PERSIST. INHALED: REMOVE TO FRESH AIR. PROVIDE CPR/OXYGEN IF NEEDED. EYES: IMMEDIATELY FLUSH WITH WATER FOR 15 MINUTES. HOLD EYELIDS OPEN. SKIN: WASH WITH PLENTY OF SOAP & WATER. ORAL: DO NOT INDUCE VOMITING. IF CONSCIOUS, DRINK WATER. SEEK IMMEDIATE MEDICAL ATTENTION. IF VOMITING OCCURS, KEEP HEAD BELOW HIPS. DO NOT GIVE ANYTHING BY MOUTH TO AN UNCONSCIOUS PERSON. ===================== Fire Fighting Measures ===================== Flash Point Method:TCC Flash Point:57.2F,14.0C Lower Limits:2.0 Upper Limits:12.0 Extinguishing Media:USE WATER FOG, CARBON DIOXIDE, ALCOHOL FOAM, OR DRY CHEMICAL. COOL FIRE EXPOSED CONTAINERS WITH WATER SPRAY. Fire Fighting Procedures:WEAR FULL PROTECTIVE CLOTHING AND NIOSH-APPROVED SELF-CONTAINED BREATHING APPARATUS WITH FULL FACEPIECE OPERATED IN POSITIVE PRESSURE MODE. Unusual Fire/Explosion Hazard:VAPOR IS HEAVIER THAN AIR AND CAN TRAVEL CONSIDERABLE DISTANCE TO A SOURCE OF IGNITION AND FLASH BACK. CONTAINERS MAY RUPTURE DUE TO VAPOR PRESSURE BUILDUP. ================== Accidental Release Measures ================== Spill Release Procedures:WEAR PROTECTIVE EQUIPMENT. ELIMINATE SOURCES OF IGNITION. VENTILATE AREA. REMOVE SPILL WITH NON-FLAMMABLE ABSORBENT SUCH AS SAND. PLACE IN CONTAINER FOR DISPOSAL. PREVENT LIQUID FROM ENTERING SEWERS, WATERWAYS OR LOW AREAS. Neutralizing Agent:DILUTE WITH WATER ======================Handling and Storage ====================== Handling and Storage Precautions:STORE IN TIGHTLY CLOSED CONTAINERS IN A COOL & VENTILATED AREA AWAY FROM INCOMPATIBLES. AVOID EXCESSIVE HEAT. KEEP AWAY FROM SOURCES OF IGNITION. Other Precautions:AVOID BREATHING VAPORS. DO NOT GET IN EYES, ON SKIN OR ON CLOTHING. WASH THOROUGHLY AFTER HANDLING AND BEFORE EATING OR DRINKING. KEEP OUT OF REACH OF CHILDREN. DO NOT INGEST. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:IF TLV IS EXCEEDED OR FOR SYMPTOMS OF OVER EXPOSURE, WEAR NIOSH-APPROVED ORGANIC VAPOR RESPIRATOR OR SUPPLIED AIR RESPIRATOR. IN EMERGENCY, WEAR A NIOSH-APPROVED POSITIVE-PRESSURE SELF-CONTAINED BREAT HING APPARATUS. Ventilation:MECHANICAL (GENERAL AND/OR LOCAL EXHAUST, EXPLOSION-PROOF) VENTILATION TO MAINTAIN EXPOSURE BELOW TLV(S). Other Protective Equipment:EYE WASH STATION & SAFETY SHOWERS SHOULD BE AVAILABLE IN THE IMMEDIATE VICINITY OF ANY POTENTIAL EXPOSURE. Work Hygienic Practices:OBSERVE GOOD INDUSTRIAL HYGIENE PRACTICES AND RECOMMENDED PROCEDURES. Supplemental Safety and Health NOTE TO PHYSICIAN: IF SYMPTOMS SUCH AS LOSS OF GAG REFLEX, CONVULSION OR UNCONSCIOUSNESS OCCUR BEFORE VOMITING, GASTRIC LAVAGE WITH A CUFFED ENDOTRACHEAL TUBE SHOULD BE CONSIDERED. ================== Physical/Chemical Properties ================== HCC:F2 NRC/State Lic Num:NOT RELEVANT Boiling Pt:B.P. Text:180F - 181F Melt/Freeze Pt:M.P/F.P Text:-123F/-129F Vapor Pres:>33 @ 68F Vapor Density:2.1 Spec Gravity:0.79 Evaporation Rate & Reference:1.44 (N-BUTYL ACETATE=1) Solubility in Water:COMPLETE Appearance and Odor:CLEAR, COLORLESS LIQUID - ALCOHOL ODOR Percent Volatiles by Volume:100 ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES STRONG OXIDIZING AGENTS, STRONG ACIDS, ALUMINUM AT HIGH TEMPERATURES Stability Condition to Avoid:HIGH HEAT, SUNLIGHT, SPARKS, OPEN FLAMES AND OTHER SOURCES OF IGNITION Hazardous Decomposition Products:MAY EMIT CARBON MONOXIDE, CARBON DIOXIDE. ==================== Disposal Considerations ==================== Waste Disposal Methods:DISPOSE IN AN APPROVED INCINERATOR/CONTRACT WITH LICENSED CHEMICAL WASTE DISPOSAL SERVICE. DISCHARGE, TREATMENT/DISPOSAL IS SUBJECT TO FEDERAL, STATE OR LOCAL LAWS (WASTE CODE D001). WHEN EMPTY, THROU GHLY RINSE CONTAINER WITH WATER BEFORE DISPOSAL.
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:TURP-SUB, 1145 Preparer's Name:J.C.Z. CAGE:FO802 CAGE:FO802 CAGE:9B440 ============= Composition/Information on Ingredients ============= Ingred Name:PINE OIL; (TERPINOL; YARMOR 302 PINE OIL). VP:1 @ 406F. CAS:8002-09-3 RTECS #:TK5100000 Fraction by Wt: <5% OSHA PEL:N/K ACGIH TLV:N/K Ingred Name:VOLATILE ORGANIC COMPOUNDS. %: 6.45 LB/GAL (773 G/L). RTECS #:9999999VO Fraction by Wt: SEE ING Ingred Name:STODDARD SOLVENT; (ALIPHATIC PETROLEUM DISTILLATES). VP:2 @ 68F. CAS:8052-41-3 RTECS #:WJ8925000 Fraction by Wt: 95% OSHA PEL:500 PPM ACGIH TLV:100 PPM ===================== Hazards Identification ===================== LD50 LC50 Mixture:NONE SPECIFIED BY MANUFACTURER. Routes of Entry: Inhalation:YES Skin:NO Ingestion:NO Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:INHAL:MAY CAUSE HEADACHE, INCOORDINATION. SKIN:IRRITANT. MAY CAUSE DRYNESS, CRACKING, ITCHING, DERMATITIS. EYE:IRRITANT. INGEST:CAUSES GASTROINTESTINAL TRACT IRRITATION, VOMITING, DEPRESSION. ACUTE & CHRONIC:ASPIRATION INTO LUNGS MAY CAUSECHEMICAL PNEUMONITIS. HARMFUL/FATAL IF SWALLOWED. DIZZINESS, (EFTS OF OVEREXP) Explanation of Carcinogenicity:NOT RELEVANT Effects of Overexposure:HLTH HAZ:HEADACHE, NAUSEA, UNCONSCIOUSNESS IF INHALED IN LARGE DOSES. Medical Cond Aggravated by Exposure:SOME SKIN CONDITIONS MAY BE AGGRAVATED. ======================= First Aid Measures ======================= First Aid:SKIN:FLUSH W/WATER FOR AT LEAST 15 MINUTES. SEEK MEDICAL ATTENTION IF IRRITATION PERSISTS. EYES:FLUSH W/WATER FOR AT LEAST 15 MINUTES. SEEK MEDICAL ATTENTION IF IRRITATION PERSISTS. INHAL:REMOVE TO FR ESH AIR. RESTORE BREATHING IF NECESSARY. SEEK MEDICAL ATTENTION IF IRRITATION PERSISTS. INGEST:DO NOT INDUCE VOMITING. SEEK IMMEDIATE MEDICAL ATTENTION. ===================== Fire Fighting Measures ===================== Flash Point Method:TCC Flash Point:105F,41C Lower Limits:1% Upper Limits:6% Extinguishing Media:FOAM, CO*2, DRY CHEMICAL. Fire Fighting Procedures:USE NIOSH/MSHA APPROVED SCBA & FULL PROTECTIVE EQUIPMENT . USE WATER ONLY AS A FOG. Unusual Fire/Explosion Hazard:VAPOR-AIR MIXTURES MAY FLASH/EXPLODE IF IGNITED. TREAT AS A COMBUSTIBLE LIQUID. ================== Accidental Release Measures ================== Spill Release Procedures:ELIMINATE ALL SOURCES OF IGNITION. CONTAIN & ABSORB W/INERT MATERIAL. Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER. ======================Handling and Storage ====================== Handling and Storage Precautions:STORE IN A COOL, VENTILATED AREA. KEEP AWAY FROM SPARKS & OPEN FLAMES. KEEP CONTAINER CLOSED WHEN NOT IN USE. Other Precautions:GROUND CONTAINERS WHEN FILLING OR EMPTYING. DO NOT EAT, DRINK OR SMOKE AROUND PRODUCT. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:NIOSH/MSHA APPROVED RESPIRATOR IF TLV IS EXCEEDED. Ventilation:LOCAL EXHAUST IS RECOMMENDED, BUT MECHANICAL EXHAUST IS PREFERRED. Other Protective Equipment:SAFETY SHOWER/EYEBATH. Work Hygienic Practices:WASH HANDS AFTER USE. Supplemental Safety and Health NONE SPECIFIED BY MANUFACTURER. ================== Physical/Chemical Properties ================== Boiling Pt:B.P. Text:>316F,>158C Vapor Pres:SEE INGS Vapor Density:HVR/AIR Spec Gravity:0.8 (H*2O=1) Evaporation Rate & Reference:SLOWER THAN ETHER Solubility in Water:NEGLIGIBLE Appearance and Odor:WATER-WHITE LIQUID; MILD HYDROCARBON ODOR. ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES STRONG OXIDANTS, STRONG ACIDS & BASES. Stability Condition to Avoid:HEAT, SPARKS, OPEN FLAMES. Hazardous Decomposition Products:BURNING MAY PRODUCE CARBON MONOXIDE. ==================== Disposal Considerations ==================== Waste Disposal Methods:DISPOSE OF I/A/W LOCAL, STATE & FEDERAL REGULATIONS.
1
eyes_protection_mandatory
======================================================= Product ID: TANDEM-E PAP Kit Part: Y Cage: FO596 Box: 269006 ======================================================= Preparer Co. when other than Responsible Party Co. ======================================================= Cage: FO596 Assigned Ind: Y Box: 269006 ======================================================= Contractor Summary ======================================================= Cage: 63493 Box: 269006 Cage: FO596 Box: 269006 ======================================================= Ingredients ======================================================= Cas: 26628-22-8 RTECS #: VY8050000 % Wt: 0.1 Other REC Limits: 0.1 PPM ACGIH TLV: C 0.29 MG/CUM EPA Rpt Qty: 1000 LBS DOT Rpt Qty: 1000 LBS ======================================================= Health Hazards Data ======================================================= Route Of Entry Inds - Inhalation: NO Skin: NO Ingestion: NO Carcinogenicity Inds - NTP: NO IARC: NO OSHA: NO Explanation Of Carcinogenicity: NONE First Aid: EYES/SKIN: IMMEDIATELY FLUSH W/COPIOUS AMOUNTS OF WATER. OBTAIN MEDICAL ATTENTION IN ALL CASES. ======================================================= Handling and Disposal ======================================================= Spill Release Procedures: FLUSH DRAINS W/COPIOUS AMOUNTS OF WATER TO PREVENT AZIDE ACCUMULATION. Waste Disposal Methods: DISPOSE OF IN ACCORDANCE W/LOCAL, STATE & FEDERAL REGULATIONS. Handling And Storage Precautions: STORE IN A COOL, DRY PLACE. REFRIGERATE, UNLESS OTHERWISE SPECIFIED IN KIT INSERT. Other Precautions: AZIDE REACTS W/MANY HEAVY METALS SUCH AS LEAD, COPPER, MERCURY, SILVER & GOLD TO FORM EXPLOSIVE COMPOUNDS. ======================================================= Fire and Explosion Hazard Information ======================================================= Extinguishing Media: DRY CHEMICAL Unusual Fire/Explosion Hazard: CONTACT W/COPPER/LEAD DRAIN PIPES MAY RESULT IN THE FORMATION OF POTENTIALLY EXPLOSIVE AZIDE DEPOSITS. ======================================================= Control Measures ======================================================= Other Protective Equipment: LAB COAT Work Hygienic Practices: REMOVE/LAUNDER CONTAMINATED CLOTHING BEFORE REUSE. ======================================================= Physical/Chemical Properties ======================================================= Spec Gravity: 1.85 ======================================================= Reactivity Data ======================================================= Stability Indicator: YES Materials To Avoid: ACIDS, HEAVY METALS; LEAD, COPPER, BROMINE, CARBON DISULFIDE, CHROMYCHLORIDE, DIBROMO MALONITRILE, DIMETHYL SULFATE Hazardous Decomposition Products: SODIUM & OXIDES OF NITROGEN Hazardous Polymerization Indicator: NO ======================================================= Toxicological Information ======================================================= ======================================================= Ecological Information ======================================================= ======================================================= ======================================================= ======================================================= Regulatory Information ======================================================= ======================================================= Other Information ======================================================= ======================================================= HAZCOM Label ======================================================= Product ID: TANDEM-E PAP Cage: FO596 Assigned IND: Y Company Name: HYBRITECH INCORPORATED Street: 11095 TORREYANA ROAD PO Box: 269006 Zipcode: 92126 Label Required IND: Y Date Of Label Review: 12/16/1998 Status Code: C Label Date: 12/16/1998 Origination Code: G Hazard And Precautions: N/K N/K =======================================================
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:145-22 DECORATOR WHITE, PACON SUPREME (SUPP DATA) CAGE:EO376 CAGE:EO376 CAGE:85520 ============= Composition/Information on Ingredients ============= Ingred Name:ETHYLENE GLYCOL (SARA III). PERCENT(WT): 1.92/2.83. CAS:107-21-1 RTECS #:KW2975000 Fraction by Wt: SEE ING OSHA PEL:N/K ACGIH TLV:50 PPM, C EPA Rpt Qty:1 LB DOT Rpt Qty:1 LB Ingred Name:VOLATILE ORGANIC CONTENT: 0.94 - 1.15. RTECS #:9999999VO OSHA PEL:N/K ACGIH TLV:N/K Ingred Name:SUPP DATA: AIR-LINE TYPE RESP OR HOODS. RESP PROT MAY ALSO BE NEC IN ANY LATER MFG OPS IN WHICH THESE PRODS (ING 4) RTECS #:9999999ZZ Ingred Name:ING 3: MAY BECOME AIRBORNE IN THE FORM OF VAPOR OR DUST. RTECS #:9999999ZZ Ingred Name:VENT: APPRVD RESP TO PVNT OVEREXP. PROVIDE GENL DILUTION/LOC EXHAUST VENT IN VOL & PATTERN TO KEEP TLV OF MOST (ING 6) RTECS #:9999999ZZ Ingred Name:ING 5: HAZ INGREDIENT BELOW ACCEPTABLE LIMIT, LEL AT STATED LIMIT & REMOVE DECOMP PRODS DURING WELDING/FLAME(ING 7) RTECS #:9999999ZZ Ingred Name:ING 6: CUTTING ON SURFACES COATED WITH THESE PRODUCTS. RTECS #:9999999ZZ Ingred Name:HNDLG/STOR: PROD CONTAINS PIGMENTS WHICH MAY BECOME DUST NUISANCE WHEN REMOVED BY ABRASIVE BLASTING, SANDING/GRINDING. RTECS #:9999999ZZ OSHA PEL:N/K ACGIH TLV:N/K ===================== Hazards Identification ===================== LD50 LC50 Mixture:NONE SPECIFIED BY MANUFACTURER. Routes of Entry: Inhalation:YES Skin:NO Ingestion:NO Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:REPORTS HAVE ASSOCIATED REPEATED & PROLONGED OCCUP OVEREXPOSURE TO SOLVENTS WITH PERMANENT BRAIN & NERVOUS SYSTEM DAMAGE. INTENTIONAL MISUSE BY DELIBERATELY CONCENTRATING & INHALING THE CONTENTS MAY B E HARMFUL/FATAL. DO NOT BREATHE VAPORS OR SPRAY MIST. WEAR A NIOSH/MSHA APPRVD RESPIRATOR DURING (EFTS OF OVEREXP) Explanation of Carcinogenicity:NOT RELEVANT. Effects of Overexposure:HLTH HAZ: & AFTER APPLICATION UNLESS MONITORING DEMONSTRATES VAPOR/MIST LEVELS ARE BELOW APPLICABLE LIMITS. FOLLOW RESPIRATOR MFR'S DIRECTIONS FOR RESPIRATOR USE. Medical Cond Aggravated by Exposure:NONE SPECIFIED BY MANUFACTURER. ======================= First Aid Measures ======================= First Aid:EYES: FLUSH W/LUKEWARM WATER FOR AT LEAST 15 MINS. SEEK MD IMMED. SKIN: FLUSH W/COPIOUS AMTS OF LUKEWARM WATER. REMOVE CONTAMD CLTHG PROMPTLY. IF IRRIT OCCURS, GET MED ATTN. INHAL: REMOVE EXPOS INDIVI DUAL TO FRESH AIR. CONTACT MD IMMED. INGEST: RINSE MOUTH IMMED. GIVE EXPOSED INDIVIDUALS 6 TO 8 OUNCES OF LIQ(NEVER GIVE ANYTHING BY MOUTH TO AN UNCONSCIOUS PERSON). DO NOT INDUCE VOMITING(SUPP DATA) ===================== Fire Fighting Measures ===================== Flash Point Method:TCC Extinguishing Media:USE MEDIA SUITABLE FOR SURROUNDING FIRE. Fire Fighting Procedures:WEAR NIOSH/MSHA APPROVED SCBA & FULL PROTECTIVE EQUIPMENT. Unusual Fire/Explosion Hazard:CONTAINERS EXPOSED TO INTENSE HEAT FROM FIRES SHOULD BE COOLED WITH WATER TO PREVENT VAPOR PRESSURE BUILDUP WHICH COULD RESULT IN CONTAINER RUPTURE. ================== Accidental Release Measures ================== Spill Release Procedures:DO NOT FLUSH TO SEWER, WATERSHED OR WATERWAY. Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER. ======================Handling and Storage ====================== Handling and Storage Precautions:KEEP FROM FREEZING. DO NOT STORE ABOVE 120F. DO NOT TAKE INTERNALLY. CLOSE CONTAINER AFTER EACH USE. KEEP OUT OF REACH OF CHILDREN. (ING 7) Other Precautions:GROUND CNTNRS WHEN POURING & LIM FREE-FALL TO A FEW INCHES TO PVNT STATIC SPARKS. AVOID SPONT COMBUST OF CONTAMD RAGS/OTHER EASILY IGNIT ORG MATLS BY IMMED IMMERSION IN WATER. EMPTIED CNTNRS MAY CONTA IN HAZ PROPERTIES. DO NOT CUT(SUPP DATA) ============= Exposure Controls/Personal Protection ============= Respiratory Protection:IN OUTDOOR/OPEN AREAS,USE NIOSH/MSHA APPRVD MECH FILTER RESP TO REMOVE SOLID AIRBORNE PARTICLES OF OVERSPRAY DURING SPRAY APPLIC. IN RESTRICTED VENT AREAS, USE NIOSH/MSHA APPRVD CHEM-MECH FILTERS DESI GNED TO REMOVE COMBINATION OF(SUPP DATA) Ventilation:USE VENT AS REQD TO CONTROL VAP CONC. AVOID PRLNG/RPTD BRTHG OF VAPORS. IF EXPOS EXCEEDS TLV, USE A NIOSH/MSHA (ING 5) Other Protective Equipment:NONE SPECIFIED BY MANUFACTURER. Work Hygienic Practices:WASH HANDS THOROUGHLY BEFORE EATING & USING WASHROOM. REMOVE CONTAMINATED CLOTHING & LAUNDER BEFORE REUSE. Supplemental Safety and Health TRADENAME:INTERIOR LATEX SEMI-GLOSS WALL & TRIM ENAMEL. %VOL:64.50 TO 73.49. FIRST AID PROC:UNLESS ADVISED BY MD. CONT MD IMMED. OTHER PRECS:/PUNCTURE CNTNR. DO NOT WELD NEAR CNTNR. KEEP CNTNR TIGHTLY CLSD WHEN NOT IN USE. USE ONLY W/ADEQ VENT. RESP PROT:PARTICULATE, GAS & VAP. IN CONFINED AREAS, USE NIOSH/MSHA (ING 3) ================== Physical/Chemical Properties ================== HCC:N1 Boiling Pt:B.P. Text:>212F,>100C Vapor Pres:17 @ 68F Vapor Density:HVR/AIR Spec Gravity:1.07-1.28 Evaporation Rate & Reference:SLOWER THAN BUTYL ACETATE Appearance and Odor:NONE SPECIFIED BY MANUFACTURER. Percent Volatiles by Volume:SUPDAT ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES THESE PRODUCTS ARE INCOMPATIBLE WITH STRONG ACIDS. Stability Condition to Avoid:NONE SPECIFIED BY MANUFACTURER. Hazardous Decomposition Products:MAY PRDC HAZARDOUS FUMES WHEN HEATED TO DECOMP. FUMES MAY CONTAIN CARBON MONOXIDE, CARBON DIOXIDE & OXIDES OF NITROGEN. ==================== Disposal Considerations ==================== Waste Disposal Methods:DISPOSE OF THESE PRODUCTS IN ACCORDANCE WITH LOCAL, COUNTY, STATE & FEDERAL REGULATIONS.
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:HYDRAULIC OILS 68 CAGE:CSTRL CAGE:CSTRL ============= Composition/Information on Ingredients ============= Ingred Name:MIXTURE OF HIGHLY REFINED MINERAL OILS (CONTAINING ING 2) RTECS #:9999999ZZ OSHA PEL:N/K ACGIH TLV:N/K Ingred Name:ADDITIVES OSHA PEL:N/K ACGIH TLV:N/K ===================== Hazards Identification ===================== LD50 LC50 Mixture:NONE SPECIFIED BY MANUFACTURER. Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:ACUTE:CONTACT MAY CAUSE SKIN & EYE IRRITATION. ELEVATED TEMPERATURES OR MECHANICAL ACTION MAY FORM VAPORS, MISTS OR FUMES WHICH MAY BE IRRITATING TO EYES, NOSE, THROAT & UPPER RESPIRATORY TRACT. CHRON IC:PROLONGED & REPEATED SKIN CONTACT MAY CAUSE VARIOUS FORMS OF DERMATITIS INCLUDING FOLLICULITIS & (EFTS OF OVEREXP) Explanation of Carcinogenicity:NOT RELEVANT Effects of Overexposure:HLTH HAZ:OIL ACNE. LONG TERM INTENSIVE EXPOSURE TO OIL MIST MAY CAUSE BENIGN LUNG FIBROSIS. Medical Cond Aggravated by Exposure:NONE SPECIFIED BY MANUFACTURER. ======================= First Aid Measures ======================= First Aid:EYES:FLUSH IMMEDIATELY W/COPIOUS AMOUNTS OF WATER FOR AT LEAST 15 MINUTES. CONSULT MD IF IRRITATION DEVELOPS. SKIN:REMOVE CONTAMINATED CLOTHING IMMEDIATELY & WASH BEFORE RE-USE. WASH AFFECTED AREAS IM MED W/SOAP & WATER. CONSULT MD IF IRRITDEVELOPS. INGEST:SEEK IMMED MED ATTN. DO NOT INDUCE VOMITING BECAUSE OF RISK OF ASPIR. INHAL:MOVE TO FRESH AIR. IF BRTHG IS DFCLT, GIVE OXYGEN. CONSULT MD. ===================== Fire Fighting Measures ===================== Flash Point Method:COC Flash Point:>370F,>188C Extinguishing Media:CARBON DIOXIDE, DRY POWDER, FOAM, SAND. Fire Fighting Procedures:USE NIOSH/MSHA APPROVED SCBA & FULL PROTECTIVE EQUIPMENT . Unusual Fire/Explosion Hazard:HAZARDOUS COMBUSTION PRODUCTS: OXIDES OF CARBON. ================== Accidental Release Measures ================== Spill Release Procedures:PREVENT ENTRY INTO WATER SOURCES. SOAK UP W/SUITABLE ABSORBENT SUCH AS SAND OR DIATOMACEOUS EARTH. Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER. ======================Handling and Storage ====================== Handling and Storage Precautions:AVOID REPEATED & PROLONGED SKIN CONTACT. PREVENT EYE CONTACT. AVOID BREATHING MISTS/VAPORS. Other Precautions:STORE IN A COOL, DRY WELL VENTILATED AREA, AWAY FROM HEAT & IGNITION SOURCES. KEEP DRUMS & CONTAINERS CLOSED WHEN NOT IN USE. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:NIOSH/MSHA APPROVED RESPIRATOR APPROPRIATE FOR EXPOSURE OF CONCERN . NONE REQUIRED UNDER NORMAL USE. Ventilation:GENERAL VENTILATION & LOCAL EXHAUST RECOMMENDED, ESP AT ELEVATED TEMPS. PREVENT BUILD UP OF MISTS/VAPS IN WORKING ATM. Other Protective Equipment:EYE WASH FOUNTAIN & DELUGE SHOWER WHICH MEET ANSI DESIGN CRITERIA . COVERALL/APRON RECOMMENDED. Work Hygienic Practices:MAINTAIN HIGH STANDARD OF PERSONAL HYGIENE. Supplemental Safety and Health NONE SPECIFIED BY MANUFACTURER. ================== Physical/Chemical Properties ================== Melt/Freeze Pt:M.P/F.P Text:>-13F,>-25C Spec Gravity:0.871-0.882 Solubility in Water:INSOLUBLE Appearance and Odor:CLEAR, AMBER-STRAW COLORED LIQUID; BLAND ODOR. Percent Volatiles by Volume:NIL ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES MAY REACT W/STRONG OXIDIZERS. Stability Condition to Avoid:NONE SPECIFIED BY MANUFACTURER. Hazardous Decomposition Products:FUMES, SMOKE, CARBON MONOXIDE & CARBON DIOXIDE ARE PRODUCED ON COMBUSTION. ==================== Disposal Considerations ==================== Waste Disposal Methods:DISPOSAL MUST BE I/A/W FEDERAL, STATE & LOCAL REGULATIONS . DISPOSE OF IN AN APPROVED INCINERATOR OR USE LICENSED WASTE DISPOSAL FACILITY.
1
eyes_protection_mandatory
======================================================= Product ID: GROUP B 718MC-1 WELDING ELECTRODE AWS A5.1 Cage: 28835 ======================================================= Preparer Co. when other than Responsible Party Co. ======================================================= Cage: 28835 ======================================================= Contractor Summary ======================================================= Cage: 28835 ======================================================= Ingredients ======================================================= Cas: 7789-75-5 RTECS #: EW1760000 % Wt: 1-12 Other REC Limits: 2.5 MG/CUM (AS F) OSHA PEL: 2.5 MG/CUM (AS F) ACGIH TLV: 2.5 MG/CUM (AS F) ------------------------------ Cas: 546-93-0 RTECS #: OM2470000 % Wt: <5 ACGIH TLV: 10 MG/CUM ------------------------------ % Wt: <10 ----------------------------- Cas: 7439-89-6 RTECS #: NO4565500 % Wt: 60-80 ------------------------------ Cas: 7439-96-5 RTECS #: OO9275000 % Wt: 1-5 OSHA PEL: 5 MG/CUM ACGIH TLV: 5 MG/CUM (DUST) ------------------------------ Cas: 1317-65-3 RTECS #: EV9580000 % Wt: 3-10 Other REC Limits: 5 MG/M3 RESP DUST OSHA PEL: 15 MG/M3 ACGIH TLV: 10 MG/CUM TOTAL DUST ------------------------------ Cas: 9004-34-6 RTECS #: FJ5691460 % Wt: <2 OSHA PEL: 5 MG/CUM ACGIH TLV: 10 MG/CUM (DUST) ------------------------------ Cas: 14808-60-7 RTECS #: VV7330000 IARC-GROUP 2A; SUSPECTED CARCINOGEN NTP) *97-1* % Wt: <5 Other REC Limits: 0.05 MG/CUM (NIOSH) OSHA PEL: 10 MG/CUM %RESP SIO2 ACGIH TLV: 0.1 MG/CUM RESP DUST ------------------------------ Cas: 7440-21-3 RTECS #: VW0400000 % Wt: <2 ACGIH TLV: 10 MG/CUM ------------------------------ Cas: 13463-67-7 RTECS #: XR2275000 GROUP 3) *97-1* % Wt: <10 OSHA PEL: 15 MG/CUM ACGIH TLV: 10 MG/CUM (DUST) ======================================================= Health Hazards Data ======================================================= Route Of Entry Inds - Inhalation: YES Skin: YES Ingestion: NO Carcinogenicity Inds - NTP: YES IARC: YES OSHA: NO Effects of Exposure: SHORT TERM EXPOSURE TO WELDING FUMES: DIZZINESS, NAUSEA, DRYNESS/IRRITATION OF NOSE/THROAT/LUNGS/EYES. LONG TERM EXPOSURE TO WELDING FUMES: RESPIRATORY PROBLEMS, IRON BUILD-UP IN THE LUNGS, BONE EROSI ON, REDUCED PULMONARY FUNCTIONS & NERVOUS DISORDERS. Explanation Of Carcinogenicity: SEE INGREDIENTS. Signs And Symptions Of Overexposure: SHORT TERM EXPOSURE TO WELDING FUMES: DIZZINESS, NAUSEA, DRYNESS/IRRITATION OF NOSE/THROAT/LUNGS/EYES. LONG TERM EXPOSURE TO WELDING FUMES: RESPIRATORY PROBLEMS, IRON BUILD-UP IN THE LUNGS, BONE EROSI ON, REDUCED PULOMARY FUNCTIONS & NERVOUS DISORDERS. Medical Cond Aggravated By Exposure: PRE-EXISTING RESPIRATORY/ALLERGIC CONDITONS. First Aid: IF OVERCOME BY SMOKE/FUMES, REMOVE VICTIM TO FRESH AIR & EMPLOY FIRST AID TECHNIQUES RECOMMENDED BY THE RED CROSS. OBTAIN MLATTENTION IN ALL CASES. ======================================================= Handling and Disposal ======================================================= Waste Disposal Methods: PREVENT WASTE FROM CONTAMINATING SURROUNDING ENVIRONMENT. DISCARD ANY PRODUCT, RESIDUE, DISPOSABLE CONTAINER/LINER IN AN ENVIRONMENTALLY ACCEPTABLE MANNER IAW/LOCAL, STATE & FEDERAL REGULATIONS. Handling And Storage Precautions: MONITOR THE AIR TO ENSURE THE LEVELS ARE <THE RECOMMENDED LIMITS. WEAR APPROPRIATE EQUIPMENT TO PREVENT INJURY FROM RADIATION/SPARKS/ELECTRIC SHOCK. Other Precautions: TRAIN WELDER NOT TO TOUCH LIVE ELECTRICAL PARTS & INSULATE THEMSELVES FROM WORK & GROUND. ======================================================= Fire and Explosion Hazard Information ======================================================= Flash Point Text: NON-FLAMMABLE Unusual Fire/Explosion Hazard: WELDING ARC & SPARKS CAN IGNITE COMBUSTIBLE & FLAMMABLE PRODUCTS. ======================================================= Control Measures ======================================================= Respiratory Protection: WEAR RESPIRABLE FUME RESPIRATOR/AIR SUPPLIED RESPIRATOR WHEN WELDING IN CONFINED SPACE, WHERE LOCAL EXHAUST/VENTILATION DOES NOT KEEP EXPOSURE <TLV. Ventilation: LOCAL EXHAUST AT ARC TO KEEP FUMES/GASES <TLV IN WORKERS BREATHING ZONE & GENERAL AREA. Other Protective Equipment: ARM PROTECTOR, APRON, HAT, SHOULDER PROTECTION, DARK SUBSTANTIAL CLOTHING. Supplemental Safety and Health: PRODUCT IS NON-HAZARDOUS UNTIL USED AS IN WELDING PURPOSES. THE COMPOSITION & QUANTITY OF FUMES/GASES DEPENDS ON METAL BEING WELDED, PROCESS, PROCEDURES, ELECTRODES USED, COATINGS, POSITION OF WELDERS HEAD W/RESPECT TO THE PLUME & AS WELL AS THE PRESENCE OF CONTAMINANTS IN THE ATMOSPHERE. ======================================================= Physical/Chemical Properties ======================================================= ======================================================= Reactivity Data ======================================================= Stability Indicator: YES Stability Condition To Avoid: WELDING ARCS & SPARKS CAN IGNITE COMBUSIBLES & FLAMMABLE PRODUCTS. Materials To Avoid: (SEE SUPPLEMENTAL DATA) Hazardous Decomposition Products: OXIDES OF IRON, MANGANESE, SILICON, CHROMIUM, NICKEL, MOLYBDENUM, CALCIUM, MAGNESIUM, TITANIUM (SEE SUPP) Hazardous Polymerization Indicator: NO ======================================================= Toxicological Information ======================================================= ======================================================= Ecological Information ======================================================= ======================================================= ======================================================= ======================================================= Regulatory Information ======================================================= ======================================================= Other Information ======================================================= ======================================================= HAZCOM Label ======================================================= Product ID: GROUP B 718MC-1 WELDING ELECTRODE AWS A5.1 Cage: 28835 Company Name: HOBART BROTHERS CO Street: 600 W MAIN ST HOBART SQUARE Zipcode: 45373 Label Required IND: Y Date Of Label Review: 10/12/1999 Status Code: A Origination Code: G Hazard And Precautions: SHORT TERM EXPOSURE TO WELDING FUMES: DIZZINESS, NAUSEA, DRYNESS/IRRITATION OF NOSE/THROAT/LUNGS/EYES. LONG TERM EXPOSURE TO WELDING FUMES: RESPIRATORY PROBLEMS, IRON BUILD-UP IN THE LUNGS, BONE EROSI ON, REDUCED PULMONARY FUNCTIONS & NERVOUS DISORDERS. =======================================================
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:MIL-C-22750D 10,000 ACTIVATOR PTA, PART 2 O Kit Part:Y CAGE:93981 CAGE:93981 ============= Composition/Information on Ingredients ============= Ingred Name:ISOPROPYL ALCOHOL (SARA III) (VAPOR PRESSURE 30.00 MM HG @ 20C) (LEL 2.00 @ 25 C) CAS:67-63-0 RTECS #:NT8050000 Fraction by Wt: 10-15% Other REC Limits:NONE SPECIFIED OSHA PEL:400 PPM ACGIH TLV:400 PPM/500 PPM STEL Ingred Name:N-BUTYL ACETATE (VAPOR PRESSURE 10.00 MM HG @ 20C) (LEL 1.38 @ 38C) CAS:123-86-4 RTECS #:AF7350000 Fraction by Wt: 20-25% Other REC Limits:NONE SPECIFIED OSHA PEL:150 PPM ACGIH TLV:150 PPM/200 PPM STEL EPA Rpt Qty:5000 LBS DOT Rpt Qty:5000 LBS Ingred Name:ETHYL ACETATE (VAPOR PRESSURE 100.00 MM HG @ 27C) (LEL 2.18 @ 25C) CAS:141-78-6 RTECS #:AH5425000 Fraction by Wt: 10-15% Other REC Limits:NONE SPECIFIED OSHA PEL:400 PPM ACGIH TLV:400 PPM EPA Rpt Qty:5000 LBS DOT Rpt Qty:5000 LBS Ingred Name:TOLUENE (SARA III) CAS:108-88-3 RTECS #:XS5250000 Fraction by Wt: 20-25% Other REC Limits:NONE SPECIFIED OSHA PEL:200 PPM/150 STEL ACGIH TLV:50 PPM; 9293 EPA Rpt Qty:1000 LBS DOT Rpt Qty:1000 LBS Ingred Name:N-BUTYL ACETATE (SARA III) CAS:123-86-4 RTECS #:AF7350000 Fraction by Wt: < 5% % Other REC Limits:NONE SPECIFIED OSHA PEL:150 PPM/200 STEL ACGIH TLV:150 PPM/200STEL;9192 EPA Rpt Qty:5000 LBS DOT Rpt Qty:5000 LBS Ingred Name:2-ETHOXYETHYL ACETATE (CELLOSOLVE ACETATE) (EGEEA) CAS:111-15-9 RTECS #:KK8225000 Fraction by Wt: 11% % Other REC Limits:NONE SPECIFIED OSHA PEL:S,100 PPM ACGIH TLV:S, 5 PPM; 9192 Ingred Name:TOLUENE (SARA III) CAS:108-88-3 RTECS #:XS5250000 Fraction by Wt: < 5% % Other REC Limits:NONE SPECIFIED OSHA PEL:200 PPM/150 STEL ACGIH TLV:50 PPM; 9293 EPA Rpt Qty:1000 LBS DOT Rpt Qty:1000 LBS Ingred Name:XYLENES (O-,M-,P- ISOMERS) (SARA III) CAS:1330-20-7 RTECS #:ZE2100000 Fraction by Wt: 2% % Other REC Limits:NONE SPECIFIED OSHA PEL:100 PPM/150 STEL ACGIH TLV:100 PPM/150STEL;9192 EPA Rpt Qty:1000 LBS DOT Rpt Qty:1000 LBS Ingred Name:METHYL ETHYL KETONE (2-BUTANONE) (MEK) (SARA III) CAS:78-93-3 RTECS #:EL6475000 Fraction by Wt: 8% % Other REC Limits:NONE SPECIFIED OSHA PEL:200 PPM/300 STEL ACGIH TLV:200 PPM/300STEL 9192 EPA Rpt Qty:5000 LBS DOT Rpt Qty:5000 LBS ===================== Hazards Identification ===================== Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES Health Hazards Acute and Chronic:EYE: SEVERE IRRIT, EXTENSIVE CORNEAL INJURY. VAPOR/MIST: IRRIT. PROLONG/REPEATED: DRYING, DEFATTING, DERMATITIS. INHAL: NOSE, THROAT, RESP TRACT, MUCOUS MEMBRANE IRRIT. CONC VAPOR: CENTRL NERV DEPRESS . INGEST: ASPIRATION CAUSE SEVERE LUNG DAMAGE, NERVOUS SYS DEPRESSION. Effects of Overexposure:EYE: PAIN, TEAR, SWELL. SKIN: RED, SWELL, RASH, INHAL: RUNNY NOSE, SORE THROAT, COUGH, CHEST DISCOMFORT, SHORT BREATH, REDUCED LUNG FUNCTION. INGEST: SORE THROAT, ABDOM PAIN, NAUSEA, VOMIT, DIARRHEA, CNS DEPRESSION: HEADACHE, DIZZY, NAUSEA, INTOXICATN SYMPTOMS, UNCONSCIOUSNESS, DEATH. CHRONIC: MEMORY, INTELLECT LOSS Medical Cond Aggravated by Exposure:PREEXISTING SKIN, EYE & RESPIRATORY DISORDERS MAY BE AGGRAVATED BY EXPOSURE TO THIS PRODUCT. IMPAIRED CENTRAL NERVOUS SYSTEM FUNCTIONS FROM PREEXISTING DISORDERS MAY BE AGGRAVATED BY EXPOSURE TO PROD ======================= First Aid Measures ======================= First Aid:EYE: IMMED FLUSH W/WATER 15 MIN HOLD EYELIDS OPEN. GET MED AID. SKIN: REMOVE CONTAM CLOTH/SHOES. WIPE EXCESS FROM SKIN, FLUSH W/WATER & SOAP. GET MED AID, IF IRRIT OCCURS. DON'T REUSE CLOTH. INHAL: GR OSS OVEREXPOS TO NUISANCE DUST MAY CAUSE IRRIT RESP TRACT. INGEST: DON'T INDUCE VOMIT. KEEP HEAD AT HIP LEVEL. ASPIRATN INTO LUNG VERY SERIOUS, PERM DAMAGE. GET MED AID, CALL DR, HOSP, POISON CTRL CTR ===================== Fire Fighting Measures ===================== Flash Point Method:TCC Flash Point:45.0F,7.2C Extinguishing Media:USE WATER FOG, DRY CHEMICAL, OR CARBON DIOXIDE. Fire Fighting Procedures:CLEAR AREA. DON'T ENTER CONFINED FIRE SPACE POSITIVE PRESSURE NIOSH APPROVED SCBA. Unusual Fire/Explosion Hazard:COOL CONTAINERS EXPOSED TO HEAT WITH WATER TO PREVENT PRESSURE BUILD UP OR WEAKENING OF CONTAINER STRUCTURE. ================== Accidental Release Measures ================== Spill Release Procedures:EVACUATE AREA. WEAR RESPIRATOR/PROTECT CLOTHES. STOP LEAK IF SAFE. DIKE/CONTAIN. IF VAPOR CLOUD FORMS, USE WATER FOG TO SUPPRESS. CONTAIN RUNOFF. REMOVE W/VACUUM TRUCK/PUMP TO STORAGE/ SALVAGE TANK. F LUSH AREA W/WATER. USE ABSORB MAT'L. SEAL TIGHTLY. ======================Handling and Storage ====================== Handling and Storage Precautions:KEEP AWAY FROM HEAT/IGNIT SOURCES. EXTINGUISH PILOT LIGHT/CIGS/TURN OFF IGNIT SOURCES PRIOR TO USE/TILL VAPOR GONE. VAPOR MAY TRAVEL TO IGNIT SOURCES. Other Precautions:CONTAINER MAY CONTAIN HAZARDOUS PRODUCT RESIDUE WHEN EMPTY. DON'T CUT, DRILL, GRIND, OR WELD NEAR CONTAINERS. PLACE IN NON- LEAKING CONTAINERS FOR PROPER DISPOSAL. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:IF EXPOSURE EXCEEDS THE PEL/TLV, USE THE APPROPRIATE NIOSH APPROVED RESPIRATOR. Ventilation:VENT AS REQUIRED TO CONTROL VAPOR CONCENTRATIONS-AT LEAST 10 AIR CHANGES PER HOUR ARE RECOMMENDED FOR GENERAL ROOM VENT. Other Protective Equipment:PROTECTIVE CLOTHING TO PREVENT CONTACT WITH SKIN OR CLOTHING. Work Hygienic Practices:EYE WASH FOUNTAINS AND SAFETY SHOWERS SHOULD BE AVAILABLE FOR USE IN AN EMERGENCY. Supplemental Safety and Health KEY1;F3.DO NOT WEAR CONTACTS. ================== Physical/Chemical Properties ================== HCC:F5 Vapor Density:>1 Spec Gravity:7.45 (LB/GL) Evaporation Rate & Reference:<1 (ETHER=1) Percent Volatiles by Volume:72.11 ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES OXIDIZING MATERIALS, STRONG ALKALIES, AMINES, ALKANOLAMINES, CHLORINATED COMPOUNDS, ALDEHYDES. Stability Condition to Avoid:OXIDIZING MATERIALS, STRONG ALKALIES, AMINES, ALKANOLAMINES, CHLORINATED COMPOUNDS, ALDEHYDES. Hazardous Decomposition Products:CARBON DIOXIDE, CARBON MONOXIDE, & UNIDENTIFIED ORGANIC COMPOUNDS MAY BE FORMED DURING COMBUSTION. ==================== Disposal Considerations ==================== Waste Disposal Methods:OBSERVE ALL FEDERAL, STATE AND LOCAL REGULATIONS REGARDING PROPER DISPOSAL.
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:PERCHLOROETHYLENE INDUSTRIAL CAGE:EO044 CAGE:96717 CAGE:EO044 ============= Composition/Information on Ingredients ============= Ingred Name:PERCHLOROETHYLENE (TETRACHLOROETHYLENE) (SARA III) CAS:127-18-4 RTECS #:KX3850000 Fraction by Wt: 99.9% Other REC Limits:50 PPM OSHA PEL:100 PPM ACGIH TLV:25PPM/100,A3 STEL;94 EPA Rpt Qty:100 LBS DOT Rpt Qty:100 LBS ===================== Hazards Identification ===================== LD50 LC50 Mixture:LD50 >1500MG/KG (RAT) Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:EYES: MAY CAUSE PAIN/SLIGHT TRANSIENT IRRITATION. SKIN: MAY CAUSE IRRITATION, EVEN A BURN. REPEATED CONTACT MAY CAUSE DRYING OR FLAKING. INGESTION: IF ASPIRATED , MAY BE RAPIDLY ABSORBED THROUGH THE L UNGS & RESULT IN INJURY TO OTHER BODY SYSTEMS. INHALATION: MAY CAUSE NASAL IRRITATION/NAUSEA/DRUNKENNESS. Explanation of Carcinogenicity:NONE Effects of Overexposure:POSSIBLE ORGANIC INJURY FROM PROLONGED OR REAEATED EXPOSURES; IRRIT. CENTRAL NERV.SYST DEPRESSION ======================= First Aid Measures ======================= First Aid:EYES: IRRIGATION OF EYES FOR 5 MINUTES; SKIN: WASH OFF IN FLOWING WATER OR SHOWER 15 MINUTES. INHALATION: REMOVE TO FRESH AIR IF EFFECTS OCCUR. INGESTION: DO NOT INDUCE VOMITING. CALL PHYSICIAN OR TRA NSPORT TO EMERGENCY FACILITY. ===================== Fire Fighting Measures ===================== Flash Point:NONE Lower Limits:NONE Upper Limits:NONE Extinguishing Media:NON-FLAMMABLE MATERIAL APPARATUS Unusual Fire/Explosion Hazard:PRESSURE DEMAND SELF-CONTAINED RESPIRATORY EQUIPMENT. NO AUTOIGNITION TEMPERATURE ================== Accidental Release Measures ================== Spill Release Procedures:SMALL LEAKS-MOP UP,WIPE UP, OR SOAK UP IMMEDIATELY. REMOVE TO OUT OF DOORS. LARGE SPILLS-EVACUATE AREA. CONTAIN LIQUID; TRANSFER TO CLOSED METAL CONTAINERS. KEEP OUT OF WATER SUPPLY. ======================Handling and Storage ====================== Handling and Storage Precautions:HANDLE WITH REASONABLE CARE AND CAUTION. AVOID BREATHING VAPORS. VAPORS ARE HEAVIER THAN AIR &ILL COLLECT IN LOW AREAS. Other Precautions:DO NOT ENTER AREAS WHERE VAPORS OF THIS PRODUCT ARE SUSPECTED UNLESS SPECIAL BREATHING APPARATUS IS USED AND AN OBSERVER IS ESENT FOR ASSISTANCE. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:NIOSH APPROVED RESP PROTECTION REQUIRED IN ABSENCE OF PROPER CONTROL Ventilation:RECOMMEND CONTROL OF VAPORS TO SUGGESTED GUIDE Other Protective Equipment:NONE REQUIRED Supplemental Safety and Health ================== Physical/Chemical Properties ================== Boiling Pt:B.P. Text:250F Vapor Pres:13 Vapor Density:5.76 Spec Gravity:1.619 Evaporation Rate & Reference:2.8 (BU AC=1) Solubility in Water:0.015 Appearance and Odor:COLORLESS LIQUID ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES STRONG OXIDIZERS,CHEMICALLY ACTIVE METALS:BA,LI,BE Stability Condition to Avoid:OPEN FLAMES,WELDING ARCS,OTHER HIGH TEMPERATURES. Hazardous Decomposition Products:HYDROGEN CHLORIDE, SMALL AMTS OF PHOSGENE AND CHLORINE ==================== Disposal Considerations ==================== Waste Disposal Methods:SEND SOLVENT TO LICENSED RECLAIMER, INCINERATION, EVAPORATION OF VERY SMALL QUANTITIES, OR APPROVED LANDFILL BURIAL IN COMPLIANCE WITH LOCAL, STATE AND FEDERAL REGULATION. DUMPING INTO SEWERS,ON THE G ROUND, OR INTO ANY BODY OF WATER IS DISCOURAGED.
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:ETHYL ETHER, DIETHYL ETHER, ETHYL OXIDE, EX0184 CAGE:DO242 CAGE:63612 CAGE:DO242 ============= Composition/Information on Ingredients ============= Ingred Name:ETHANE, 1,1'-OXYBIS-; (ETHER) (CERCLA) CAS:60-29-7 RTECS #:KI5775000 Fraction by Wt: 100% OSHA PEL:400 PPM ACGIH TLV:400PPM/500STEL EPA Rpt Qty:100 LBS DOT Rpt Qty:100 LBS Ingred Name:P-CRESOL- 2,6-DI-TERT-BUTYL-; (2,6-DI-TERT-BUTYL-P-CRESOL) (% WT: 1PPM) CAS:128-37-0 RTECS #:GO7875000 Fraction by Wt: <0.1% OSHA PEL:10 MG/M3 ACGIH TLV:10 MG/M3 Ingred Name:RESP PROT: CNDTNS (SEE YOUR SFTY EQUIP SUPP). ENGINEERING &/ADMINISTRATIVE CTLS SHOULD BE IMPLEMENTED TO REDUCE EXPOS. RTECS #:9999999ZZ ===================== Hazards Identification ===================== LD50 LC50 Mixture:LD50 (ORAL RAT): 1215 MG/KG. Routes of Entry: Inhalation:YES Skin:NO Ingestion:YES Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:ACUTE: HARMFUL IF INHALED/SWALLOWED. IRRIT ON CONT W/SKIN, EYES/MUC MEMB. DEPRESSANT OF CNS & CAPABLE OF PRODUCING INTOXICATION, DROW, STUPOR & UNCON. DEATH DUE TO RESP FAILURE MAY RSLT FROM SEV & CON TINUED EXPOS. CHRONIC: NONE SPECIFIED BY MANUFACTURER. Explanation of Carcinogenicity:NOT RELEVANT. Effects of Overexposure:SEE HEALTH HAZARDS. Medical Cond Aggravated by Exposure:PREEXISTING SKIN DISORDERS, EYE PROBLEMS OR IMPAIRED KIDNEY, LIVER OR RESPIRATORY FUNCTIONS. ALCOHOLIC BEVERAGE CONSUMPTION CAN ENHANCE THE TOXIC EFFECTS OF THIS SUBSTANCE. ======================= First Aid Measures ======================= First Aid:GET MEDICAL ASSISTANCE FOR ALL CASES OF OVEREXPOSURE. SKIN: IMMED FLUSH THORO W/LARGE AMOUNTS OF WATER. EYES: IMMED FLUSH THORO W/WATER FOR AT LEAST 15 MINUTES. INHALATION: REMOVE TO FRESH AIR. GIVE A RTIFICIAL RESPIRATION IF BREATHING HAS STOPPED. INGESTION: IF CONSCIOUS, DRINK WATER & INDUCE VOMITING IMMEDIATELY AS DIRECTED BY MEDICAL PERSONNEL. NEVER GIVE ANYTHING BY MOUTH TO UNCONSCIOUS PERSON. ===================== Fire Fighting Measures ===================== Flash Point Method:CC Flash Point:-49F,-45C Lower Limits:1.90% Upper Limits:36.00% Extinguishing Media:ALCOHOL FOAM, CARBON DIOXIDE, DRY CHEMICAL. Fire Fighting Procedures:WEAR NIOSH/MSHA APPROVED SCBA & FULL PROTECTIVE EQUIPMENT . USE WATER TO KEEP FIRE-EXPOSED CONTAINERS COOL. Unusual Fire/Explosion Hazard:DANGEROUS FIRE & EXPLO HAZ. MAY FORM EXPLO PEROXIDES, ESPECIALLY WHEN HEATED. CLSD CONTRS MAY EXPLODE WHEN EXPOSED TO HEAT. VAP CAN TRAVEL DIST TO (SUP DAT) ================== Accidental Release Measures ================== Spill Release Procedures:EVACUATE AREA OF ALL UNNEC PERS. WEAR SUITABLE PROT EQUIP LISTED UNDER CTL MEASURES SECTION. ELIMINATE ANY IGNIT SOURCES UNTIL AREA DETERMINED TO BE FREE FROM EXPLO/FIRE HAZ. CONTAIN RELEASE & ELIMINA TE ITS SOURCE, IF THIS CAN BE DONE W/OUT (SUP DAT) Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER. ======================Handling and Storage ====================== Handling and Storage Precautions:KEEP CONTR TIGHTLY CLSD. STORE IN COOL, DRY AREA AWAY FROM IGNIT SOURCES & OXIDIZERS. CHECK PEROXIDE CONTENT BEFORE HEATING MATL. Other Precautions:DO NOT BREATHE DUST/VAP. DO NOT GET IN EYES, ON SKIN/CLTHG. ELEC GROUND ALL EQUIP WHEN HNDLG THIS PROD. RETAINED RESIDUE MAY MAKE EMPTY CONTRS HAZ. USE CAUTION! PROT AGAINST PHYSICAL DMG & DIRECT SUNL IGHT. DO NOT TAKE INTERNALLY. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:IF WORKPLACE EXPOS LIM OF PROD/ANY COMPONENT IS EXCEEDED (SEE TLV/PEL), A NIOSH/MSHA APPRVD AIR-SUPP RESP IS ADVISED IN ABSENCE OF PROPER ENVIRON CTL. OSHA REGS ALSO PERMIT OTHER NIOSH/MSHA RESP (NEGPRESS TYPE) UNDER SPECIFIED (ING 3) Ventilation:MATERIAL MUST BE HANDLED OR TRANSFERRED IN AN APPROVED FUME HOOD OR WITH ADEQUATE VENTILATION. Other Protective Equipment:EMER EYEWASH & DELUGE SHOWER . WEAR IMPERVIOUS PROTECTIVE CLOTHING TO PREVENT SKIN CONTACT. Work Hygienic Practices:WASH THOROUGHLY AFTER HANDLING. Supplemental Safety and Health EXPLO HAZ: SOURCE & FLASH BACK. SPILL PROC: RISK. TAKE UP & CONTAINERIZE FOR PROPER DISP AS DESCRIBED UNDER DISP. WASTE DISP METH: SERVICE DEPARTMENT (609) 354-9200. THE FOLLOWING MFR SPILL-X ABSORB I S REC FOR THIS PROD: SX0863 SOLV SPILL TREATMENT KIT. ================== Physical/Chemical Properties ================== Boiling Pt:B.P. Text:95.0F,35.0C Melt/Freeze Pt:M.P/F.P Text:-189F,-123C Vapor Pres:442 @ 20C Vapor Density:2.6 Spec Gravity:0.71 (H*2O=1) Evaporation Rate & Reference:37.5 (BUTYL ACETATE=1) Solubility in Water:SOLUBLE Appearance and Odor:COLORLESS LIQUID WITH SWEET ODOR Percent Volatiles by Volume:100 ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES OXIDIZERS, ACETYL PEROXIDE, LIQUID AIR, BROMOAZIDE, CHLORINE. Stability Condition to Avoid:HEAT, CONTACT WITH IGNITION SOURCE, LIGHT, AIR. EVAPORATING TO NEAR DRYNESS. Hazardous Decomposition Products:CARBON MONOXIDE. ==================== Disposal Considerations ==================== Waste Disposal Methods:COMPLY W/FED, STATE, & LOC REGS ON REPORTING RELEASES. REFER TO REG INFO FOR REPORTABLE QTY & OTHER REG DATA. MFR REC SPILL-X ABSORB AGENTS FOR VARIOUS TYPES OF SPILLS. ADDNL INFO ON SPILL-X PROD CAN BE PROVIDED THRU EM SCIENCE TECHNICAL (SUP DAT)
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:B34W201 BASE X, PROMAR 200 ALKYD (SUP DAT) CAGE:54636 CAGE:54636 ============= Composition/Information on Ingredients ============= Ingred Name:ETHYLENE GLYCOL (SARA 313) (CERCLA) VP: 0.1 CAS:107-21-1 RTECS #:KW2975000 Fraction by Wt: <5% OSHA PEL:C 50 PPM (MFR) ACGIH TLV:C 50 PPM, VAPOR EPA Rpt Qty:1 LB DOT Rpt Qty:1 LB Ingred Name:SOLVENT NAPHTHA, PETROLEUM, MEDIUM ALIPHATIC; (MINERAL SPIRITS) VP: 2.0 CAS:64742-88-7 RTECS #:WF3450000 Fraction by Wt: 35-43% OSHA PEL:100 PPM (MFR) ACGIH TLV:100 PPM (MFR) Ingred Name:SOLVENT NAPHTHA, PETROLEUM, MEDIUM ALIPHATIC; (MINERAL SPIRITS 140-FLASH) VP: 0.5 CAS:64742-88-7 RTECS #:WF3450000 Fraction by Wt: 35-43% OSHA PEL:100 PPM (MFR) ACGIH TLV:100 PPM (MFR) Ingred Name:TALC (POWDER), CONTAINING NO ASBESTOS FIBERS; (TALC) CAS:14807-96-6 RTECS #:WW2710000 Fraction by Wt: 0-5% OSHA PEL:20 MPPCF ACGIH TLV:2 MG/M3 RDUST Ingred Name:CARBONIC ACID, CALCIUM SALT (1:1); (CALCIUM CARBONATE) CAS:471-34-1 RTECS #:FF9335000 Fraction by Wt: 5-13% OSHA PEL:15.5 MG/M3 (MFR) ACGIH TLV:10 MG/M3 (MFR) Ingred Name:TITANIUM OXIDE; (TITANIUM DIOXIDE) CAS:13463-67-7 RTECS #:XR2275000 Fraction by Wt: 10-29% OSHA PEL:15 MG/M3 TDUST ACGIH TLV:10 MG/M3 TDUST Ingred Name:EFTS OF OVEREXP: RATS EXPOSED TO TITANIUM DIOXIDE DUST AT 250 MG/M3 DEVELOPED LUNG CANCER, HOWEVER, SUCH EXPOS (ING 9) RTECS #:9999999ZZ Ingred Name:ING 8: LEVELS ARE NOT ATTAINABLE IN WORKPLACE. RPTS HAVE ASSOC RPTD/PRLNG OVEREXP TO SOLVS W/PERM BRAIN & NERV SYS DMG. RTECS #:9999999ZZ Ingred Name:OTHER PREC: INHALING CONTENTS CAN BE HARMFUL/FATAL. THESE COATINGS MAY CONTAIN MATLS CLASSIFIED AS NUISANCE (ING 11) RTECS #:9999999ZZ Ingred Name:ING 10: PARTICULATES WHICH MAY BE PRESENT AT HAZARDOUS LEVELS ONLY DURING SANDING OR ABRADING OF THE DRIED FILM. RTECS #:9999999ZZ ===================== Hazards Identification ===================== LD50 LC50 Mixture:NONE SPECIFIED BY MANUFACTURER. Routes of Entry: Inhalation:YES Skin:YES Ingestion:NO Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:ACUTE: IRRIT OF EYES, SKIN & RESP SYS. MAY CAUSE NERV SYS DEPRESS. EXTREME OVEREXP MAY RSLT IN UNCON & POSS DEATH. SIGNS & SYMPS OF OVEREXP: HDCH, DIZZ, NAUS, & LOSS OF COORD ARE INDICATIONS OF EXCESS EXPOS TO VAPS/SPRAY MISTS. REDNESS & ITCH/BURNING SENSATION MAY INDICATE EYE/EXCESS SKIN EXPOS. (EFTS OF OVEREXP) Explanation of Carcinogenicity:NOT RELEVANT. Effects of Overexposure:HLTH HAZ: ETHYLENE GLYCOL IS CONSIDERED AN ANIMAL TERATOGEN. IF HAS BEEN SHOWN TO CAUSE BIRTH DEFECTS IN RATS & MICE AT HIGH DOSES WHEN GIVEN IN DRINKING WATER/BY GAVAGE. THERE IS NO EVIDENCE TO INDIC ATE IT CAUSES BIRTH DEFECTS IN HUMANS. PRLNG OVEREXP TO SOLV INGS MAY CAUSE ADVERSE EFTS TO LIVER & URINARY SYS. (ING 8) Medical Cond Aggravated by Exposure:NONE GENERALLY RECOGNIZED. ======================= First Aid Measures ======================= First Aid:INHALATION: REMOVE FROM EXPOSURE. RESTORE BREATHING. KEEP WARM AND QUIET. SKIN: WASH AFFECTED AREA THOROUGHLY WITH SOAP AND WATER. REMOVE CONTAMINATED CLOTHING AND LAUNDER BEFORE REUSE. EYES: FLUSH WI TH LARGE AMOUNTS OF WATER FOR AT LEAST 15 MINUTES. GET MEDICAL ATTENTION. INGESTION: GET MEDICAL ATTENTION. ===================== Fire Fighting Measures ===================== Flash Point:100F,38C Lower Limits:1.0% Upper Limits:7.0% Extinguishing Media:CARBON DIOXIDE, DRY CHEMICAL, FOAM. Fire Fighting Procedures:WEAR NIOSH APPRVD SCBA & FULL PROT EQUIP . IF WATER IS USED, FOG NOZZ ARE PREF. WATER MAY BE USED TO COOL CLSD CONTRS TO PVNT PRESS BUILD-UP & (SUP DAT) Unusual Fire/Explosion Hazard:KEEP CONTRS TIGHTLY CLSD. ISOLATE FROM HEAT, ELEC EQUIP, SPKS, & OPEN FLAME. CLSD CONTRS MAY EXPLODE WHEN EXPOSED TO EXTREME HEAT. APPLICATION TO HOT (SUP DAT) ================== Accidental Release Measures ================== Spill Release Procedures:REMOVE ALL SOURCES OF IGNITION. VENTILATE AND REMOVE WITH INERT ABSORBENT. Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER. ======================Handling and Storage ====================== Handling and Storage Precautions:USE ONLY W/ADEQUATE VENTILATION. AVOID BREATHING VAP & SPRAY MIST. AVOID CONTACT W/SKIN & EYES. KEEP AWAY FROM HEAT & OPEN FLAME. CONSULT NFPA CODE. Other Precautions:USE APPRVD BONDING & GROUNDING PROC. KEEP CONTR CLSD WHEN NOT IN USE. TRANSFER ONLY TO APPRVD CONTRS W/COMPLETE & APPROP LABELING. DO NOT TAKE INTERNALLY. KEEP OUT OF REACH OF CHILDREN. INTENTIONAL MI SUSE BY DELIB CONCENTRATING & (ING 10) ============= Exposure Controls/Personal Protection ============= Respiratory Protection:IF PERS EXPOS CANNOT BE CONTROLLED BELOW APPLIC LIMS BY VENT, WEAR PROPERLY FITTED ORG VAP/PARTICULATE RESP APPRVD BY NIOSH FOR PROT. WHEN SANDING/ABRADING DRIED FILM, WEAR DUST/MIST RESP APPRVD BY NI OSH FOR DUST WHICH MAY BE (SUP DAT) Ventilation:LOC EXHST PREF. GEN EXHST ACCEPTABLE IF EXPOS IS MAINT < APPLIC EXPOS LIMS. REFER TO OSHA STDS 1910.94, 1910.107/108. Other Protective Equipment:EMERGENCY EYEWASH AND DELUGE SHOWER MEETING ANSI DESIGN CRITERIA . Work Hygienic Practices:WASH HANDS AFTER USE. Supplemental Safety and Health TRADE NAME/PART #:INTERIOR FINISHES. FIRE FIGHT PROC:POSS AUTOIGNIT/EXPLO WHEN EXPOSED TO EXTREME HEAT. EXPLO HAZ:SURFS REQUIRES SPECIAL PREC. DURING EMER CNDTNS OVEREXP TO DECOMP PRODS MAY CAUSE HLTH HAZ. SYMPS MAY NOT BE IMMED APPARENT. OBTAIN MED ATTN. RESP PROT:GENERATED FROM THIS PROD, UNDERLYING PAINT/ABRASIVE. ================== Physical/Chemical Properties ================== Boiling Pt:B.P. Text:>300F,>149C Vapor Pres:SEE INGS Vapor Density:HVR/AIR Spec Gravity:0.82-1.80 VOC Grams/Liter:3.97 Evaporation Rate & Reference:SLOWER THAN ETHER Appearance and Odor:NONE SPECIFIED BY MANUFACTURER Percent Volatiles by Volume:29-90 ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES NONE KNOWN. Stability Condition to Avoid:NONE SPECIFIED BY MANUFACTURER. Hazardous Decomposition Products:BY FIRE: CARBON DIOXIDE, CARBON MONOXIDE. ==================== Disposal Considerations ==================== Waste Disposal Methods:WASTE MAY BE HAZ AS DEFINED UNDER RCRA 40 CFR 261. WASTE MUST BE TESTED FOR IGNITABILITY TO DETERMINE APPLIC EPA HAZ WASTE NUMBERS. INCIN IN APPRVD FACILITY. DO NOT INCIN CLSD CONTR. DISP OF I/A/W FED , STATE, & LOC REGS REGARDING POLLUTION. ======================= Other Information =======================
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:DISODIUM PHOSPHATE 910311 NO 57 A CAGE:66202 CAGE:66202 ============= Composition/Information on Ingredients ============= Ingred Name:PHOSPHORIC ACID (SARA III) CAS:7664-38-2 RTECS #:TB6300000 Other REC Limits:NONE SPECIFIED OSHA PEL:1 MG/M3/3 STEL ACGIH TLV:1 MG/M3/3 STEL; 9192 EPA Rpt Qty:5000 LBS DOT Rpt Qty:5000 LBS Ingred Name:SODIUM HYDROXIDE (SARA III) CAS:1310-73-2 RTECS #:WB4900000 Other REC Limits:NONE SPECIFIED OSHA PEL:2 MG/M3 ACGIH TLV:C 2 MG/M3; 9293 EPA Rpt Qty:1000 LBS DOT Rpt Qty:1000 LBS ===================== Hazards Identification ===================== LD50 LC50 Mixture:LD50 (ORAL RAT) IS 600 MG/KG Routes of Entry: Inhalation:YES Skin:YES Ingestion:NO Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:ACUTE-CORROSIVE TO ALL BODY TISSUE.INHALATION:MAY CAUSE DAMAGE TO MUCOUS MEMBRANE.SKIN:MAY CAUSE IRRITATION.EYES-MAY CAUSE BURNS.INGESTION:MAY CAUSE BURNS OF INTESTINAL TRACT,THROAT,STOMACH..CHRONIC-M AY CAUSE SKIN IRRITATION,MAY BURN EYES,MAY CAUSE AN INCREASE IN RESPIRATORY ILLNESS. Effects of Overexposure:BURNING OF EYES OR SKIN. Medical Cond Aggravated by Exposure:DERMATITIS ======================= First Aid Measures ======================= First Aid:SEE A DOCTOR IF NEEDED.INHALATION:REMOVE TO FRESH AIR.EYES:FLUSH WITH WATER FOR 15 MINUTES.SKIN:WASH THOROUGHLY WITH WATER. ===================== Fire Fighting Measures ===================== Flash Point:NONE Extinguishing Media:USE WATER ================== Accidental Release Measures ================== Spill Release Procedures:MAY BE SWEPT UP AND TRANSFERRED TO A CONTAINER AND DISCARD IN GENERAL DUMP IN ACCORDANCE WITH STATE,FEDERAL, AND CITY REGULATIONS. Neutralizing Agent:NOT APPLICABLE. ======================Handling and Storage ====================== Handling and Storage Precautions:STORE IN A COOL,DRY,CLEAN PLACE AWAY FROM HEAT.USE FIRST IN FIRST OUT STORAGE SYSTEM. Other Precautions:NO SPECIAL HANDLING. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:USE BUREAU OF MINES APPROVED TOXIC DUST RESPIRATOR. Ventilation:USE ONLY IN WELL VENTILATED AREA. CONTROL DUST IN WORK PLACE AREA AT OR BELOW PROPOSED TLV (5 MG/M3 AS S2O5 FOR 8 HRS). Other Protective Equipment:EYE WASH STATION.PROTECTIVE CLOTHING. Work Hygienic Practices:OBSERVE GOOD PERSONAL HYGIENE PRACTICES AND RECOMMENDED PROCEDURES. Supplemental Safety and Health ================== Physical/Chemical Properties ================== HCC:N1 Melt/Freeze Pt:M.P/F.P Text:DECOMPOSES Solubility in Water:VERY SOLUBLE Appearance and Odor:WHITE CRYSTALLINE SOLID-ODORLESS ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:NO NONE Stability Condition to Avoid:NO SPECIAL HANDLING REQUIRED Hazardous Decomposition Products:NONE ==================== Disposal Considerations ==================== Waste Disposal Methods:CONTAINERS MAY BE INCINERATED OR DISCARDED WITH GENERAL TRASH.
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:FORMULA 450 CAGE:58396 CAGE:58396 ============= Composition/Information on Ingredients ============= Ingred Name:HYPOCHLOROUS ACID, SODIUM SALT; (SODIUM HYPOCHLORITE) (SARA III) CAS:7681-52-9 RTECS #:NH3486300 EPA Rpt Qty:100 LBS DOT Rpt Qty:100 LBS ===================== Hazards Identification ===================== LD50 LC50 Mixture:NONE SPECIFIED BY MANUFACTURER. Routes of Entry: Inhalation:YES Skin:NO Ingestion:YES Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:MODERATE TO SEVERE IRRITATION AND POSSIBLE TISSUE DAMAGE TO EYES DEPENDING ON EXPOSURE. NAUSEA, VOMITING AND DIARRHEA MAY OCCUR UPON INGESTION. PROLONGED SKIN CONTACT MAY CAUSE MODERATE IRRITATION, DE FATTING AND DERMATITIS. Explanation of Carcinogenicity:NOT RELEVANT Effects of Overexposure:SEE HEALTH HAZARDS. Medical Cond Aggravated by Exposure:NONE SPECIFIED BY MANUFACTURER. ======================= First Aid Measures ======================= First Aid:INHAL:MOVE TO FRESH AIR. CONSULT PHYSICIAN IF SYMPTOMS PERSIST. INGEST:GIVE LARGE QUANTITIES OF WATER THEN SEVERAL GLASSES OF MILK. GET MEDICAL ATTENTION IMMEDIATELY. DO NOT INDUCE VOMITING. EYE:FLUSH EYES IMMEDIATELY WITH LARGE AMOUNTS OFWATER FOR AT LEAST 15 MINUTES LIFTING EYELIDS OCCASIONALLY. GET MEDICAL ATTENTION. SKIN:REMOVE CONTAMINATED CLOTHING AND WASH WITH PLENTY OF SOAP AND WATER. ===================== Fire Fighting Measures ===================== Flash Point:NONE Extinguishing Media:USE EXTINGUISHING MEDIA SUITABLE FOR SURROUNDING FIRE . Fire Fighting Procedures:WEAR NIOSH/MSHA APPROVED SCBA AND FULL PROTECTIVE EQUIPMENT . Unusual Fire/Explosion Hazard:WILL BURN IN THE PRESENCE OF A STRONG IGNITION SOURCE AFTER THE WATER IS REMOVED. ================== Accidental Release Measures ================== Spill Release Procedures:CONTAIN LARGE SPILLS AND PUMP TO RECOVER. Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER. ======================Handling and Storage ====================== Handling and Storage Precautions:STORE IN COOL, DRY PLACE. KEEP CONTAINER CLOSED WHEN NOT IN USE. KEEP OUT OF THE REACH OF CHILDREN. Other Precautions:NONE SPECIFIED BY MANUFACTURER. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:ONLY WITHOUT ADEQUATE VENTILATION. NIOSH/MSHA APPROVED RESPIRATOR APPROPRIATE FOR EXPOSURE OF CONCERN . Ventilation:USE ADEQUATE VENTLIATION. Other Protective Equipment:AS REQUIRED TO LIMIT SKIN CONTACT. Work Hygienic Practices:WASH HANDS THOROUGHLY AFTER USE. Supplemental Safety and Health NONE SPECIFIED BY MANUFACTURER. ================== Physical/Chemical Properties ================== HCC:D4 Boiling Pt:B.P. Text:>150F,>66C Spec Gravity:1.08 (H*2O=1) Solubility in Water:COMPLETE Appearance and Odor:CLEAR LIQUID. CHLORIDE ODOR. ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES ACIDS, AMINES, METALS, ORGANICS. Stability Condition to Avoid:NONE Hazardous Decomposition Products:REACTS WITH ACIDS TO RELEASE CHLORINE. ==================== Disposal Considerations ==================== Waste Disposal Methods:DISPOSE OF IN ACCORDANCE WITH ALL LOCAL, STATE, AND FEDERAL REGULATIONS.
1
eyes_protection_mandatory
======================================================= Product ID: DURABOND D-500 CLEAR THIN SPREAD ADHESIVE Cage: 90300 Box: 277 Proprietary Ind: Y ======================================================= Contractor Summary ======================================================= Cage: 90300 Box: 277 ======================================================= Ingredients ======================================================= ----------------------------- ======================================================= Health Hazards Data ======================================================= LD50 LC50 Mixture: NONE SPECIFIED BY MANUFACTURER. Route Of Entry Inds - Inhalation: YES Skin: YES Ingestion: NO Carcinogenicity Inds - NTP: NO IARC: NO OSHA: NO Effects of Exposure: ACUTE: MAY IRRITATE EYES, SKIN, NOSE & RESPIRATORY TRACT. HARMFUL IF INHALED. HARMFUL/FATAL IF SWALLOWED. IF INGESTED CAUSES VOMITING, DIARRHEA & DEPRESSED RESPIRATION. ASPIR OF MATL INTO LUNGS DUE TO VOM CAN CAUSE CHEM PNEUMONITIS WHICH CAN BE FATAL. INHALATION MAY AFFECT THE BRAIN OR NERVOUS SYSTEM (EFTS OF OVEREXP) Explanation Of Carcinogenicity: NOT RELEVANT. Signs And Symptions Of Overexposure: HLTH HAZ:CAUSING DIZZINESS, HEADACHE OR NAUSEA. CHRONIC: REPORTS HAVE ASSOCIATED PROLONGED & REPEATED OVEREXPOSURE TO SOLVENTS W/PERMANENT BRAIN & NERVOUS SYSTEM DAMAGE. Medical Cond Aggravated By Exposure: NONE KNOWN. First Aid: EYES:FLUSH W/LARGE AMOUNTS OF WATER FOR AT LEAST 15 MINS. CONTACT MD IMMEDIATELY. SKIN:WASH W/SOAP & WATER. INHAL:REMOVE TO FRESH AIR. CONTACT MD IMMEDIATELY. INGEST:DO NOT INDUCE VOMITING. CONTACT MD OR REGIONAL POISON CONTROL CENTER IMMEDIATELY. ======================================================= Handling and Disposal ======================================================= Spill Release Procedures: USE ABSORBENT MATERIAL OR SCRAPE UP DRIED MATERIAL & PLACE INTO CONTAINERS. Neutralizing Agent: NONE SPECIFIED BY MANUFACTURER. Waste Disposal Methods: DISPOSE OF ACCORDING TO FEDERAL, STATE & LOCAL STANDARDS. DISCARDED MATERIAL SHOULD BE INCINERATED AT A PERMITTED FACILITY. LIQUIDS CANNOT BE DISPOSED OF AT A LANDFILL. DO NOT REUSE EMPTY CONTAINERS. Handling And Storage Precautions: STORE AWAY FROM CAUSTICS & OXIDIZERS. KEEP CONTAINER TIGHTLY CLOSED WHEN NOT IN USE. KEEP CONTAINERS FROM EXCESSIVE HEAT & FREEZING. Other Precautions: KEEP OUT OF REACH OF CHILDREN. INTENTIONAL MISUSE BY DELIBERATELY CONCENTRATING & INHALING VAPORS MAY BE HARMFUL OR FATAL. ======================================================= Fire and Explosion Hazard Information ======================================================= Flash Point Method: CC Flash Point Text: NONE Extinguishing Media: FOAM & WATER. Fire Fighting Procedures: WEAR NIOSH/MSHA APPROVED SCBA & FULL PROTECTIVE EQUIPMENT (FP N). USE WATER SPRAY TO COOL EXPOSED CONTAINERS. Unusual Fire/Explosion Hazard: NONE KNOWN. ======================================================= Control Measures ======================================================= Respiratory Protection: IF 8-HOUR EXPOSURE LIMIT OR VALUE IS EXCEEDED FOR ANY COMPONENT, USE A NIOSH/MSHA APPROVED RESPIRATOR. CONSULT YOUR SAFETY EQUIPMENT SUPPLIER & THE OSHA REGULATION 29 CFR 1910.134 FOR RESPIRATOR REQUI RMENTS. Ventilation: PROVIDE SUFFICIENT MECH VENT (LOC OR GEN EXHST) TO MAINTAIN EXPOS BELOW PEL/TLV. VAPS ARE HVR THAN AIR & WILL (SUP DAT) Other Protective Equipment: PROVIDE EYEWASH & SOLVENT IMPERVIOUS APRON IF BODY CONTACT W/PRODUCT MAY OCCUR. BARRIER CREAMS MAY BE USED. Work Hygienic Practices: WASH CONTAMINATED CLOTHING BEFORE REUSE. Supplemental Safety and Health: VENT:COLLECT IN LOW AREAS. CHECK LOW AREAS (BASEMENTS, SUMPS, ETC) BEFORE ENTERING. ======================================================= Physical/Chemical Properties ======================================================= HCC: T6 Vapor Pres: 17.5 Vapor Density: >1 Spec Gravity: 1.02 (H*2O=1) Appearance and Odor: CLEAR, LIGHT YELLOW LIQUID. Percent Volatiles by Volume: 60 ======================================================= Reactivity Data ======================================================= Stability Indicator: YES Stability Condition To Avoid: EXCESSIVE HEAT & FREEZING. Materials To Avoid: STRONG OXIDIZERS & CAUSTICS. Hazardous Decomposition Products: NORMAL COMBUSTION PRODUCTS, I.E. OXIDES OF CARBON & NITROGEN. Hazardous Polymerization Indicator: NO Conditions To Avoid Polymerization: NOT RELEVANT. ======================================================= Toxicological Information ======================================================= ======================================================= Ecological Information ======================================================= ======================================================= ======================================================= ======================================================= Regulatory Information ======================================================= ======================================================= Other Information ======================================================= ======================================================= Transportation Information ======================================================= Trans ID NO: 39700 Product ID: DURABOND D-500 CLEAR THIN SPREAD ADHESIVE Review Date: 03/24/1993 Multiple KIT Number: 0 Review IND: Y Additional Data: NOT REGULATED FOR TRANSPORTATION ======================================================= Detail DOT Information ======================================================= DOT PSN Code: ZZZ DOT Proper Shipping Name: NOT REGULATED BY THIS MODE OF TRANSPORTATION ======================================================= Detail IMO Information ======================================================= IMO PSN Code: ZZZ IMO Proper Shipping Name: NOT REGULATED FOR THIS MODE OF TRANSPORTATION ======================================================= Detail IATA Information ======================================================= IATA PSN Code: ZZZ IATA Proper Shipping Name: NOT REGULATED BY THIS MODE OF TRANSPORTATION ======================================================= Detail AFI Information ======================================================= AFI PSN Code: ZZZ AFI Proper Shipping Name: NOT REGULATED BY THIS MODE OF TRANSPORTATION ======================================================= HAZCOM Label ======================================================= Product ID: DURABOND D-500 CLEAR THIN SPREAD ADHESIVE Cage: 90300 Company Name: DAP INC. PO Box: 277 Zipcode: 45401-0277 Label Required IND: Y Date Of Label Review: 10/06/1992 Status Code: C Label Date: 10/06/1992 Origination Code: G Chronic Hazard IND: Y Skin Protection IND: YES Signal Word: CAUTION Respiratory Protection IND: YES Health Hazard: Slight Contact Hazard: Slight Fire Hazard: None Reactivity Hazard: None Hazard And Precautions: STORE AWAY FROM CAUSTICS AND OXIDIZERS. KEEP CONTAINERS FROM EXCESSIVE HEAT AND FREEZING. ACUTE: MAY IRRITATE EYES, SKIN, NOSE AND RESPIRATORY TRACT. HARMFUL IF INHALED. HARMFUL OR FATAL IF SWALLOWED. IF INGESTED CAUSES VOMITING, DIARRHEA AND DEPRESSED RESPIRATION. ASPIRATION OF MATERIAL INTO LUNGS DUE TO VOMITING CAN CAUSE CHEMICAL PNEUMONITIS WHICH CAN BE FATAL. INHALATION MAY AFFECT THE BRAIN O R NERVOUS SYSTEM CAUSING DIZZINESS, HEADACHE OR NAUSEA. CHRONIC: REPORTS HAVE ASSOCIATED PROLONGED AND REPEATED OVEREXPOSURE TO SOLVENTS WITH PERMANENT BRAIN AND NERVOUS SYSTEM DAMAGE. =======================================================
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:ACTIVATED CARBON, CX0640 CAGE:DO242 CAGE:0SK29 CAGE:DO242 ============= Composition/Information on Ingredients ============= Ingred Name:CHARCOAL, ACTIVATED (COCONUT) CAS:68647-86-9 Fraction by Wt: 100% ===================== Hazards Identification ===================== LD50 LC50 Mixture:NONE SPECIFIED BY MANUFACTURER. Routes of Entry: Inhalation:YES Skin:NO Ingestion:NO Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:DUST INHALATION MAY IRRITATE NASAL AND RESPIRATORY PASSAGES. MAY CAUSE EYE IRRITATION ON CONTACT. Explanation of Carcinogenicity:NOT RELEVANT. Effects of Overexposure:SEE HEALTH HAZARDS. Medical Cond Aggravated by Exposure:NONE SPECIFIED BY MANUFACTURER. ======================= First Aid Measures ======================= First Aid:GET MEDICAL ASSISTANCE FOR ALL CASES OF OVEREXPOSURE. SKIN: WASH THORO WITH SOAP AND WATER. EYES: IMMEDIATELY FLUSH THOROUGHLY WITH WATER FOR AT LEAST 15 MINUTES. INHALATION: REMOVE TO FRESH AIR; GIVE ARTF RESP IF BREATHING HAS STOPPED. INGESTION: IF CONSCIOUS, DRINK WATER AND INDUCE VOMITING IMMEDIATELY AS DIRECTED BY MEDICAL PERSONNEL. NEVER GIVE ANYTHING BY MOUTH TO AN UNCONSCIOUS PERSON. ===================== Fire Fighting Measures ===================== Extinguishing Media:WATER, FOAM. Fire Fighting Procedures:WEAR NIOSH/MSHA APPROVED SCBA AND FULL PROTECTIVE EQUIPMENT . Unusual Fire/Explosion Hazard:DANGER FROM SPONTANEOUS HEATING WHEN WET OR TIGHTLY PACKED MAY IGNITE ABOVE 300F IN AMBIENT CONDITIONS. ================== Accidental Release Measures ================== Spill Release Procedures:EVAC AREA OF ALL UNNEC PERS.WEAR SUITABLE PROT EQUIP LISTED UNDER PERS PROT.ELIM ANY IGNIT SOURCES UNTIL AREA IS DETERMINED TO BE FREE FROM EXPLO/FIRE HAZS. CONTAIN RELS & ELIM ITS SOURCE,IF THIS CANBE DONE W/OUT RISK.TAKE UP & CONTAINERIZE (SUPDAT) Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER. ======================Handling and Storage ====================== Handling and Storage Precautions:KEEP CONTAINER CLOSED AND AWAY FROM SPARKS, OPEN FLAME AND OXIDIZING AGENTS. AVOID WETTING AND SUBSEQUENT DRYING IN STORAGE. Other Precautions:DO NOT BREATHE DUST. DO NOT GET IN EYES. AVOID PROLONGED OR REPEATED SKIN CONTACT. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:WEAR NIOSH/MSHA APPROVED RESPIRATOR APPROPRIATE FOR EXPOSURE OF CONCERN . Ventilation:MATERIAL SHOULD BE HANDLED OR TRANSFERRED IN AN APPROVED FUME HOOD OR WITH ADEQUATE VENTILATION. Other Protective Equipment:EYE WASH AND SAFETY EQUIPMENT SHOULD BE READILY AVAILABLE. Work Hygienic Practices:WASH THOROUGHLY AFTER HANDLING. DO NOT TAKE INTERNALLY. Supplemental Safety and Health CONDITIONS TO AVOID: STRONG OXIDIZERS WHICH MAY RESULT IN FIRE. SPILL PROCEDURE: FOR PROPER DISPOSAL AS DESCRIBED. COMPLY WITH FEDERAL, STATE, AND LOCAL REGULATIONS ON REPORTING RELEASES. REFER TO REG ULATORY INFORMATION FOR REPORTABLE QUANTITY AND OTHER REGULATORY DATA. ================== Physical/Chemical Properties ================== Boiling Pt:B.P. Text:8721F,4827C Melt/Freeze Pt:M.P/F.P Text:6332F,3500C Spec Gravity:2.3 (H*2O=1) Solubility in Water:INSOLUBLE Appearance and Odor:BLACK, ODORLESS AMORPHOUS POWDER OR GRANULES ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES OXIDIZERS. Stability Condition to Avoid:AVOID DUSTING (DISPERSION OF FINE PARTICLES IN AIR) AS DUST PARTICLES CAN FORM EXPLO MIX W/AIR; AVOID CONT W/ (SUPDAT) Hazardous Decomposition Products:OXIDES OF CARBON. ==================== Disposal Considerations ==================== Waste Disposal Methods:DISPOSE OF IN ACCORDANCE WITH FEDERAL, STATE AND LOCAL REGULATIONS .
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:49F4348 CAGE:01002 CAGE:01002 ============= Composition/Information on Ingredients ============= Ingred Name:POLYCHLORINATED BIPHENYLS (PCBS) (SARA III) CAS:1336-36-3 RTECS #:TQ1350000 EPA Rpt Qty:1 LB DOT Rpt Qty:1 LB ===================== Hazards Identification ===================== Effects of Overexposure:ABSORBED THRU SKIN,LUNGS,INTESTINE.CAUSES CANCER,LIVER,KIDNEY,STOMACH,EYE,HEARING DISORDER(SUP DATA) ======================= First Aid Measures ======================= First Aid:EYES:FLUSH W/WATER IMMEDIATELY.SKIN:WASH W/SOAP IMMEDIATELY.INHAL:REMOVE TO FRESH AIR,GIVE ART.RESPIR.AS NEEDED.INGEST:GET MEDICAL ATTN.GIVE LARGE QTY OF SALT WATER,INDUCE VOMITING,BUT DO NOT MAKE UNC ONSCIOUS PERSON VOMIT. ================== Accidental Release Measures ================== Spill Release Procedures:USE ABSORBENT & DIKES TO PREVENT RUNOFF.ISOLATE & NOTIFY PROPER AUTHORITIES. ======================Handling and Storage ====================== Handling and Storage Precautions:STORAGE MUST FOLLOW RCRA REQUIREMENTS. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:SUPPLIED AIR W/FULL FACEPIECE,HELMET OR HOOD Ventilation:LOCAL EXHAUST Other Protective Equipment:FULL CLOTHING TO PREVENT SKIN CONTACT Supplemental Safety and Health OVEREXPOS:CAN CAUSE FORMATION OF CYSTS,CAUSES STILLBIRTHS.IRRITATES EYES,NOSE THROAT. ================== Physical/Chemical Properties ================== HCC:Z3 Appearance and Odor:LIGHT STRAW-COLORED LIQUID,AROMATIC ODOR ================= Stability and Reactivity Data ================= STRONG OXIDIZERS ==================== Disposal Considerations ==================== Waste Disposal Methods:CONTROLLED DISPOSAL REQUIRED-GENERALLY HIGH TEMPERATURE INCINERATION.ONLY APPROVED DISPOSAL OPERATOR PERMITTED.
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:PRIMER 1086, PART A CAGE:18565 CAGE:18565 ============= Composition/Information on Ingredients ============= Ingred Name:VM&P NAPHTHA (LIGROINE) CAS:8032-32-4 RTECS #:OI6180000 Fraction by Wt: 60-70% Other REC Limits:NONE SPECIFIED OSHA PEL:300 PPM ACGIH TLV:300 PPM; 9596 Ingred Name:TOLUENE (SARA 313) (CERCLA) CAS:108-88-3 RTECS #:XS5250000 Fraction by Wt: 15-20% Other REC Limits:NONE SPECIFIED OSHA PEL:200 PPM; Z-2 ACGIH TLV:S, 50 PPM; 9596 EPA Rpt Qty:1000 LBS DOT Rpt Qty:1000 LBS Ingred Name:SILICONE Fraction by Wt: 10-15% Other REC Limits:NONE SPECIFIED Ingred Name:ALKYL SILICATE Fraction by Wt: < 5% Other REC Limits:NONE SPECIFIED Ingred Name:N-BUTYL ALCOHOL (SARA 313) (CERCLA) CAS:71-36-3 RTECS #:EO1400000 Fraction by Wt: < 5% Other REC Limits:NONE SPECIFIED OSHA PEL:100 PPM ACGIH TLV:S, C 50 PPM; 9596 EPA Rpt Qty:5000 LBS DOT Rpt Qty:5000 LBS ===================== Hazards Identification ===================== LD50 LC50 Mixture:NOT GIVEN Routes of Entry: Inhalation:YES Skin:YES Ingestion:NO Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:OVEREXPOSURE TO TOLUENE HAS PRODUCED SEVERE BUT REVERSIBLE LIVER AND KIDNEY INJURY IN HUMANS. REPEATED AND PROLONGED OVEREXPOSURE HAS BEEN ASSOCIATED WITH CENTRAL NERVOUS SYSTEM INJURY AND CARDIAC SEN SITIZATION. Explanation of Carcinogenicity:THIS COMPOUND CONTAINS NO INGREDIENTS AT CONCENTRATIONS OF 0.1% OR GREATER THAT ARE CARCINOGENS OR SUSPECT CARCINOGENS. Effects of Overexposure:EYE CONTACT:IRRIT,BLURRED VISION,BURNING SENSATION & TEARING. SKIN:IRRIT,DEFATTING OR DRYING ACTION ON THE SKIN POSSIBLY RESULTING IN DERMATITIS. INHALATION:RESPIRATORY IRRIT,HEADACHES, NAUSEA,DIZZINE SS. MAY CAUSE ANETHETIC EFFECTS OR OTHERTEMPORARY CENTRAL SYSTEM EFFECTS. INGESTION:HARMFUL IF SWALLOWED. Medical Cond Aggravated by Exposure:EXPOSURE MAY AGGRAVATE PRE-EXISTING SKIN AND/OR EYE DISORDERS. ======================= First Aid Measures ======================= First Aid:EYE:FLUSH W/H2O FOR 15 MIN WHILE HOLD EYELIDS OPEN.GET MED ATTN.SKIN:REMOVE CONTAM CLOTHES/FLUSH W/LOTS OF H2O. FOLLOW BY WASHING W/SOAP/H2O.GET MED ATTN IF IRRIT PERSISTS.DO NOT REUSE CLOTHES UNTIL P ROPERLY CLEANED.INHALED:REMOVE TO FRESHAIR.GIVE OXYGEN IF BREATHING DIFFICULT.GIVE CPR IF NOT BREATHING.GET MED ATTN.INGESTION.DO NOT INDUCE VOMIT.IF VICTIM IS CONSCIOUS,DILUTE BY GIVING H2O TO DRINK ===================== Fire Fighting Measures ===================== Flash Point:59F/15C Lower Limits:1 % Upper Limits:7 % Extinguishing Media:USE CARBON DIOXIDE, DRY CHEMICAL, FOAM, WATER FOG Fire Fighting Procedures:FIRE FIGHTERS SHOULD WEAR SELF CONTAINED BREATHING APPARATUS AND FULL PROTECTIVE GEAR. COOL TANKS AND CONTAINERS EXPOSED TO FIRE WITH WATER. Unusual Fire/Explosion Hazard:VAPOR IS FLAMMABLE AND HEAVIER THAN AIR AND MAY TRAVEL TO SOURCE OF IGNITION AND FLASHBACK. USE WATER TO KEEP FIRE EXPOSED CONTAINERS COOL TO REDUCE PRESSURE. ================== Accidental Release Measures ================== Spill Release Procedures:USE EXPO-PROOF EXHAUST VENT IN IMMED SPILL AREA.EXTIN OPEN FLAMES/SOURCES OF IGNIT.WIPE UP/ABSORB W/VERMICULITE/ SIMILAR MAT'L.WASH W/SOAPY H2O TO REMOVE RESIDUE.COLLECT ABSORBED MAT'L/H2O RINSES IN A PPROP CHEM WASTE CONTAINERS.STOP RELEASETO SEWER. Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER. ======================Handling and Storage ====================== Handling and Storage Precautions:EMPLOYEES MUST BE PROPERLY TRAINED IN SAFE HANDLING PRIOR TO USE.STORE IN COOL,DRY AREA W/ADEQUATE VENT.KEEP CONTAINER TIGHTLY SEALED WHEN NOT IN USE. Other Precautions:DO NOT STORE NEAR HEAT,SPARKS/OPEN FLAME.TO PREVENT FIRE/EXPLOSION RISK,EFFECTIVELY GROUND STORAGE AND TRANSFER CONTAINERS IN ACCORDANCE WITH NFPA STANDARDS.DO NOT CUT,WELD,SOLDER,DRILL,GRIND/EXPOSE T O HEAT,FLAME/OTHER SOURCE OF IGNIT. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:USE AN APPROPRIATE, PROPERLY FITTED RESPIRATOR IF EXPOSURES EXCEED PEL/TLV VALUE. THE TYPE OF RESPIRATORY PROTECTION SELECTED WILL DEPEND UPON THE CONDITION. Ventilation:PROVIDE EFFECTIVE EXPLOSION-PROOF MECHANICAL EXHAUST VENT SUFF TO MAINTAIN AIRBORNE CONC BELOW THEIR PEL/TLV VALUES. Other Protective Equipment:CHEMICAL RESISTANT CLOTHING AS NECESSARY TO PREVENT SKIN CONTACT. AN EMERGENCY EYEWASH AND SHOWER SHOULD BE AVAILABLE. Work Hygienic Practices:WASH HANDS THOROUGHLY WITH SOAP AND WATER BEFORE EATING, DRINKING, SMOKING OR USING TOILET FACILITIES. Supplemental Safety and Health NONE SPECIFIED BY MANUFACTURER. ================== Physical/Chemical Properties ================== HCC:F2 Boiling Pt:B.P. Text:210F,99C Melt/Freeze Pt:M.P/F.P Text:NOT GIVEN Decomp Temp:Decomp Text:NOT GIVEN Vapor Pres:25 Vapor Density:> 1 Spec Gravity:0.77 Evaporation Rate & Reference:NOT GIVEN Solubility in Water:INSOLUBLE Appearance and Odor:LIGHT-COLORED LIQUID, SOLVENT ODOR Percent Volatiles by Volume:95 ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES INCOMPATIBLE WITH STRONG OXIDIZERS, ACIDS, BASES. Stability Condition to Avoid:AVOID STORAGE IN OPEN CONTAINERS,EXPO TO OPEN FLAME OR UNCONTROLLED EXPO TO HEAT AND UNCONTROLLED MIXING W/CURING AGENTS Hazardous Decomposition Products:CO,CO2,OXIDES OF SILICON/OTHER ORGANIC SUBST MAY FORM DURING COMBUST.DECOMP PRODUCTS WILL VARY DEPENDING ON CONDITIONS. ==================== Disposal Considerations ==================== Waste Disposal Methods:DISPOSE OF AS AN IGNITABLE WASTE IN ACCORDANCE WITH ALL CURRENT FEDERAL, STATE AND LOCAL REGULATIONS.
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:WATER INDICATING PASTE Preparer's Name:G. CHEKIHIAN CAGE:60115 CAGE:60115 ============= Composition/Information on Ingredients ============= Ingred Name:PER MFG'S MSDS NO HAZARDOUS INGREDIENTS LISTED. Fraction by Wt: NONE Other REC Limits:NONE RECOMMENDED ===================== Hazards Identification ===================== LD50 LC50 Mixture:NOT ESTABLISHED. Routes of Entry: Inhalation:NOSkin:NO Ingestion:YES Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:INGEST:MAY CAUSE GASTRIC DISCOMFORT IF SWALLOWED. Explanation of Carcinogenicity:PER MFG'S MSDS NOT LISTED FOR NTP & IARC AND NOT REGULATED BY OSHA FOR CARCINOGENICITY. Effects of Overexposure:GASTRIC DISCOMFORT. Medical Cond Aggravated by Exposure:NONE KNOWN. ======================= First Aid Measures ======================= First Aid:IN CASE OF INGESTION GIVE PLENTY OF WATER, INDUCE VOMITING. ===================== Fire Fighting Measures ===================== Flash Point:>300F,>149C Extinguishing Media:NONE SPECIFIED BY MFG. Fire Fighting Procedures:NONE. Unusual Fire/Explosion Hazard:NONE. ================== Accidental Release Measures ================== Spill Release Procedures:NONE STATED BY MFG; HOWEVER ABSORBE SPILL WITH INERT MATERIAL. PLACE IN CONTAINER FOR PROPER DISPOSAL. ======================Handling and Storage ====================== Handling and Storage Precautions:NONE STATED BY MFG; HOWEVER, KEEP AWAY FROM STRONG OXIDIZING AGENTS AND STRONG ACIDS. ADDITINALLY KEEP ALL CONTAINERS CLOSED WHEN NOT IN USE. Other Precautions:NONE STATED BY MFG. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:NOT REQUIRED PER MFG'S MSDS. Ventilation:PER MFG NO. Other Protective Equipment:NONE STATED BY MFG. Work Hygienic Practices:WASH HANDS THOROUGHLY AFTER HANDLING. Supplemental Safety and Health ================== Physical/Chemical Properties ================== HCC:N1 Boiling Pt:B.P. Text:>300F,>149C Spec Gravity:>1 Solubility in Water:DISPERSIBLE Appearance and Odor:PURPLISH-BLUE PASATE WITH NO ODOR. ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES STRONG OXIDIZING AGENTS, STRONG ACIDS. Stability Condition to Avoid:NONE SPECIFIED BY MFG. Hazardous Decomposition Products:NONE SPECIFIED BY MFG. ==================== Disposal Considerations ==================== Waste Disposal Methods:SMALL QUANTITIES MAY BE DISPOSED OF IN LANDFILL OR SEWAGE SYSTEM. LARGE QUANTITIES CONTACT MANUFACTURER AND LOCAL ORDINANCE.
0
eyes_protection_not_mandatory
===================== Product Identification ===================== Product ID:NICKEL-CADMIUM (NI-CD) BATTERY,VENTED,10K01 CAGE:02731 CAGE:02731 ============= Composition/Information on Ingredients ============= Ingred Name:NO INGREDIENT FOR THIS FORMULATION_INGREDIENT ===================== Hazards Identification ===================== LD50 LC50 Mixture:NOT KNOWN Routes of Entry: Inhalation:YES Skin:NO Ingestion:NO Reports of Carcinogenicity:NTP:YES IARC:YES OSHA:NO Health Hazards Acute and Chronic:INTACT BATTERIES PRESENT NO SPECIFIC HAZARDS.BURNING BATTERIES MAY EMIT TOXIC FUMES. Explanation of Carcinogenicity:CD & CMPD:LTD EVID FOR CARCIN IN HUMANS,SUFF IN ANIMALS (IARC 1987);SUSP HUMAN,KNOWN ANIMAL CARCIN (NTP 1991);(SUP DATA) Effects of Overexposure:LEAKING BATTERIES LEAK CORROSIVE MATERIAL IRRITATING TO EYES,SKIN,MUCOUS MEMBRANES.ELECTROLYTE EXPOSURE TO SKIN,EYES WILL CAUSE SEVERE IRRITATION,INHALATION OF FUMES MAY CAUSE SEVERE RESPIRATORY IRRIT ATION. Medical Cond Aggravated by Exposure:BURNING BATTERIES:RESPIRATORY AILMENTS.LEAKING BATTERIES:SKIN CONDITIONS. ======================= First Aid Measures ======================= First Aid:BATTERY CONTENTS IN CONTACT WITH EYES/SKIN:WASH AFFECTED AREA WITH CLEAN WATER FOR AT LEAST 15 MINUTES.DO NOT ATTEMPT TO NEUTRALIZE.SEEK MEDICAL ATTENTION PROMPTLY.INGESTION/INHALATION:NOT KNOWN. ===================== Fire Fighting Measures ===================== Flash Point:NOT KNOWN Lower Limits:NOT KNOWN Upper Limits:NOT KNOWN Extinguishing Media:USE CARBON DIOXIDE OR DRY CHEMICAL FIRE EXTINGUISHER,10-B:C. Fire Fighting Procedures:FIRE FIGHTERS SHOULD USE SELF-CONTAINED BREATHING APPARATUS (SCBA). Unusual Fire/Explosion Hazard:BATTERY/CELLS MAY RUPTURE AND/OR RELEASE TOXIC FUMES,IF SUBJECTED TO FIRE/EXTREME HEAT.FIRE MAY CAUSE BATTERY TO FUME. ================== Accidental Release Measures ================== Spill Release Procedures:AVOID SKIN OR EYE CONTACT.USE NONFLAMMABLE ABSORBENT FOR CLEANUP.COORDINATE WITH INSTALLATION SAFETY AND ENVIRONMENTAL OFFICES. Neutralizing Agent:NOT KNOWN ======================Handling and Storage ====================== Handling and Storage Precautions:DO NOT ABUSE OR SHORT CIRCUIT.WHEN STORING,STORE IN COOL,DRY& WELL VENTILATED AREA,SEPARATE FROM OTHER HAZ MATLS,WHICH IS APPROVED BY LOCAL FIRE DEPT. Other Precautions:DO NOT INVERT OR CAUSE TO SPILL.RECHARGE IAW METHODS SPECIFIED IN APPLICABLE TECHNICAL MANUAL. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:IF BATTERIES ARE BURNING USE SELF-CONTAINED BREATHING APPARATUS (SCBA). Ventilation:CONTACT LOCAL SAFETY/INDUSTRIAL HYGIENE OFFICE TO DETERMINE IF LOCAL EXHAUST VENTILATION IS NEEDED . Other Protective Equipment:CHEMICALLY RESISTANT APRON. Work Hygienic Practices:AVOID SKIN OR EYE CONTACT WITH ELECTROLYTE.DO NOT EAT OR SMOKE IN BATTERY SERVICE AREA. Supplemental Safety and Health EXPLAN OF CARCIN:ACGIH:A2=SUSP HUMAN CARCIN (1992-93);CHEMICALS KNOWN TO CAUSE CANCER (PROP CAL 1987).NI/CMPD:SUFF EVID FOR CARCIN IN HUMANS AND ANIMALS (IARC 1987);SUSPECTED HUMAN,KNOWN ANIMAL CARCIN OGEN (NTP 1991);ACGIH:A1=CONFIRMED HUMAN CARCIN (1992-93);CHEMICALS KNOWN TO CAUSE CANCER (PROP CAL 1987). ================== Physical/Chemical Properties ================== HCC:B1 Boiling Pt:B.P. Text:NOT KNOWN Melt/Freeze Pt:M.P/F.P Text:NOT KNOWN Decomp Temp:Decomp Text:NOT KNOWN Vapor Pres:NOT KNOWN Vapor Density:NOT KNOWN Spec Gravity:NOT KNOWN Evaporation Rate & Reference:NOT KNOWN Solubility in Water:NOT KNOWN Appearance and Odor:NOT KNOWN ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES STRONG OXIDIZING AGENT,ACIDS. Stability Condition to Avoid:FIRE AND EXTREME HEAT.DO NOT SHORT CIRCUIT OR OVERCHARGE. Hazardous Decomposition Products:TOXIC FUMES Conditions to Avoid Polymerization:WILL NOT OCCUR. ==================== Disposal Considerations ==================== Waste Disposal Methods:DISPOSAL MUST BE IAW FEDERAL,STATE,AND LOCAL REGULATIONS.COORDINATE WITH SUPPORTING INSTALLATION AND/OR MACOM ENVIRONMENTAL OFFICE PRIOR TO DISPOSAL .NI-CD BATTERIES CLASSIFIED AS HAZARDOUS WAST E UNDER RCRA REGULATIONS.RECYCLING IS PREFERRED.
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:TANTALUM OXIDE 99% CAGE:60928 CAGE:60928 ============= Composition/Information on Ingredients ============= Ingred Name:TANTALUM OXIDE CAS:1314-61-0 RTECS #:WW5855000 Fraction by Wt: 99% Other REC Limits:NONE RECOMMENDED ===================== Hazards Identification ===================== LD50 LC50 Mixture:ORAL LD50 (RAT) IS 8 G/KG Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:MAY CAUSE EYE IRRITATION. MAY CAUSE SKIN IRRITATION. Explanation of Carcinogenicity:NONE. Effects of Overexposure:NONE SPECIFIED BY MANUFACTURER. Medical Cond Aggravated by Exposure:NONE SPECIFIED BY MANUFACTURER. ======================= First Aid Measures ======================= First Aid:IN CASE OF CONTACT, IMMEDIATELY FLUSH EYES WITYH COPIOUS AMOUNTS OF WATER FOR AT LEAST 15 MIN. IN CASE OF CONTACT, IMMEDIATELY WASH SKIN WITH SOAP AND COPIOUS AMOUNTS OF WATER. IF INHALED, REMOVE TO F RESH AIR. IF NOT BREATHING GIVE ARTIFICIAL RESPIRATION. IF BREATHING IS DIFFICULT, GIVE OXYGEN. IF SWALLOWED, WASH OUT MOUTH WITH WATER PROVIDED PERSON IS CONSCIOUS. CALL A PHYSICIAN. ===================== Fire Fighting Measures ===================== Flash Point:NONE Extinguishing Media:WATER SPRAY. CABON DIOXIDE, DRY CHEMICAL POWDER OR APPROPIATE FOAM. Fire Fighting Procedures:WEAR SELF-CONTAINED BREATHING APPARATUS AND PROTECTIVE CLOTHING TO PREVENT CONTACT WITH SKIN AND EYES. Unusual Fire/Explosion Hazard:NONE SPECIFIED BY MANUFACTURER. ================== Accidental Release Measures ================== HOLD FOR WASTE DISPOSAL. AVOID RAISING DUST. VENTILATE AREA AND WASH SPILL SITE AFTER MATERIA L PICKUP IS COMPLETE. Neutralizing Agent:NONE ======================Handling and Storage ====================== Handling and Storage Precautions:KEEP TIGHTLY CLOSED. STORE IN A COOL DRY PLACE. Other Precautions:NONE. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:NIOSH/MSHA APPROVED RESPIRATO. AVOID INHALATION. Ventilation:MECHANICAL EXAHUST REQUIRED. Other Protective Equipment:SAFETY SHOWER AND EYE BATH. Work Hygienic Practices:WASH THOROUGHLY AFTER HANDLING. Supplemental Safety and Health AVOID CONTACT WITH EYES, SKIN AND CLOTHING, AVOID PROLONGED OR REPEATED EXPOSURE. ================== Physical/Chemical Properties ================== HCC:N1 Melt/Freeze Pt:M.P/F.P Text:NONE Appearance and Odor:OFF-WHITE POWDER. ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES STRONG OXIDIZING AGENTS. Stability Condition to Avoid:NONE SPECIFIED BY MANUFACTURER. Hazardous Decomposition Products:NATURE OF DECOMPOSITION PRODUCTS NOT KNOWN. ==================== Disposal Considerations ==================== Waste Disposal Methods:BURY IN A LANDFILL SITE APPROVED FOR THE DISPOSAL OF CHEMICAL AND HAZARDOUS WASTE. OBSERVE ALL FEDERAL, STATE AND LOCAL ENVIRONEMTAL REGULATIONS.
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:STYCAST 2651-40 BLACK Kit Part:Y Resp. Party Other MSDS Num.:150265 Preparer's Name:DAVID HAAS CAGE:UO004 CAGE:UO004 CAGE:04552 Contract Num:SP0430-00-M-H369 CAGE:7Z016 Contract Num:SP0430-01-M-H935 CAGE:7B953 Contract Num:SP0430-00-M-H518 CAGE:0ZBE8 ============= Composition/Information on Ingredients ============= Ingred Name:DGEBA EPOXY RESIN Minumum % Wt:50. Maxumum % Wt:60. Ingred Name:CRYSTALLINE SILICA Minumum % Wt:20. Maxumum % Wt:25. OSHA PEL:0.1 MG/M3 ACGIH TLV:0.1MG/M3 Ingred Name:MICA CAS:12001-26-2 RTECS #:VV8760000 Minumum % Wt:15. Maxumum % Wt:20. OSHA PEL:20 MPPCF ACGIH TLV:3 MG/M3 Ingred Name:PHENYL GLYCIDYL ETHER CAS:122-60-1 RTECS #:TZ3675000 Minumum % Wt:2. Maxumum % Wt:5. OSHA PEL:60 MG/M3;10 PPM ACGIH TLV:0.6 MG/M3;0.1 PPM Ingred Name:CARBON BLACK CAS:1333-86-4 RTECS #:FF5800000 < Wt:.2 OSHA PEL:3.5 MG/M3 ACGIH TLV:3.5 MG/M3 ===================== Hazards Identification ===================== LD50 LC50 Mixture:NO DATA PROVIDED BY MANUFACTURER Reports of Carcinogenicity:NTP:UNKNOWN IARC:YES Health Hazards Acute and Chronic:EYE CONTACT: CONTAINS MATERIALS IRRITATING TO THE EYES. SKIN CONTACT: CONTAINS MATERIALS WHICH CAUSE MODERATE SKIN IRRITATION. PROLONGED OR REPEATED EXPOSURE TO THE LIQUID MAY EXERT A DEFATTING ACTION ON THE SKIN, POSSIBLY RESULTING IN DERMATITIS. THIS PRODUCT MAY CAUSE SKIN SENSITIZATION/ ALLERGIC SKIN REACTIONS WHICH MAY BE SEVERE IN CERTAIN INDIVIDUALS. INHALATION: HEATING CAN GENERATE VAPORS THAT MAY CAUSE RESPIRATORY IRRITATION, NAUSEA AND HEADACHES. INHALATION HAZARD AT ROOM TEMPERATURE IS UNLIKELY, DUE TO THE LOW VOLATILITY OF THIS PRODUCT. INGESTION: HARMFUL IF SWALLOWED. Explanation of Carcinogenicity:IARC: DGBA EPOXY RESINS ARE NOT CLASSIFABLE AS CARCINOGENS. IARC CLASSIFIES FREE CRYSTALLINE SILICA AS A CLASS 2 CARCINOGEN. IARC HAS CLASSIFIED FREE CARBON BLACK AS A CLASS 2B CARCINOGEN. IARC HAS CL ASSIFIED PHENYL GLYCIDYL ETHER AS A CLASS 2B CARCINOGEN. Effects of Overexposure:EYE CONTACT: BLURRED VISION, BURNING SENSATION AND TEARING. SKIN CONTACT: DEFATTING OR DRYING ACTION ON THE SKIN, DERMATITIS, SKIN SENSITIZATION/ALLERGIC SKIN REACTIONS WHICH MAY BE SEVERE IN CERTAIN INDIBIDUALS; SYMPTOMS INCLUDE RASH, ITCHING, HIVES, SWELLING OF THE EXTREMITIES. INHALATION: RESPIRATORY IRRITATION, NAUSEA AND HEADACHES. Medical Cond Aggravated by Exposure:EXPOSURE MAY AGGRAVATE PREEXISTING SKIN AND/OR EYE DISORDERS. ======================= First Aid Measures ======================= First Aid:EYES: FLUSH WITH WATER FOR 15 MINUTES, HOLDING EYELIDS OPEN. GET MEDICAL ATTENTION. SKIN: REMOVE CONTAMINATED CLOTHING AND FLUSH AREA OF SKIN WITH PLENTY OF WATER. FOLLOW BY WASHING WITH SOAP AND WAT ER. GET MEDICAL ATTENTION IF IRRITATIONPERSISTS. PROPERLY CLEAN CONTAMINATED CLOTHING BEFORE REUSE. INHALATION: MOVE TO FRESH AIR. GIVE OXYGEN IF BREATHING DIFFICULT. GIVE ARTIFICIAL RESPIRATION IF NO T BREATHING. GET MEDICAL ATTENTION. INGESTION: GIVE PLENTY OF WATER TO DRINK, IF VICTIM IS CONSCIOUS AND ALERT. NEVER GIVE ANYTHING BY MOUTH TO A DROWSY, UNCONSCIOUS, OR CONVULSIVE PERSON. GET MEDICAL ATTENTION. ===================== Fire Fighting Measures ===================== Flash Point:>93.3C, 200.F Lower Limits:N/E Upper Limits:N/E Extinguishing Media:USE CARBON DIOXIDE, DRY CHEMICAL, FOAM, WATER FOG. Fire Fighting Procedures:FIREFIGHTERS/RESCUE PERSONNEL SHOULD WEAR POSITIVE PRESSURE SELF-CONTAINED BREATHING APPARATUS AND FULL PROTECTIVE EQUIPMENT. COOL EXPOSED CONTAINERS WITH WATER TO PREVENT PRESSURE BUILDUP. IF LARGE Q UANTITIES OF MATERIAL ARE INVOLVED, EVACUATE AREA AND FIGHT FIRE FROM A SAFE DISTANCE. Unusual Fire/Explosion Hazard:DECOMPOSITION AND COMBUSTION PRODUCTS MAY BE TOXIC. CLOSED CONTAINERS MAY VIOLENTLY RUPTURE UNDER FIRE CONDITIONS. REACTION WITH CURING AGENTS IS EXOTHERMIC; SMOKE OR TOXIC FUMES MAY BE EVOLVED IF HEA T OF REACTION BECOMES EXCESSIVE DUE TO HIGH CURING TEMPERATURES OR CURING OF LARGE MASSES OF MATERIAL. ================== Accidental Release Measures ================== Spill Release Procedures:STOP SOURCE OF SPILL. ACTIVATE EXHAUST VENTILATION IN AREA. DIKE AREA TO PREVENT RELEASES TO SEWERS, DRAINS, WATERWAYS. COLLECT SPILL FOR SALVAGE/DISPOSAL. APPLY ABSORBENT MATERIAL TO SOAK UP RESIDUE . WASH AREA WITH SOAPY WATER. PREVENT RUNOFF FROM ENTERING WATERWAYS. TRANSFER ABSORBED MATERIAL AND WATER RINSES TO CONTAINERS. DISPOSE OF IN ACCORDANCE WITH FEDERAL, STATE, AND LOCAL REGULATIONS. Neutralizing Agent:NO DATA PROVIDED BY MANUFACTURER ======================Handling and Storage ====================== Handling and Storage Precautions:EMPLOYEES MUST BE PROPERLY TRAIN IN SAFE HANDLING OF THIS PRODUCT PRIOR TO USE. STORE IN COOL, DRY LOCATION WITH ADEQUATE VENTILATION. KEEP CONTAINER TIGHTLY SEALED WHEN NOT IN USE. KEEP AWAY FROM OPE N FLAMES AND HEAT SOURCES. CONSULT THE PRODUCT TECHNICAL BULLETIN FOR DETAILED STORAGE INFORMATION. Other Precautions:BECAUSE USAGE CONDITIONS VARY DEPENDING ON CUSTOMER APPLICATION, SPECIFIC SAFE HANDLING PROCEDURES SHOULD BE DEVELOPED BY A PERSON KNOWLEDGEABLE IN THE INTENDED USAGE CONDITIONS, AND EQUIPMENT. EMPLOY EES MUST BE TRAINED IN SAFE HANDLING OF THIS PRODUCT PRIOR TO USE. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:USE AN APPROPRIATE, PROPERLY FITTED RESPIRATOR IF EXPOSURES EXCEED PEL/TLV VALUES. THE TYPE OF PROTECTION SELECTED (SCBA, AIR-PURIFYING, ETC.) WILL DEPEND UPON THE CONDITIONS OF USE. OBSERVE OSHA REGU LATIONS FOR RESPIRATORY PROTECTION (29 CFR 1910.134). Ventilation:PROVIDE EFFECTIVE MECHANICAL EXHAUST VENTILATION TO DRAW VAPORS, MISTS OR FUMES GENERATED DURING PROCESSING AWAY FROM THE WORKER AND PREVENT ROUTINE INHALATION. OR FACE SHIELD. Other Protective Equipment:IF NECESSARY, A PROPER CHEMICAL-RESISTANT APRON AND ADDITIONAL IMPERVIOUS CLOTHING SHOULD BE USED TO PREVENT SKIN CONTACT AND CONTAMINATION OF CLOTHING. EMERGENCY EYE WASH FACILITIES AND SAFETY SHOWER. Work Hygienic Practices:WASH HANDS AND FACE THOROUGHLY AFTER HANDLING THIS PRODUCT AND BEFORE EATING, DRINKING OR SMOKING. Supplemental Safety and Health THIS IS A THREE PART KIT, SAME NSN. FOR OTHER TWO ITEMS IN THE KIT, SEE MSDS # CKSWV COVERING CATALYST 11,& MSDS SERIAL # CKSWH FOR CATALYST 9. HCC FOR KIT= B2. ================== Physical/Chemical Properties ================== HCC:V5 NRC/State Lic Num:NOT RELEVANT Boiling Pt:B.P. Text:ND Vapor Pres:<1 MM HG @ 25C Vapor Density:>AIR Spec Gravity:1.60 Solubility in Water:INSOLUBLE Appearance and Odor:BLACK LIQUID, PUNGENT ODOR. Percent Volatiles by Volume:<3 ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES INCOMPATIBLE WITH STRONG OXIDIZERS, ACIDS, BASES; UNCONTROLLED MIXING WITH AMINES, ANHYDRIDES, MERCAPTANS, IMIDAZOLES MAY CAUSE HAZARDOUS POLYMERIZATION. Stability Condition to Avoid:PRODUCT IS STABLE UNDER NORMAL HANDLING AND STORAGE CONDITIONS. Hazardous Decomposition Products:CO, CO2, ALEDEHYDES, ACIDS AND OTHER ORGANIC SUBSTANCES MAY BE FORMED DURING COMBUSTION. THE CHEMICAL NATURE AND QUANTITY OF DECOMPOSITION BY-PRODUCTS VARY WIDELY DEPENDING ON CONDITION OF COMBUSTION. Conditions to Avoid Polymerization:IHAZARDOUS POLYMERIZATION WILL NOT OCCUR. SEE "MATERIALS TO AVOID" ABOVE. =================== Toxicological Information=================== Toxicological Information:ALTHOUGH THE SIGNIFICANCE IS UNKNOWN, THE DGEBA EPOXY RESIN IN THIS PRODUCT HAS BEEN SHOWN TO BE MUTAGENIC IN COME MICROBIAL TESTS, BUT HAS FAILED TO SHOW MUTAGENICITY IN OTHERS. CHROMOSOMAL ABERRATIO NS WERE OBSERVED IN CULTURED RAT LIVER CELLS. PROLONGED EXPOSURE TO FREE CRYSTALLINE SILICA MAY CAUSE SCARRING OF THE LUNGS, WITH COUGH AND SHORTNESS OF BREAATH. A DELAYED LUNG DISEASE, SILICOSIS, MA Y RESULT FROM PROLONGED BREATHING OF FREE CRYSTALLINE SILICA. PHENYL GLYCIDYL ETHER HAS BEEN REPORTED TO PRODUCE NASAL CANCERS IN LIFETIME INHALATION STUDIES ON RATS AT CONCENTRATIONS OF 12 PPM ===================== Ecological Information ===================== Ecological:NO DATA PROVIDED BY MANUFACTURER. ==================== Disposal Considerations ==================== Waste Disposal Methods:DISPOSE OF IN ACCORDANCE WITH CURRENT FEDERAL, STATE AND LOCAL REGULATIONS. =================== MSDS Transport Information =================== Transport Information:D.O.T. INFORMATION: RESIN COMPOUND, N.O.I- NON-REGULATED. FREIGHT CODE: 2015. ===================== Regulatory Information ===================== SARA Title III Information:THIS PRODUCT DOES NOT CONTAIN ANY SUBSTANCES REGULATED BY THE SARA SECTION 313 AMENDMENTS TO RCRA. Federal Regulatory Information:TSCA STATUS: ALL COMPNENTS OF THIS PRODUCT ARE LISTED IN THE EPA TOXIC SUBSTANCE CONTROL ACT INVENTORY. THIS PRODUCT CONTAINS THE FOLLOWING SUBSTANCES WHICH ARE SUBJECT TO TSCA SECTION 12(B) EXPORT N OTIFICATION REQUIREMENTS: DIGLYCIDYL ETHER OF BISPHENOL A (1675-54-3). State Regulatory Information:NO DATA PROVIDED BY MANUFACTURER. ======================= Other Information =======================
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:45F929 CAGE:01002 CAGE:01002 ============= Composition/Information on Ingredients ============= Ingred Name:POLYCHLORINATED BIPHENYLS (PCBS) (SARA III) CAS:1336-36-3 RTECS #:TQ1350000 EPA Rpt Qty:1 LB DOT Rpt Qty:1 LB ===================== Hazards Identification ===================== Effects of Overexposure:ABSORBED THRU SKIN,LUNGS,INTESTINE.CAUSES CANCER,LIVER,KIDNEY,STOMACH,EYE,HEARING DISORDER(SUP DATA) ======================= First Aid Measures ======================= First Aid:EYES:FLUSH W/WATER IMMED.SKIN:WASH W/SOAP IMMED.INHAL:REMOVE TO FRESH AIR.GIVE ART.RESPIR. AS NEEDED.INGEST:GET MEDICAL ATTN.GIVE LARGE QTY OF SALT WATER,INDUCE VOMITING,BUT DO NOT MAKE UNCONSCIOUS PE RSON VOMIT. ================== Accidental Release Measures ================== Spill Release Procedures:USE ABSORBENT & DIKES TO PREVENT RUNOFF.ISOLATE & NOTIFY PROPER AUTHORITIES. ======================Handling and Storage ====================== Handling and Storage Precautions:STORAGE MUST FOLLOW RCRA REQUIREMENTS. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:SUPPLIED AIR W/FULL FACEPIECE,HELMET OR HOOD Ventilation:LOCAL EXHAUST Other Protective Equipment:FULL CLOTHING TO PREVENT SKIN CONTACT Supplemental Safety and Health OVEREXPOS:CAN CAUSE FORMATION OF CYSTS.CAUSES STILLBIRTHS.IRRITATES EYES,NOSE,THROAT. ================== Physical/Chemical Properties ================== HCC:Z3 Appearance and Odor:LIGHT STRAW COLORED LIQUID,AROMATIC ODOR ================= Stability and Reactivity Data ================= STRONG OXIDIZERS ==================== Disposal Considerations ==================== Waste Disposal Methods:CONTROLLED DISPOSAL REQUIRED-GENERALLY HIGH TEMPERATURE INCINERATION.ONLY APPROVED DISPOSAL OPERATOR PERMITTED.
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:DISTILLED WATER CAGE:24774 CAGE:24774 ============= Composition/Information on Ingredients ============= Ingred Name:NON HAZARDOUS INGREDIENT Fraction by Wt: 100% Other REC Limits:NONE SPECIFIED ===================== Hazards Identification ===================== Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:ACUTE: NON-HAZARDOUS TO THE EYES, SKIN AND RESPIRATORY SYSTEM. CHRONIC: NO EVIDENCE OF POTENTIAL CHRONIC EFFECTS. Explanation of Carcinogenicity:THIS COMPOUND CONTAINS NO INGREDIENTS AT CONCENTRATIONS OF 0.1% OR GREATER THAT ARE CARCINOGENS OR SUSPECT CARCINOGENS. Effects of Overexposure:NONE. Medical Cond Aggravated by Exposure:NONE SPECIFIED BY MANUFACTURER. ======================= First Aid Measures ======================= First Aid:SKIN-NO TREATMENT REQUIRED. EYE-NO TREATMENT REQUIRED. INHALATION-NO TREATMENT REQUIRED-NO HAZARD. INGESTION-(GENERAL) DO NOT FEED ANYTHING BY MOUTH TO AN UNCONSCIOUS OR CONVULSIVE VICTIM. SPECIFIC-NO TREATMENT REQUIRED-NO HAZARD. ===================== Fire Fighting Measures ===================== Flash Point:NONE Extinguishing Media:USE WATER, CARBON DIOXIDE, FOAM, OR DRY CHEMICAL. Fire Fighting Procedures:FIRE FIGHTERS SHOULD WEAR POSITIVE PRESSURE SELF CONTAINED BREATHING APPARATUS (FULL FACE-PIECE TYPE). Unusual Fire/Explosion Hazard:NONE SPECIFIED BY MANUFACTURER. ================== Accidental Release Measures ================== Spill Release Procedures:CONTAMINATED AREA MAT BE WASHED DOWN WITH WATER. ======================Handling and Storage ====================== Handling and Storage Precautions:KEEP CONTAINER CLOSED WHEN NOT IN USE. REASONABLE AND SAFE CHEMICAL STORAGE. THIS REAGENT IS NON-HAZARDOUS. Other Precautions:NONE ============= Exposure Controls/Personal Protection ============= Respiratory Protection:IF VENTILATION IS INADEQUATE OR SIGNIFICANT REAGENT EXPOSURE IS LIKELY, NO RESPIRATOR IS REQUIRED. Ventilation:TO PROVIDE ADEQUATE VENTILATION. Other Protective Equipment:NONE SPECIFIED BY MANUFACTURER. Work Hygienic Practices:NONE SPECIFIED BY MANUFACTURER. Supplemental Safety and Health NONE ================== Physical/Chemical Properties ================== HCC:N1 Boiling Pt:B.P. Text:212F,100C Melt/Freeze Pt:M.P/F.P Text:32.0F,0.0C Vapor Pres:18 Spec Gravity:1.0 pH:7 Solubility in Water:100% Appearance and Odor:COLORLESS, NO ODOR, LIQUID. ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES NONE SPECIFIED BY MANUFACTURER. Stability Condition to Avoid:NONE SPECIFIED BY MANUFACTURER. Hazardous Decomposition Products:THERMAL DECOMPOSITION YIELDS ELEMENTAL OXIDES. ==================== Disposal Considerations ==================== Waste Disposal Methods:THIS REAGENT OR WATER CONTAMINATED WITH THIS REAGENT MAY BE SENT TO A SANITARY SEWER.
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:BLUE STREAK, PFX-400-89 CAGE:FO983 CAGE:72556 CAGE:FO983 ============= Composition/Information on Ingredients ============= Ingred Name:S-TRIAZINE-2,4,6(1H,3H,5H)-TRIONE, 1,3,5-TRIS (2,3-EPOXYPROPYL-; (TRIBLYCIDAL ISOCYANURATE). VP: 0.01 CAS:2451-62-9 RTECS #:XZ1994900 Fraction by Wt: 5% OSHA PEL:N/K ACGIH TLV:N/K Ingred Name:BLUE PIGMENT; (COPP PHTHALOCYAN, BLUE PGMT COMP) CAS:147-14-8 Fraction by Wt: <5% OSHA PEL:N/K ACGIH TLV:N/K Ingred Name:CALCIUM CARBONATE CAS:1317-65-3 RTECS #:EV9580000 Fraction by Wt: 10% OSHA PEL:15 MG/M3 TDUST;5RESP ACGIH TLV:10 MG/M3 TDUST Ingred Name:NUISANCE DUST Fraction by Wt: 100% OSHA PEL:10 MG/M3 ACGIH TLV:10 MG/M3 ===================== Hazards Identification ===================== LD50 LC50 Mixture:SEE INGREDIENTS Routes of Entry: Inhalation:YES Skin:YES Ingestion:NO Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:ACUTE: EYE: POSS IRRIT. INHAL: MAY CAUSE HEADACHE AND RESPIRATORY IRRITATION. SKIN: POSSIBLE IRRITATION OR SENSITIZATION. ING 2: INGEST: MOD TOX. SYMPS ARE NOT FULLY KNOWN, MAY INCL LOSS OF APPETITE & BLEEDING FROM NOSE. INHAL: IRRITATING TO UPPER RESP TRACT. MAY CAUSE NOSEBLEEDS. EYE: IRRITATING. (EFTS OF OVEREXP) Explanation of Carcinogenicity:NOT RELEVANT Effects of Overexposure:HLTH HAZ: SKIN: IRRITATION. CAN BE ABSORBED THRU SKIN IN HARMFUL AMTS. EFTS SIMILAR TO INGEST. ING 4: IRRITATING TO EYES & SKIN. CHRONIC: ING 2: SEE MSDS ADDENUM FOR ADDNL CHRONIC DATA. ING 4: NO CHRO NIC HEALTH EFFECTS ARE KNOWN. Medical Cond Aggravated by Exposure:ING 2: RESPIRATORY ILLNESS AND DERMATITIS MAY BE AGGRAVATED BY EXCESSIVE EXPOSURE. ======================= First Aid Measures ======================= First Aid:INGEST: DRINK 1-2 GLASSES OF WATER & INDUCE VOMIT BY PLACING FINGER @ BACK OF THROAT. CONSULT PHYS/POIS CTL CTR IMMED. INHAL: REMOVE FROM AREA TO FRESH AIR. EYE: IMMED BEGIN FLUSHING EYES W/COOL WATER , OCCAS LIFTING LIDS TO ENSURE THOROUGHRINSING. CONTINUE FOR @ LST 15 MIN, WHILE FLUSHING EYES, SEND FOR MED ASSIST. SKIN: WASH THORO W/SOAP AND WATER. ===================== Fire Fighting Measures ===================== Flash Point:>600F,>316C Lower Limits:40 GRAMS Extinguishing Media:FOAM, CARBON DIOXIDE, DRY CHEMICAL, WATER FOG, DRY SAND. Fire Fighting Procedures:WEAR NIOSH/MSHA APPROVED SCBA AND FULL PROTECTIVE EQUIPMENT . Unusual Fire/Explosion Hazard:DUST CLOUD OF 40 GRAMS PER CUBIC METER CAN BE IGNITED BY A SPARK OF 20 MILLIJOULES. ================== Accidental Release Measures ================== Spill Release Procedures:SWEEP UP CAREFULLY OR USE EXPLOSION-PROOF VACUUM CLEANER. Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER. ======================Handling and Storage ====================== Handling and Storage Precautions:KEEP ALL EQUIPMENT CLEAN AND PROPERLY GROUNDED TO AVOID STATIC ELECTRICITY BUILD-UP. KEEP WORK AREAS FREE OF DUST THROUGH ADEQUATE VENTILATION. Other Precautions:AVOID PROLONGED CONTACT W/SKIN. DO NOT INGEST. KEEP OUT OF REACH OF CHILDREN. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:USE A PROPERLY FITTED NIOSH/MSHA APPROVED MECHANICAL RESPIRATOR OR MASK TO AVOID BREATHING DUST. CAREFULLY FOLLOW RESP MFR'S INSTRUCTIONS FOR USE. Ventilation:PROVIDE SUFFICIENT VENT IN VOL & PATTERN TO KEEP AIR CONTAM CONC BELOW APPLIC OSHA PERMISSIBLE EXPOS LEVEL/ (SUPP DATA) Other Protective Equipment:PROTECTIVE OVERALLS RECOMMENDED. REMOVE AND WASH CONTAMINATED CLOTHING. Work Hygienic Practices:NONE SPECIFIED BY MANUFACTURER. Supplemental Safety and Health VENT: ACGIH'S TLV TWA LIMIT. ================== Physical/Chemical Properties ================== HCC:N1 Vapor Pres:SEE INGRED Appearance and Odor:NONE SPECIFIED BY MANUFACTURER. Percent Volatiles by Volume:0 ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES NONE SPECIFIED BY MANUFACTURER. Stability Condition to Avoid:STATIC ELECTRICAL CHARGES. Hazardous Decomposition Products:MAY PRODUCE FUMES WHEN HEATED TO DECOMPOSITION. FUMES MAY CONTAIN CARBON MONOXIDE, CARBON DIOXIDE, AND NO*2. ==================== Disposal Considerations ==================== Waste Disposal Methods:DISPOSE I/A/W LOCAL, STATE AND FEDERAL REGULATIONS. DO NOT INCINERATE CLOSED CONTAINERS.
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:MOLECULAR SIEVE TYPE 4A Resp. Party Other MSDS Num.:MSDS REV NO. 7 CAGE:02QC3 Contract Num:SP0450-00-M-SA49 CAGE:61134 Contract Num:SP0450-01-M-ZB26 CAGE:00334 CAGE:02QC3 ============= Composition/Information on Ingredients ============= Ingred Name:SILICON OXIDE (SYNTHETIC) CAS:112945-52-5 RTECS #:VV7310000 < Wt:50. Other REC Limits:NONE RECOMMENDED OSHA PEL:6 MG/M3 ACGIH TLV:10 MG/M3 Ingred Name:SODIUM OXIDE CAS:1313-59-3 < Wt:30. Other REC Limits:NONE RECOMMENDED Ingred Name:ALUMINUM OXIDE (NON-FIBROUS) CAS:1344-28-1 RTECS #:BD1200000 < Wt:30. Other REC Limits:NONE RECOMMENDED OSHA PEL:15 MG/M3 TDUST ACGIH TLV:10 MG/M3 TDUST; 9596 Ingred Name:MAGNESIUM OXIDE CAS:1309-48-4 RTECS #:OM3850000 < Wt:5. Other REC Limits:NONE RECOMMENDED OSHA PEL:15 MG/M3 PARTICULATE ACGIH TLV:10 MG/M3; FUME; 9596 ===================== Hazards Identification ===================== Routes of Entry: Inhalation:NOSkin:YES Ingestion:NO Reports of Carcinogenicity:NTP:NO IARC:UNKNOWN OSHA:NO Health Hazards Acute and Chronic:TARGET ORGAN: PROLONGED OR REPEATED EXPOSURE MAY CAUSE LUNG INJURY. SKIN-:THE PRODUCT DUST MAY DRY THE SKIN. THIS MATERIAL BECOMES HOT WHEN IT FIRST COMES INTO CONTACT W/ MOISTURE. THE HOT MATERIAL CO ULD CAUSE THERMAL BURNS. EYE-DUST &/OR PRODUCT MAY CAUSE EYE DISCOMFORT &/OR IRRITATION SEEN AS TEARING & REDDENING. INGESTION-THE PRODUCT GETS HOT AS IT ABSORBS WATER. BURNS TO MOIST BODY TISSUES CAN RESULT IF CONTACT IS PROLONGED. INHALATION-INHALATION OF PRODUCT &/OR DUST MAY CAUSE IRRITATION OF THE RESPIRATORY TRACT. IRRITATION MAY BE ACCOMPANIED BY COUGHING & CHEST DISCOMFORT. Explanation of Carcinogenicity:INTERNATIONAL AGENCY FOR RESEARCH ON CANCER (IARC): SILICON OXIDE (SYNTHETIC)-NOT CLASSIFIABLE AS HUMAN CARCINOGEN (GROUP 3). U.S. NATIONAL TOXICOLOGY PROGRAM (NTP): NEITHER THE PRODUCT NOR THE COMPON ENT(S) ARE CLASSIFIED. U.S. OCCUPATIONAL SAFETY AND HEALTH ADMINISTRATION (OSHA): NEITHER THE PRODUCT NOR THE COMPONENT(S) ARE CLASSIFIED OR REGULATED. ======================= First Aid Measures ======================= First Aid:SKIN: WASH AFFECTED AREA WITH SOAP AND WATER. EYE: FLUSH WITH WATER FOR AT LEAST 15 MINUTES. INGESTION: DRINK AT LEAST 2 GLASSES OF WATER. OBTAIN MEDICAL ATTENTION. INHALATION: REMOVE AFFECTED PERSON TO FRESH AIR. IF RESPIRATORY PROBLEMS DEVELOP, OBTAIN MEDICAL ATTENTION. NOTES TO PHYSICIAN: THIS PRODUCT IS A DESICCANT AND GENERATES HEAT AS IT ABSORBS WATER. THE USED PRODUCT CAN CONTAIN MATERIAL O F A HAZARDOUS NATURE. IDENTIFY THAT MATERIAL AND TREAT SYMPTOMATICALLY. ===================== Fire Fighting Measures ===================== Flash Point:NOT COMBUSTIBLE. Autoignition Temp:Autoignition Temp Text:NP Lower Limits:NOT GIVEN Upper Limits:NOT GIVEN Extinguishing Media:UNUSED MATERIAL WILL NOT BURN. USE MEDIA APPROPRIATE FOR SURROUNDING FIRE. Unusual Fire/Explosion Hazard:USED MATERIAL MAY CONTAIN MATERIALS OF A HAZARDOUS NATURE. THE USER OF THIS PRODUCT MUST IDENTIFY THE HAZARDS OF THE RETAINED MATERIAL AND INFORM THE FIRE FIGHTERS OF THESE HAZARDS. ================== Accidental Release Measures ================== Spill Release Procedures:SMALL SPILL: SWEEP OR VACUUM SPILLED PRODUCT INTO APPROPIATE CONTAINER (DO NOT USE A VACUUM IF MATERIAL HAS CONTACTED A HYDROCARBON). PRODUCT SHOULD BE DISPOSED OF IN ACCORDANCE WITH ALL APPLICABLE GO VERNMENT REGULATIONS. "SEE OTHER INFORMATION" ======================Handling and Storage ====================== Handling and Storage Precautions:STORE IN TIGHTLY CLOSED, PROPERLY LABELED CONTAINERS. A COPY OF UOP'S BOOKLET, " PRECAUTIONS AND SAFE PRACTICES FOR HANDLING MOLECULAR SIEVES IN PROCESS UNITS," M-1001, CAN BE OBTAINED FROM YOUR UOP R EPRESENTATIVE AT NO COST. Other Precautions:THIS PRODUCT (IN ITS FRESH UNUSED STATE) IS NOT LISTED BY GENERIC NAME OR TRADEMARK NAME IN THE U.S. EPA RESOURCE CONSERVATION & RECOVERY ACT (RCRA) HAZARDOUS WASTE MANAGEMENT REGULATIONS & DOES NOT P OSSESS ANY OF THE FOUR IDENTIFYING CHARACTERISTICS OF HAZARDOUS WASTE (IGNITABILITY, CORROSIVITY, RE ACTIVITY, TOXICITY). ============= Exposure Controls/Personal Protection ============= Respiratory Protection:WHERE NATURAL VENTILATION IS INADEQUATE, USE MECHANICAL VENTILATION, OTHER ENGINEERING CONTROLS, OR A TOXIC DUST RESPIRATOR ( IN USA - NIOSH/MSHA APPROVED) TO PREVENT INHALATION OF PRODUCT DUST. Ventilation:WHERE NATURAL VENTILATION IS INADEQUATE, USE MECHANICAL VENTILATION, OTHER ENGINEERING CONTROLS. SKIN CONTACT. CONTACT. Other Protective Equipment:WORK UNIFORM AS NECESSARY TO PREVENT REPEATED/ PROLONGED SKIN CONTACT. Supplemental Safety and Health PROUCT NAME: MOLECULAR SIEVE TYPE 4A. CHEMICAL NAME: SODIUM ALUMINOSILICATE. SYNONYMS: ZEOLITE. TRADE NAME: UOP MOLECULAR SIEVE. ================== Physical/Chemical Properties ================== HCC:N1 Boiling Pt:B.P. Text:NOT GIVEN Melt/Freeze Pt:M.P/F.P Text:NOT GIVEN Decomp Temp:Decomp Text:NOT GIVEN Vapor Pres:NOT GIVEN Vapor Density:NOT GIVEN Spec Gravity:1.1PC; 2.1CRYST pH:8 - 11 Viscosity:NA Evaporation Rate & Reference:NOT GIVEN Solubility in Water:NOT GIVEN Appearance and Odor:TAN PELLETS/BEADS, WHITE POWDER OR CAKE, ODOR:NONE. ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES SUDDEN CONTACT WITH HIGH CONCENTRATIONS OF CHEMICALS HAVING HIGH HEATS OF ADSORPTION SUCH AS OLEFINS, HCI, ETC. Stability Condition to Avoid:THE ADDITION OF MOISTURE (WATER) WITHOUT FLOODING CAN CAUSE RISE IN TEMPERATURE FROM HEAT OF ADSORPTION. CONTACT WITH SKIN MIGHT RESULT IN BURNS. Hazardous Decomposition Products:HYDROCARBONS/OTHER MATERIALS THAT CONTACT THE PRODUCT DURING NORMAL USE CAN BE RETAINED ON THE PRODUCT. IT IS REASONABLE TO EXPECT THAT DECOMPOSITION PRODUCT WILL COME FROM THE RETAINED MATERIALS USED. =================== Toxicological Information=================== Toxicological Information:ACUTE ORAL TOXICITY: THE FOLLOWING IS FOR A PRODUCT WITH A SIMILAR COMPOSITION. THE LD50 IS GREATER THAN 5 G/KG (RAT). ACUTE DERMAL TOXICITY: A DERMAL LD50 IS NOT AVAILABLE FOR THIS PRODUCT. ACUTE INH ALATION TOXICITY:AN INHALATION LC50 IS NOT AVAILABLE FOR THIS PRODUCT. IRRITATION: NOT AVAILABLE. ADDITIONAL TOXICOLOGICAL INFORMATION: A SIMILAR PRODUCT HAS AS EXTREMELY LOW ODRER OF TOXICITY BY SWLL OWING. THIS SIMILAR PELLETS WERE PULVERIZED & SUSPENDED IN SEMI-SOLID AGAR FOR EASE OF ADMINISTRATION. WHEN THE MOLECULAR SIEVE WAS ADMINISTERED BY STOMACH INTUBATION TO MALE RATS, THE ANIMALS SURVIVE D MASSIVE DOSES EQUIVALENT TO 32.0 G/K ===================== Ecological Information ===================== Ecological:AQUATIC TOXICITY: NONE KNOWN. WATERFOWL TOXICITY: NONE KNOWN. BIOCHEMICAL OXYGEN DEMAND: NONE. FOOD CHAIN CONCENTRATION POTENTIAL: NONE EXPECTED. ==================== Disposal Considerations ==================== Waste Disposal Methods:DISCARD ANY PRODUCT (INCLUDING ANY RETAINED MATERIALS OF USE), DISPOSABLE CONTAINER OR LINER IN AN ENVIRONMENTALLY ACCEPTABLE MANNER, IN FULL COMPLIANCE WITH ALL APPLICABLE GOVERRNMENT REGULATIONS. "S EE OTHER PRECAUTION" =================== MSDS Transport Information =================== Transport Information:US DEPARTMENT OF TRANSPORTATION SHIPPING NAME: NOT REGULATED. INTERNATIONAL MARITIME ORGANIZATION (IMO): NOT REGULATED. ===================== Regulatory Information ===================== SARA Title III Information:SUPERFUND AMENDMENTS & REAUTHORIZATION ACT TITLE II, SECTION 313: THE FOLLOWING COMPONENT(S) OF THIS PRODUCT ARE SUBJECT TO RELEASE REPORTING UNDER 40 CFR 302 WHEN A RELEASE EXCEEDS THE REPORTABLE QUA NTITY (RQ) &/OR THE COMPONENT(S)ARE SUBJECT TO THE EMERGENCY PLANNING PROVISIONS OF 40 CFR 355 WHEN THERE ARE AMOUNTS PRESENT WHICH ARE EQUAL TO OR GREATER THAN THEIR THRESHOLD PLNNING QUANTITY (TPQ). -NONE-. SUPERFUND AMENDMENTS & REAUTHORIZATION ACT TITLE III: NO COMPONENTS OF THIS PRODUCT ARE SUBJECT TO EMERGENCY PLANNING BASED ON TPQ`S & RELEASE REPORTING BASED ON RQ`S IN 40 CFR 355 (USED FOR SARA 302, 304, 311 & 312). Federal Regulatory Information:TOXIC SUBSTANCES CONTROL ACT (TSCA): ALL THE INGREDIENTS OF THIS MIXTURE ARE REGISTERED IN THE TSCA CHEMICAL SUBSTANCE INVENTORY. State Regulatory Information:STATE COMMUNITY RIGHT-TO-KNOW LEGISLATION: THE FOLLOWING COMPONENTS OF THIS PRODUCT ARE REGULATED UNDER CALIFORNIA`S PROPOSITION 65: NONE. ======================= Other Information =======================
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:CGL 1330 Preparer's Name:PETER HENIGE CAGE:CIBAG CAGE:02684 CAGE:CIBAG ============= Composition/Information on Ingredients ============= Ingred Name:FIBERGLASS CLOTH Ingred Name:2-ETHYL-4-METHYLIMIDAZOLE CAS:931-36-2 Ingred Name:DIGLYCIDYL ETHER OF BISPHENOL A;(EPOXY RESIN) CAS:25085-99-8 Ingred Name:2,4 & 2,6-DIMETHYLENE PHENOL GLYCIDYL ETHER POLYMER;(EPOXY PHENOLIC NOVOLAC) CAS:28064-14-4 Ingred Name:AMINE ADDUCT CAS:68738-77-2 Ingred Name:GRAPHITE CLOTH ===================== Hazards Identification ===================== LD50 LC50 Mixture:NONE SPECIFIED BY MANUFACTURER. Routes of Entry: Inhalation:NOSkin:NO Ingestion:NO Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:SKIN/EYE: IRRITANT. ACUTE: IRRITATION, SENSITIZATION AND DERMATITIS. Explanation of Carcinogenicity:NOT RELEVANT. Effects of Overexposure:SEE HEALTH HAZARDS. Medical Cond Aggravated by Exposure:SKIN AND EYE CONDITIONS. ======================= First Aid Measures ======================= First Aid:EYES: IMMED FLUSH WITH WATER FOR AT LEAST 15 MIN. CALL PHYS. SKIN: WASH WITH SOAP AND WATER. REMOVE CONTAMD CLOTHING AND LAUNDER BEFORE REUSE. INGEST: IF CONSCIOUS, GIVE PLENTY OF WATER TO DRINK. DO N OT INDUCE VOMITING. CALL PHYS. INHAL: REMOVE TO FRESH AIR. GIVE O*2/ARTF RESP, IF NEEDED. CALL PHYS. REFERRAL TO PHYS IS RECOMMENDED IF THERE IS ANY QUESTION ABOUT THE SERIOUSNESS OF ANY INJURY. ===================== Fire Fighting Measures ===================== Extinguishing Media:CARBON DIOXIDE, FOAM, DRY CHEMICAL, WATER SPRAY. Fire Fighting Procedures:USE NIOSH/MSHA APPROVED SCBA & FULL PROTECTIVE EQUIPMENT . Unusual Fire/Explosion Hazard:DECOMPOSITION AND COMBUSTION PRODUCTS MAY BE TOXIC. ================== Accidental Release Measures ================== Spill Release Procedures:COLLECT AND PLACE INTO A CLOSABLE CONTAINER FOR DISPOSAL. WEAR NIOSH/MSHA APPROVED ORGANIC VAPOR. Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER. ======================Handling and Storage ====================== Handling and Storage Precautions:WARNING! CAUSES SKIN/EYE IRRIT. MAY CAUSE ALLERGIC SKIN RXN. DO NOT HEAT IN BULK AS DANGEROUS DECOMP MAY OCCUR, LIBERATING TOXIC FUMES. Other Precautions:AVOID CONT W/EYES/SKIN/CLTHG. AVOID PRLNG/RPTD CONT W/SKIN. AVOID BRTHG VAPORS/MIST. STORE IN COOL, DRY AREA IN CLSD CONTR. USE W/ADEQ VENTILATION. WASH THOROUGHLY AFTER HANDLING. KEEP CONTR CLSD WHEN NOT IN USE & DURING TRANSPORT.(SUPDAT) ============= Exposure Controls/Personal Protection ============= Respiratory Protection:USE NIOSH/MSHA APPROVED ORGANIC VAPOR CARTRIDGE RESPIRATOR WHEN VAPOR/MIST EXPOSURE IS LIKELY. Ventilation:GOOD GENERAL MECHANICAL VENTILATION AND LOCAL EXHAUST ARE REQUIRED TO MEET THE RECOMMENDED TWA. Other Protective Equipment:WEAR PROTECTIVE CLOTHING. APPLY BARRIER CREAM FOR THE PROTECITON OF EXPOSED SKIN. Work Hygienic Practices:NONE SPECIFIED BY MANUFACTURER. Supplemental Safety and Health OTHER PREC: RECOMMENDED STORAGE TEMPERATURE IS 0 TO 15F. BRING TO ROOM TEMPERATURE BEFORE REUSE. ================== Physical/Chemical Properties ================== HCC:N1 Decomp Temp:Decomp Text:392F,200C Solubility in Water:INSOLUBLE Appearance and Odor:LIGHT YELLOW RESIN ON FABRIC. Percent Volatiles by Volume:NEGLIG ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES STRONG OXIDIZERS, ACIDS AND BASES. Stability Condition to Avoid:CONDITIONS OVER 200F. Hazardous Decomposition Products:THERMAL DECOMPOSITION & BURNING MAY PRODUCE CO, CO*2, NITROGEN OXIDES & OTHER TOXIC ORGANIC SPECIES. Conditions to Avoid Polymerization:DO NOT HEAT IN BULK, DANGEROUS EXOTHERMIC REACTION MAY OCCUR. ==================== Disposal Considerations ==================== Waste Disposal Methods:DISPOSE OF IN ACCORDANCE WITH FEDERAL, STATE AND LOCAL REGULATIONS.
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:SWEEPING COMPOUND II CAGE:FLOOR CAGE:FLOOR ============= Composition/Information on Ingredients ============= Ingred Name:NO INGREDIENT FOR THIS FORMULATION_INGREDIENT ===================== Fire Fighting Measures ===================== Flash Point Method:PMCC Flash Point:125F/51.67C Extinguishing Media:WATER Fire Fighting Procedures:NONE REQUIRED. Unusual Fire/Explosion Hazard:NONE ================== Accidental Release Measures ================== Spill Release Procedures:SWEEP UP. ======================Handling and Storage ====================== Handling and Storage Precautions:NONE REQUIRED. Other Precautions:NONE REQUIRED. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:NONE REQUIRED. Ventilation:NONE REQUIRED. Other Protective Equipment:NONE REQUIRED. Supplemental Safety and Health ================== Physical/Chemical Properties ================== Appearance and Odor:LOOKS LIKE SAWDUST-SMELLS WAXY. ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES STRONG OXIDIZERS. ==================== Disposal Considerations ==================== Waste Disposal Methods:WITH ORDINARY TRASH.
0
eyes_protection_not_mandatory
===================== Product Identification ===================== Product ID:PC/UA 946-436 KONICA TONER RED 8028 150G Preparer's Name:TATESHI LITAKA CAGE:89431 CAGE:89431 ============= Composition/Information on Ingredients ============= Ingred Name:POLYESTER RESIN Ingred Name:PIGMENT (RED I, II) Ingred Name:WAX-1,3 Ingred Name:DYE Ingred Name:SILICON DIOXIDE, CELITE 322 CAS:7631-86-9 RTECS #:VV3100000 Fraction by Wt: <1% OSHA PEL:80 MG/CUM ACGIH TLV:0.2 MG/CUM Ingred Name:TITANIUM DIOXIDE, TIO2 CAS:13463-67-7 RTECS #:XR2275000 Fraction by Wt: <1% OSHA PEL:15 MG/M3 TDUST ACGIH TLV:10 MG/M3 TDUST; 9293 ===================== Hazards Identification ===================== LD50 LC50 Mixture:LD50 ORAL (RAT): >5,000 MG/KG Routes of Entry: Inhalation:YES Skin:NO Ingestion:NO Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:MINIMAL RESPIRATORY TRACT IRRITATION MAY OCCUR AS W/EXPOSURE TO LARGE AMOUNT OF ANY NON-TOXIC DUST. Explanation of Carcinogenicity:NONE ======================= First Aid Measures ======================= First Aid:INGESTION: DILUTE STOMACH CONTENTS W/SEVERAL GLASSES OF WATER. INHALATION: REMOVE TO FRESH AIR. EYES: FLUSH W/WATER. SKIN: WASH W/SOAP & WATER. OBTAIN MEDICAL ATTETNION IN ALL CASES. ===================== Fire Fighting Measures ===================== Extinguishing Media:WATER, FOAM, OR DRY CHEMICAL. IF FIRE IS IN THE MACHINE TREAT AS AN ELECTRIC FIRE, DON'T USE WATER. Fire Fighting Procedures:AVOID INHALATION OF SMOKE. Unusual Fire/Explosion Hazard:TONER IS A COMBUSTIBLE POWDER. WHEN DISPARSED IN AIR, IT FORMS EXPLOSIVE MIXTURES. ================== Accidental Release Measures ================== Spill Release Procedures:MINIMIZE DUSTING SITUATION & SWEEP UP OR VACUUM. ======================Handling and Storage ====================== Handling and Storage Precautions:KEEP FROM CONTACT W/OXIDIZING MATERIALS. KEEP OUT OF REACH OF CHILDREN. AVOID INHALATION OF SMOKE. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:AS REQUIRED Supplemental Safety and Health SOFTENING RANGE: 140C. FLAMMABLE LIMITS: 20G/CUM IN AIR (LOWER LIMIT). ================== Physical/Chemical Properties ================== Vapor Pres:NEGLIGIBLE Spec Gravity:1.1 Evaporation Rate & Reference:NEGLIGIBLE Solubility in Water:NEGLIGIBLE Appearance and Odor:RED FINE POWDER W/SLIGHT MILD ODOR. ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES STRONG OXIDIZERS Stability Condition to Avoid:TEMP >200C Hazardous Decomposition Products:CO & CO2 ==================== Disposal Considerations ==================== Waste Disposal Methods:DISPOSE OF IN ACCORDANCE W/LOCAL, STATE, & FEDERAL REGULATIONS.
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:GERMANIUM OXIDE, GE70-20 Preparer's Name:SUSHA RAMONE CAGE:04XT3 CAGE:04XT3 ============= Composition/Information on Ingredients ============= Ingred Name:GERMANIUM DIOXIDE CAS:1310-53-8 RTECS #:LY5240000 Fraction by Wt: 100% OSHA PEL:N/K ACGIH TLV:N/K ===================== Hazards Identification ===================== LD50 LC50 Mixture:LD50 (ORAL RAT): 1910 MG/KG. Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:ACUTE: THIS SOLUTION MAY BE HARMFUL IF INHALED, INGESTED, OR CONTACTED WITH THE SKIN OR EYES. INHALATION MAY CAUSE RESPIRATORY TRACT IRRITATION. CONTACT WITH SKIN OR EYES MAY BE IRRITATING. CHRONIC: N ONE SPECIFIED BY MANUFACTURER. Explanation of Carcinogenicity:NOT RELEVANT. Effects of Overexposure:SEE HEALTH HAZARDS. Medical Cond Aggravated by Exposure:NONE SPECIFIED BY MANUFACTURER. ======================= First Aid Measures ======================= First Aid:EYES: FLUSH WITH WATER FOR AT LEAST 15 MINUTES OCCASIONALLY LIFTING UPPER AND LOWER EYELIDS. SKIN: REMOVE CONTAMINATED CLOTHING, THE FLUSH WITH WATER FOR AT LEAST 15 MINUTES. WASH CLOTHING THOROUGHLY BEFORE REUSE. INHAL: MOVE TO FRESH AIR.INGEST: DO NOT INDUCE VOMITING. GET IMMED MEDICAL HELP. IF CONSCIOUS, GIVE LARGE QUANTITY OF WATER/MILK. IF IRRIT CONTINUES, GET MEDICAL ATTENTION IMMED. ===================== Fire Fighting Measures ===================== Flash Point:NOT COMBUSTIBLE Extinguishing Media:APPROPRIATE TO SURROUNDING FIRE CONDITIONS. Fire Fighting Procedures:NONE. WEAR NIOSH APPROVED SCBA & FULL PROTECTIVE EQUIPMENT . Unusual Fire/Explosion Hazard:MAY EMIT TOXIC FUMES. ================== Accidental Release Measures ================== Spill Release Procedures:EVACUATE AND VENTILATE AREA. SWEEP UP AND PLACE IN BAG. HOLD FOR DISPOSAL. WEAR PROTECTIVE CLOTHING. Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER. ======================Handling and Storage ====================== Handling and Storage Precautions:STORE AT ROOM TEMPERATURE. KEEP TIGHTLY SEALED WHEN NOT IN USE. Other Precautions:NONE SPECIFIED BY MANUFACTURER. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:NIOSH APPROVED RESPIRATOR. Ventilation:CHEMICAL FUME HOOD. Other Protective Equipment:EMERGENCY EYEWASH AND DELUGE SHOWER MEETING ANSI DESIGN CRITERIA . LAB COAT. Work Hygienic Practices:NONE SPECIFIED BY MANUFACTURER. Supplemental Safety and Health MP: >1987F, >1806C. SOL IN WATER: COLD-0.447G/100CC; HOT-1.07G/100CC. ================== Physical/Chemical Properties ================== Melt/Freeze Pt:M.P/F.P Text:SUP DAT Spec Gravity:4.228 Solubility in Water:SUP DAT Appearance and Odor:COLORLESS POWDER ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES NONE SPECIFIED BY MANUFACTURER. Stability Condition to Avoid:NONE SPECIFIED BY MANUFACTURER. Hazardous Decomposition Products:TOXIC FUMES. ==================== Disposal Considerations ==================== Waste Disposal Methods:CONTACT LOCAL HAZARDOUS OR CHEMICAL WASTE DISPOSAL AGENCY FOR REGULATIONS. DISPOSE OF IN ACCORDANCE WITH LOCAL, STATE AND FEDERAL REGULATIONS .
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:QIAQUICK NUCLEOTIDE REMOVAL KIT,28304,28306 CAGE:01QTQ CAGE:01QTQ ============= Composition/Information on Ingredients ============= Ingred Name:TRIS(HYDROXYMETHYL)AMINOMETHANE (AQUEOUS SOLUTION MIXED WITH HYDROCHLORIC ACID) CAS:77-86-1 RTECS #:TY2900000 Ingred Name:HYDROCHLORIC ACID CAS:7647-01-0 RTECS #:MW4025000 OSHA PEL:C7 MG/M3;C5 PPM ACGIH STEL:C7.5 MG/M3;C5 PPM EPA Rpt Qty:5000 LBS DOT Rpt Qty:5000 LBS ===================== Hazards Identification ===================== Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:ACUTE: INHALATION: MAY BE HARMFUL BY INHALATION. EYE/SKIN CONTACT: MAY CAUSE IRRITATION. INGESTION: MAY BE HARMFUL IF SWALLOWED. CHRONIC: NOT APPLICABLE. Effects of Overexposure:SEE HEALTH HAZARDS. ======================= First Aid Measures ======================= First Aid:CALL MD. REMOVE AND WASH CONTAMINATED CLOTHING PROMPTLY. EYES: IMMEDIATLEY FLUSH WITH COPIOUS AMOUNTS OF WATER FOR AT LEAST 15 MINUTES. ASSURE ADEQUATE FLUSHING BY SEPARATING LIDS WITH FINGERS. SKIN: IMMEDIATELY WASH WITH SOAP AND COPIOUS AMOUNTS OF WATER. INHALATION: REMOVE TO FRESH AIR. IF NOT BREATHING GIVE ARTIFICIAL RESPIRATION. IF BREATHING IS DIFFICULT, GIVE OXYGEN. INGESTION: WASH OUT MOUT H WITH WATER PROVIDED PERSON IS CONSCIOUS. ===================== Fire Fighting Measures ===================== Extinguishing Media:NONCOMBUSTIBLE. USE EXTINGUISHING MEDIA APPROPRIATE TO SURROUNDING FIRE CONDITIONS. Fire Fighting Procedures:USE NIOSH APPROVED SCBA AND FULL PROTECTIVE EQUIPMENT . ================== Accidental Release Measures ================== Spill Release Procedures:WEAR NIOSH APPROVED SELF-CONTAINED BREATHING CONTAINERS FOR DISPOSAL. VENTIL ATE AREA AND WASH SPILL SITE AFTER MATERIAL PICKUP IS COMPLETE. ======================Handling and Storage ====================== Handling and Storage Precautions:STORE TIGHTLY CLOSED AT 20-25C. KEEP TIGHTLY CLOSED. DO NOT GET IN EYES, ON SKIN, OR ON CLOTHING. DO NOT BREATHE VAPOR. SEVERE EYE IRRITANT. STORE IN A DRY PLACE. Other Precautions:THE PRODUCT SHOULD BE HANDLED WITH THE NORMAL CAUTION ACCORDED CHEMICALS. ADDITIONAL HARMFUL PROPERTIES CANNOT BE RULED OUT. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:NIOSH APPROVED RESPIRATOR. Ventilation:MECHANICAL EXHAUST REQUIRED. Other Protective Equipment:ANSI APPROVED EYE WASH & DELUGE SHOWER . LAB COATS. Work Hygienic Practices:WASH THOROUGHLY AFTER HANDLING. Supplemental Safety and Health ================== Physical/Chemical Properties ================== Vapor Pres:NOT APPLICABLE (20C) Spec Gravity:0.985 G/CM3 @ 20C pH:7.7 @ 20C Viscosity:NOT APPLICABLE (20C) Solubility in Water:S0LUBLE Appearance and Odor:COLORLESS LIQUID; NO ODOR. ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES NOT APPLICABLE. Hazardous Decomposition Products:NOT APPLICABLE. =================== Toxicological Information=================== Toxicological Information:NOT APPLICABLE. ===================== Ecological Information ===================== Ecological:NOT APPLICABLE, ==================== Disposal Considerations ==================== Waste Disposal Methods:FOR SMALL QUANTITIES, FLUSH DOWN SINK WITH WATER. OBSERVE ALL FEDERAL, STATE AND LOCAL LAWS. =================== MSDS Transport Information =================== Transport Information:NOT APPLICABLE. ===================== Regulatory Information ===================== SARA Title III Information:NOT APPLICABLE. Federal Regulatory Information:NOT APPLICABLE. State Regulatory Information:NOT APPLICABLE. ======================= Other Information =======================
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:204 PLASTIC ROOF CEMENT Preparer's Name:GEORGE MARCINA CAGE:EO927 CAGE:64841 CAGE:11761 CAGE:EO927 ============= Composition/Information on Ingredients ============= Ingred Name:LIGHT ALIPHATIC NAPHTHA, VM & P NAPHTHA, LACOLENE*93/1* CAS:64742-89-8 Fraction by Wt: 15-20% OSHA PEL:300 PPM ACGIH TLV:300 PPM Ingred Name:ASBESTOS (BULK), AMPHIBOLE, ASBESTOS FIBER, SERPENTINE (A1 HUMAN CARCINOGEN BY IARC, NTP, OHSA, & ACGIH. CAS:1332-21-4 RTECS #:CI6475000 Fraction by Wt: 12-14% Other REC Limits:A1 HUMAN CARCINOGEN OSHA PEL:2 FB/CC ACGIH TLV:2 FB/CC EPA Rpt Qty:1 LB DOT Rpt Qty:1 LB Ingred Name:WEIGHT PER GALLON IN POUNDS: 10 RTECS #:9999999WG ===================== Hazards Identification ===================== Routes of Entry: Inhalation:YES Skin:NO Ingestion:NO Reports of Carcinogenicity:NTP:YES IARC:YES OSHA:YES Health Hazards Acute and Chronic:VAPORS MAY ASPHYXIATE Explanation of Carcinogenicity:SEE INGREDIENTS ======================= First Aid Measures ======================= First Aid:INHALATION: REMOVE TO FRESH AIR. IF BREATHING STOPS, GIVE ARTIFICAL RESPIRATION. SKIN: WASH W/SOAP & WATER. EYES: FLUSH W/WATER FOR 15 MINS. DON'T USE SOLVENTS. INGESTION: DON'T INDUCE VOMITING. OBTA IN MEDICAL ATTENTION IN ALL CASES. ===================== Fire Fighting Measures ===================== Flash Point:120F Lower Limits:1% Extinguishing Media:FOAM, CO2, DRY CHEMICAL ================== Accidental Release Measures ================== Spill Release Procedures:EXTINGUISH ALL SOURCES OF IGNITION IN THE AREA. CLEAN UP SPILLS AS SOON AS POSSIBLE. ABSORB SPILLED MATERIAL W/CLAY, DIATOMACEOUS EARTH OR OTHER NON-FLAMMABLE ABSORBANT MATERIAL. ======================Handling and Storage ====================== Handling and Storage Precautions:STORE AWAY FROM HEAT AND SOURCES OF IGNITION. VAPORS ABOVE TLV MAY ASPHYXIATE. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:AS REQUIRED Ventilation:USE SUPPLIED AIR SYSTEM IF VAPOR CONCENTRATIONS EXCEED TLV Work Hygienic Practices:CLEAN SKIN W/SOAP & WATER OR WATERLESS HAND CLEANER. DON'T USE SOLVENTS. Supplemental Safety and Health ================== Physical/Chemical Properties ================== Boiling Pt:B.P. Text:310-400F Vapor Density:>1 Evaporation Rate & Reference:SLOWER THAN ETHER Percent Volatiles by Volume:25-30 ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES STRONG OXIDIZING AGENTS Stability Condition to Avoid:HEAT & SOURCES OF IGNITION Hazardous Decomposition Products:BLACK SMOKE, CO2 & CO ==================== Disposal Considerations ==================== Waste Disposal Methods:DISPOSE OF IN ACCORDANCE W/LOCAL, STATE, & FEDERAL REGULATIONS.
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:BATTERY,STORAGE Preparer's Name:DGSC-SSH CAGE:33825 CAGE:33825 ============= Composition/Information on Ingredients ============= Ingred Name:CADMIUM (SARA III) CAS:7440-43-9 RTECS #:EU9800000 Other REC Limits:NONE SPECIFIED OSHA PEL:SEE 1910.1027 ACGIH TLV:0.01 MG/M3 DUST;9394 EPA Rpt Qty:10 LBS DOT Rpt Qty:10 LBS Ingred Name:CADMIUM HYDROXIDE CAS:21041-95-2 Other REC Limits:NONE SPECIFIED OSHA PEL:0.1 MG/M3 (CD FUME) ACGIH TLV:0.05 MG/M3 (CD FUME) Ingred Name:NICKEL (SARA III) CAS:7440-02-0 RTECS #:QR5950000 Other REC Limits:NONE SPECIFIED OSHA PEL:1 MG/M3 ACGIH TLV:1 MG/M3; 9192 Ingred Name:NICKEL HYDROXIDE (SARA III) CAS:12054-48-7 RTECS #:QR7040000 Other REC Limits:NONE SPECIFIED OSHA PEL:1 MG NI/M3 ACGIH TLV:0.1 MG NI/M3; 9293 EPA Rpt Qty:10 LBS DOT Rpt Qty:10 LBS Ingred Name:POTASSIUM HYDROXIDE (SARA III) CAS:1310-58-3 RTECS #:TT2100000 Other REC Limits:NONE SPECIFIED OSHA PEL:C, 2 MG/M3 ACGIH TLV:C 2 MG/M3; 9192 EPA Rpt Qty:1000 LBS DOT Rpt Qty:1000 LBS ===================== Hazards Identification ===================== Routes of Entry: Inhalation:YES Skin:YES Ingestion:NO Reports of Carcinogenicity:NTP:YES IARC:YES OSHA:YES Health Hazards Acute and Chronic:ACUTE-IF BATTERY SPILLS:EYES/SKIN: CAN CAUSE BURNS AND PERMANENT INJURY DUE TO CAUSTIC POTASSIUM HYDROXIDE(KOH). CADMIUM AND NICKEL AND THEIR COMPOUNDS CAN CAUSE CHRONIC HEALTH PROBLEMS SUCH AS CANCER , RENAL FAILURE AND RESPIRATORY PROBLEMS. Explanation of Carcinogenicity:NICKEL AND CADMIUM AND THEIR COMPOUNDS ARE KNOWN OR SUSPECT CARCINOGENS. Effects of Overexposure:EYE AND SKIN BURNS FROM POTASSIUM HYDROXIDE. CENTRAL NERVOUS SYSTEM DISORDERS AND CANCERS FROM LONG TERM EFFECTS OF HEAVY METAL POISONING. Medical Cond Aggravated by Exposure:PERSONS WITH SKIN AND RESPIRATORY DISORDERS MAY BE AT INCRESED RISK FROM EXPOSURE. ======================= First Aid Measures ======================= First Aid:SEE A DOCTOR IN ALL CASES.SKIN:FLUSH WITH PLENTY OF WATER.EYE CONTACT:FLUSH WITH WATER FOR 15 MINUTES WHILE HOLDING EYELIDS OPEN.INHALATION:REMOVE TO FRESH AIR.PROVIDE CPR/OXYGEN IF NEEDED.INGESTION:C ALL A PHYSICIAN. ===================== Fire Fighting Measures ===================== Extinguishing Media:USE WATER FOG, CARBON DIOXIDE, FOAM, OR DRY CHEMICAL AS APPROPRIATE FOR SURROUNDINGS Fire Fighting Procedures:FIRE FIGHTERS SHOULD USE NIOSH APPROVED SCBA & FULL PROTECTIVE EQUIPMENT WHEN FIGHTING CHEMICAL FIRE. USE WATER SPRAY TO COOL NEARBY CONTAINERS EXPOSED TO FIRE. Unusual Fire/Explosion Hazard:FIRE OR EXCESSIVE HEAT MAY CAUSE PRODUCTION OF HAZARDOUS DECOMPOSITION PRODUCTS SUCH AS HEAVY METAL FUMES AND DUST OF CADMIUM OXIDE. ================== Accidental Release Measures ================== Spill Release Procedures:AVOID EYE AND SKIN CONTACT. PROVIDE VENTILATION. NEUTRALIZE WITH ACETIC ACID. TRANSFER TO APPROPRIATE CONTAINERS FOR DISPOSAL. Neutralizing Agent:5% ACETIC ACID OR VINEGAR ======================Handling and Storage ====================== Handling and Storage Precautions:STORAGE-STORE AT ROOM TEMPERATURE IN A DRY PLACE AWAY FROM EXCESSIVE HEAT AND FLAMES. Other Precautions:DO NOT BREATHE VAPORS/MIST. AVOID CONTACT WITH EYES AND SKIN. WASH THOROUGHLY AFTER HANDLING. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:NON REQUIRED UNDER NORMAL CONDITIONS.IF WORKING IN A CONFINED AREA OR MISTING IS OCCURRING, USE NIOSH-APPROVED SELF-CONTAINED BREATHING APPARATUS. Ventilation:GOOD VENTILATION Other Protective Equipment:RUBBER OR PLASTIC GARMENTS. Work Hygienic Practices:AVOID EYE/SKIN CONTACT WITH LEAKING BATTERIES. Supplemental Safety and Health NO MSDS WAS AVAILABLE FROM MANUFACTURER. THIS MSDS WAS PREPARED BY THE PROFESSIONALS OF DGSC-SSH WITHOUT ANY WARRANTY. IT IS THE USER'S RESPONSIBILITY TO GATHER INFORMATION AND USE THE MATERIAL PROPER LY TO PROTECT EMPLOYEES AND ENVIRONMENT. ================== Physical/Chemical Properties ================== HCC:B1 pH:>13 Appearance and Odor:STORAGE BATTERY ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES ACIDS. Stability Condition to Avoid:HIGH TEMPERATURE, FLAMES Hazardous Decomposition Products:BATTERY MAY EMIT HAZARDOUS VAPORS OF POTASSIUM HYDROXIDE AND CADMIUM AND NICKEL AND THEIR COMPOUNDS WHEN HEATED. ==================== Disposal Considerations ==================== Waste Disposal Methods:DO NOT INCINERATE. SEND FOR RECYCLING. DISPOSE OF IN ACCORDANCE WITH ALL LOCAL, STATE AND FEDERAL REGULATIONS.
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:QUAKER STATE 2-CYCLE OUTBOARD LUBRICANT CAGE:DO899 CAGE:DO899 ============= Composition/Information on Ingredients ============= Ingred Name:STODDARD SOLVENT CAS:8052-41-3 RTECS #:WJ8925000 Fraction by Wt: 17% OSHA PEL:500 PPM ACGIH TLV:100 PPM; 9293 Ingred Name:MINERAL OIL (EXPOSURE REGULATED AS 'OIL MIST') CAS:8012-95-1 RTECS #:PY8030000 Fraction by Wt: >75% OSHA PEL:5 MG/M3 ACGIH TLV:5 MG/M3/10 STEL;9192 ===================== Hazards Identification ===================== Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES Health Hazards Acute and Chronic:ACUTE: SWALLOWING-IRRITATION TO MOUTH AND THROAT. MAY ALSO CAUSE NAUSEA AND DIARRHEA. HOWEVER, ASPIRATION OF HYDROCARBON LIQUIDS INTO THE LUNGS MAY CAUSE PNEUMONITIS. SKIN ABSORPTION-NO DATA AVAILABLE . INHALATION-IRRITATION TO RESPIRATORY PASSAGES AT LOW LEVELS. THE CREATION OF VAPORS AND MISTS IS UNLIKELY. Effects of Overexposure:SKIN CONTACT-STODDARD SOLVENT IS A DEFATTING AGENT. PROLONGED AND REPEATED CONTACT MAY CAUSE DERMATITIS. EYE CONTACT-MAY CAUSE EYE IRRITATION IF CONTACT OCCURS. ======================= First Aid Measures ======================= First Aid:SWALLOWING: IF MATERIAL IS SWALLOWED, DO NOT INDUCE VOMITING AND CONTACT A PHYSICIAN. SKIN-WASH SKIN THOROUGHLY WITH SOAP AND WATER. LAUNDER SOILED CLOTHING. INHALATION-ALTHOUGH INHALATION OF THIS MAT ERIAL IS UNLIKELY, IF RESPIRATORY DISCOMFORT OR IRRITATION OCCURS DUE TO INHALATION MOVE PERSON TO FRESH AIR. CONTACT A PHYSICIAN IF DISCOMFORT OR IRRITATION CONTINUES. EYES-FLUSH WITH WATER FOR 15MIN ===================== Fire Fighting Measures ===================== Flash Point Method:COC Flash Point:135 F Extinguishing Media:CO2, DRY CHEMICAL, FOAM, WATER FOG. H20 MAY BE INEFFECTIVE IN FIGHTING AN OIL FIRE UNLESS USED BY EXPERIENCED FIRE FIGH Fire Fighting Procedures:FOR LARGE STORAGE FIRES-DO NOT ENTER ANY ENCLOSED OR CONFINED SPACE WITHOUT FULL PROTECTIVE EQUIPMENT INCLUDING SELF-CONTAINED BREATHING APPARATUS. Unusual Fire/Explosion Hazard:AS LIQUID EVAPORATES, VAPORS ARE FORMED WHICH CAN IGNITE. THESE VAPORS SPREAD TO LOW AREAS AND MAY BE IGNITED BY VARYING SOURCES. ================== Accidental Release Measures ================== Spill Release Procedures:CLEAN UP SPILLS AS SOON AS POSSIBLE. ABSORB LARGE SPILLS WITH COMMERCIALLY AVAILABLE ABSORBENT MATERIALS, SUCH AS ABSORBENT CLAY. ======================Handling and Storage ====================== Handling and Storage Precautions:COMBUSTIBLE LIQUID (135 F-FLASH POINT): DO NOT STORE NEAR HEAT OR OPEN FLAMES. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:NOT APPLICABLE FOR INTENDED USE. HOWEVER, IF UNUSUAL OPERATING CONDITIONS CREATE CONCENTRATIONS IN EXCESS OF THE TLV, AN APPROVED RESPIRATOR IS RECOMMENDED. Ventilation:NONE NEEDED FOR INTENDED USE. SPECIAL VENTILATION IS NECESSARY ONLY IF UNUSUAL OPERATING CONDITIONS CREATE CONCENTRATION Other Protective Equipment:NONE NORMALLY NECESSARY FOR INTENDED USE. Supplemental Safety and Health ================== Physical/Chemical Properties ================== Boiling Pt:B.P. Text:>310 F Vapor Pres:N/D Vapor Density:>1 Spec Gravity:.87 Evaporation Rate & Reference:<1 Solubility in Water:NIL Appearance and Odor:GREEN LIQUID. HYDROCARBON ODOR. Percent Volatiles by Volume:17 ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES STRONG OXIDIZING AGENTS Stability Condition to Avoid:HIGH TEMPERATURES AND OPEN FLAME. Hazardous Decomposition Products:CARBON DIOXIDE, WATER VAPOR. MAY PRODUCE OXIDES OF SULPHUR, NITROGEN AND PHOSPHORUS. Conditions to Avoid Polymerization:HIGH TEMPERATURES AND OPEN FLAME. ==================== Disposal Considerations ==================== Waste Disposal Methods:PLACE CONTAMINATED MATERIAL IN DISPOSABLE CONTAINERS AND BURY IN AN APPROVED LANDFILL SITE PER LOCAL, STATE AND FEDERAL REGULATIONS.
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:HYVAR X HERBICIDE M0000018 CAGE:18873 CAGE:76415 CAGE:0AGD9 CAGE:18873 CAGE:0FHX3 CAGE:1HB45 ============= Composition/Information on Ingredients ============= Ingred Name:BROMACIL CAS:314-40-9 RTECS #:YQ9100000 Fraction by Wt: 80.0% Other REC Limits:10 MG/M3 DU PONT ACGIH TLV:10 MG/M3 8HR TWA Ingred Name:INERT INGREDIENTS. (NON HAZARDOUS) DIURON DUPONT ACCEPTABLE EXPOSURE LIMIT: 10MG/M3 ACGIH 10 MG/M3 OSHA PEL 10 MG/M3. Fraction by Wt: 20.0% Other REC Limits:NONE RECOMMENDED OSHA PEL:NOT RELEVANT ACGIH TLV:NOT RELEVANT ===================== Hazards Identification ===================== LD50 LC50 Mixture:INHALE 4HR LC50 >4.8MG/L RATS. ** Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:MAY IRRITATE EYES/NOSE/THROAT/SKIN. SKIN CONTACT MAY INITIALLY CAUSE IRRIT OR RASH EYE: CONTACT MAY INCLUDE IRRIT/TEARING/BLEARING OF VISION. SIGNIFICANT SKIN PERMIATION & SYSTEMIC TOXICITY AFTER CONT ACT UNLIKELY NO REPORTS OF HUMAN SENSIZATION. ======================= First Aid Measures ======================= First Aid:INHALATION: MOVE TO FRESH AIR. IF NOT BREATHING GIVE ARTIFICIAL RESPIRATION. IF BREATHING DIFFICULT GIVE OXYGEN, CALL DR. SKIN: IN CASE OF CONTACT IMMED WASH W/SOAP & WATER. WASH CONTAM CLOTHING BEFOR E REUSE. EYE: FLUSH W/WATER >15 MINUTES. CALL DR. INGEST. IF SWALLOWED IMMED GIVE 2 GLASSES WATER & INDUCE VOMITING. NEVER GIVE ANYTHING BY MOUTH TO UNCONSCIOUS PERSON CALL DR. ===================== Fire Fighting Measures ===================== Flash Point:IGNITABLE Extinguishing Media:WATER SPRAY, CHEMICAL FOAM, DRY CHEMICAL, CO2. Fire Fighting Procedures:EVACUATE PERSONNEL. WEAR SCBA. COOL W/WATER SPRAY. RUN-OFF FROM FIRE CONTROL MAY BE POLUTION HAZ. IF POSSIBLE ALLOW TO BURN OUT, WATER MAY INCREASE CONTAM HAZ. Unusual Fire/Explosion Hazard:LIKE MOST ORGANIC POWDERS/CRYSTALS, UNDER SEVERE DUSTING CONDITIONS, THIS MATERIAL MAY FORM EXPLOSIVE MIXTURES IN AIR. ================== Accidental Release Measures ================== Spill Release Procedures:USE APPROPRIATE PROTECTIVE EQUIPMENT DURING CLEANUP. INITIAL CONTAINMENT DIKE SPILL CLEANUP, SHOVEL OR SWEEP UP ACCIDENT OR RELEASE MEASURES IF SPILL AREA IS ON GROUND NEAR PLANTS OR TREES REMOVE TOP 2 INCHES OF SOIL AFTER INITIAL CLEANUP. ======================Handling and Storage ====================== Handling and Storage Precautions:STORE IN WELL-VENTILATED AREA. KEEP CNTNR TIGHTLY CLSD. DONT STORE, EAT, DRINK, SMOKE IN AREAS WHERE THESE MAY BECOME CONTAMINATED W/MATERIAL. Other Precautions:***DISPOSE EMPTY CNTNR IN SANITARY LANDFILL BY INCERNATION OR BY BURNING. OTHER PRECAUTIONS:AVOID BREATING DUST, AVOID CONTACT W/EYES/SKIN/CLOTHING. WASH THOROUGLY AFTER HANDLING BEFORE EATING, DRINKI NG, CHEWING GUM,TOBACCO/USING TOILET. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:APPROVED PESTICIDE RESPIRATOR IF EXPOSURE MAY EXCEED TLV. Ventilation:ADEQUATE. Other Protective Equipment:LONG SLEVE SHIRT/LONG PANTS/SHOES/SOCKS COVERALLS. Supplemental Safety and Health **ORAL LD50 2000MG/KG MALE RAT/1300MG/KG FEMALE. SLIGHTLY TOXIC BY INGESTION. SKIN: LD50 >5000MG/KG RABBITS. SLIGHTLY TOXIC. INHAL 4 HR LC50 >4.8 MG/L RATS. SLIGHTLY TOXIC ================== Physical/Chemical Properties ================== pH:8.5-* Evaporation Rate & Reference:NK *9.5 Solubility in Water:WETTABLE POWDER. Appearance and Odor:SOLID BEIGE POWDER, NO ODOR ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES AMINES, PARTICULARLY PRIMARY AMINES. Hazardous Decomposition Products:WILL NOT OCCUR ==================== Disposal Considerations ==================== Waste Disposal Methods:TREATMENT, STORAGE, TRANSPORTATION, DISPOSAL IN ACCORDANCE W/APPLICABLE FEDERAL, STATE, LOCAL REGULATIONS. REMOVE UNUSEABLE SOLID/CONTAM SOIL FOR DISPOSAL IN APPROVED/PERMITTED LANDFILL. DON'T FLUSH T O SURFACE WATER/SANITARY SEWERS.***
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:36647 PROPHY-JET CLEANING POWDER-3 Preparer's Name:HAROLD BRINKMAN CAGE:13961 CAGE:13961 ============= Composition/Information on Ingredients ============= Ingred Name:SODIUM BICARBONATE CAS:144-55-8 RTECS #:VZ0950000 Fraction by Wt: >95% ===================== Hazards Identification ===================== Routes of Entry: Inhalation:NOSkin:NO Ingestion:YES Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:LARGE INGESTED DOSES HAVE PRODUCED SYSTEMIC ALKALOSIS & EXPANSION IN EXTRACELLULAR FLUID VOLUME W/EDEMA. Explanation of Carcinogenicity:NONE Effects of Overexposure:LARGE INGESTED DOSES HAVE PRODUCED SYSTEMIC ALKALOSIS & EXPANSION IN EXTRACELLULAR FLUID VOLUME W/EDEMA. ======================= First Aid Measures ======================= First Aid:EYES: FLUSH W/LARGE AMOUNTS OF WATER. INGESTION: DON'T INDUCE VOMITING. OBTAIN MEDICAL ATTENTION IN ALL CASES. ===================== Fire Fighting Measures ===================== Extinguishing Media:WATER ALCOHOL FOAM/DRY CHEMICAL Fire Fighting Procedures:SCBA MAY BE NECESSARY IF EXTREMELY LARGE QUANTITIES ARE INVOLVED. ================== Accidental Release Measures ================== Spill Release Procedures:SCOOP UP DRY & PLACE INTO CLEAN CONTAINERS. WASH AWAY UNCONTAMINATED RESIDUE W/WATER. ======================Handling and Storage ====================== Handling and Storage Precautions:STORE IN TIGHTLY SEALED CONTAINERS IN DRY LOCATIONS <95F. DON'T STORE NEAR INCOMPATIBLE SUBSTANCES. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:DUST MASK REQUIRED IF DUST LEVELS EXCEEDS 10 MG/M3. Ventilation:KEEP DUST LEVELS BELOW 10 MG/M3 Supplemental Safety and Health ================== Physical/Chemical Properties ================== Melt/Freeze Pt:M.P/F.P Text:228F Decomp Temp:Decomp Text:95F Spec Gravity:2.2 pH:8.2 Solubility in Water:8.6 GM/100ML Appearance and Odor:WHITE ODORLESS CRYSTALLINE POWDER ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES ACIDS Stability Condition to Avoid:TEMPS >228F Hazardous Decomposition Products:CO2, SALT, WATER ==================== Disposal Considerations ==================== Waste Disposal Methods:DISPOSE IN DRY LANDFILL IAW/FEDERAL, STATE & LOCAL REGULATIONS. EMPTY PACKAGES MAY BE DISCARDED AS TRASH.
0
eyes_protection_not_mandatory
===================== Product Identification ===================== Product ID:CARBON STEEL WELDING STUD Preparer's Name:A.L. LOTT CAGE:85105 CAGE:85105 ============= Composition/Information on Ingredients ============= Ingred Name:IRON CAS:7439-89-6 RTECS #:NO4565500 Fraction by Wt: 98.6%MIN Other REC Limits:AS OXIDE FUME OSHA PEL:10 MG FE/M3 ACGIH TLV:5 MG FE/M3 Ingred Name:MANGANESE (SARA III) CAS:7439-96-5 RTECS #:OO9275000 Fraction by Wt: 1.9% MAX OSHA PEL:(C) 5 MG/M3 DUST ACGIH TLV:5 MG/M3 DUST 9293 ===================== Hazards Identification ===================== Routes of Entry: Inhalation:YES Skin:NO Ingestion:NO Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:PRODUCT IS NON-HAZARDOUS IN AND OF ITSELF. WHEN USED IN WELDING,THE HEAT GENERATES FUMES WHICH OXIDIZE IN THE AIR. THESE FUMES CAUSES AN INFLUENZA-LIKE ILLNESS, OR UNDER CHRONIC CONDITIONS, PRODUCE PN EUMONCONIOSIS. Explanation of Carcinogenicity:BREATHING FERRIC OXIDES DUST OVER LONG PERIODS MAY LEAD TO LUNG CANCER. Effects of Overexposure:INHALED:METAL FUME FEVER:FEVER,CHILLS,MUSCLE ACHE,METALLIC TASTE IN MOUTH. CARBON MONOXIDE/NITROGEN OXIDE OVER EXPOSURE;RESPIRATORY IRRITATION,DIZZINESS,HEADACHE,PULMONARY EDEMA. Medical Cond Aggravated by Exposure:PRE-EXISTING RESPIRATORY PROBLEMS. ======================= First Aid Measures ======================= First Aid:EYE:(FOREIGN PARTICLE)FLUSH WITH WATER. INHALED:METAL FUME FEVER; NORMALLY SELF LIMITING;TREAT SYMPTOMATICALLY. CARBON MONOXIDE,NITROGEN OXIDE EXPOSURE;TREAT SYMPTOMATICALLY(BY PHYSICIAN). ===================== Fire Fighting Measures ===================== Flash Point:NONE Extinguishing Media:NON-FLAMMABLE. USE MEDIA APPROPRIATE FOR SURROUNDING FIRE. Fire Fighting Procedures:NONE Unusual Fire/Explosion Hazard:NONE ================== Accidental Release Measures ================== Spill Release Procedures:USE NORMAL GOOD HOUSEKEEPING PROCEDURES. SWEEP UP MINIMIZING DUST. Neutralizing Agent:NONE ======================Handling and Storage ====================== Handling and Storage Precautions:PROTECT FROM ELEMENTS TO PREVENT RUST. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:USE NIOSH/MSHA RESPIRATOR FOR METAL FUMES IF EXPOSED ABOVE TLV/PEL. Ventilation:USE LOCAL EXHAUST TO KEEP EXPOSURE BELOW PEL/TLV. Other Protective Equipment:OTHER CLOTHING AS NEEDED TO PREVENT THERMAL BURNS. Work Hygienic Practices:USE GOOD INDUSTRIAL HYGIENE PRACTICE. Supplemental Safety and Health ================== Physical/Chemical Properties ================== HCC:N1 Vapor Pres:2750F Appearance and Odor:METALLIC,NO ODOR. ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES STRONG ACIDS (WILL GENERATE EXPLOSIVE HYDROGEN). Stability Condition to Avoid:NONE Hazardous Decomposition Products:NONE ==================== Disposal Considerations ==================== Waste Disposal Methods:DISPOSE I/A/W FEDERAL,STATE,LOCAL REGULATIONS. MFR SUGGESTS LANDFILL AS NORMAL WASTE ANY MATERIAL THAT CANNOT BE RECLAIMED.
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:RPC-057 2,2',3,4,5,5',6-HEPTACHLOROBIPHENYL CAGE:0MU35 CAGE:0MU35 ============= Composition/Information on Ingredients ============= Ingred Name:2,2',3,4,5,5',6-HEPTACHLOROBIPHENYL CAS:52712-05-7 ===================== Hazards Identification ===================== Routes of Entry: Inhalation:YES Skin:NO Ingestion:NO Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:TOXIC; IRRITANT. TOXIC MATERIAL CAUSING OTHER TOXIC EFFECTS. Explanation of Carcinogenicity:NONE ======================= First Aid Measures ======================= First Aid:EYES/SKIN: FLUSH W/COPIOUS AMOUNTS OF WATER. INHALATION: REMOVE TO FRESH AIR. GIVE OXYGEN IF NECESSARY. OBTAIN MEDICAL ATTENTION IN ALL CASES. ===================== Fire Fighting Measures ===================== Extinguishing Media:CO2, DRY CHEMICAL POWDER/WATER SPRAY. ================== Accidental Release Measures ================== Spill Release Procedures:LEAKING BOTTLE MAY BE PLACED IN A PLASTIC BAG & NORMAL DISPOSAL PROCEDURES FOLLOWED. LIQUID SAMPLES MAY BE ABSORBED ON VERMICULITE/SAND. ======================Handling and Storage ====================== Handling and Storage Precautions:KEEP TIGHTLEY CLOSED & STORE IN A COOL/DRY PLACE. Other Precautions:THIS MATERIAL SHOULD ONLY BE USED BY THOSE PERSONS TRAINED IN THE SAFE HANDLING OF HAZARDOUS CHEMICALS. PREVENT CONTACT W/SKIN, EYES & CLOTHING. ALL CHEMICALS SHOULD BE CONSIDERED HAZARDOUS, DIRECT PH YSICAL CONTACT SHOULD BE AVOIDED. ============= Exposure Controls/Personal Protection ============= Other Protective Equipment:CHEMICAL RESISTANT LABORATORY COAT &/RUBBER APRON, USE APPROPRIATE OSHA/MSMA APPROVED SAFETY EQUIPMENT. Supplemental Safety and Health ================== Physical/Chemical Properties ================== Melt/Freeze Pt:M.P/F.P Text:296.6-302F ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES STRONG OXIDIZERS ==================== Disposal Considerations ==================== Waste Disposal Methods:BURN IN CHEMICAL INCINERATOR EQUIPPED W/AN AFTERBURNER & SCRUBBER IAW/FEDERAL, STATE & LOCAL REGULATIONS.
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:POLOCAINE WITH LEVONORDEFRIN,NDC 00186-0440-14 CAGE:NO284 CAGE:04473 CAGE:NO284 ============= Composition/Information on Ingredients ============= Ingred Name:MEPIVACAINE HYDROCHLORIDE CAS:1722-62-9 RTECS #:TK6475000 Fraction by Wt: 2% Other REC Limits:NONE RECOMMENDED Ingred Name:LEVONORDEFRIN CAS:829-74-3 Fraction by Wt: 0.005% Other REC Limits:NONE RECOMMENDED Ingred Name:SODIUM CHLORIDE CAS:7647-14-5 RTECS #:VZ4725000 Fraction by Wt: <1% Other REC Limits:NONE RECOMMENDED Ingred Name:SODIUM METABISULFITE CAS:7681-57-4 RTECS #:UX8225000 Fraction by Wt: <1% Other REC Limits:NONE RECOMMENDED OSHA PEL:5 MG/M3 ACGIH TLV:5 MG/M3; 9596 Ingred Name:SODIUM HYDROXIDE (CERCLA) CAS:1310-73-2 RTECS #:WB4900000 Fraction by Wt: <1% Other REC Limits:NONE RECOMMENDED OSHA PEL:2 MG/M3 ACGIH TLV:C 2 MG/M3; 9596 EPA Rpt Qty:1000 LBS DOT Rpt Qty:1000 LBS Ingred Name:HYDROGEN CHLORIDE (HYDROCHLORIC ACID) (SARA 302/313) (CERCLA) CAS:7647-01-0 RTECS #:MW4025000 Fraction by Wt: <1% Other REC Limits:NONE RECOMMENDED OSHA PEL:C 5 PPM ACGIH TLV:C 5 PPM; 9596 EPA Rpt Qty:5000 LBS DOT Rpt Qty:5000 LBS ===================== Hazards Identification ===================== LD50 LC50 Mixture:LD50 (ORAL, RAT) 49 MG/KG LEVONORDEFRIN Routes of Entry: Inhalation:NOSkin:NO Ingestion:NO Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:TARGET ORGANS:EYE, SKIN, CNS, CARDIOVASCULAR SYSTEM. ACUTE- THIS PRODUCT IS INTENDED FOR THERAPEUTIC USE ONLY WHEN PRESCRIBED BY A PHYSICIAN. MAY CAUSE EYE & SKIN IRRITATION & NUMBNESS. OVEREXPOSURE C AN CAUSE CNS & CARDIOVASCULAR SYSTEM EFFECTS. CAN CAUSE ALLERGIC RESPONSES IN SENSITIVE INDIVIDUALS. CHRONIC- UNKNOWN. Explanation of Carcinogenicity:NONE Effects of Overexposure:IRRITATION, DIZZINESS, HEADACHE, CONFUSION, CARDIAC EFFECTS Medical Cond Aggravated by Exposure:INDIVIDUALS WITH PRE-EXISTING DISEASES OF CENTRAL NERVOUS SYSTEM, CARDIOVASCULAR SYSTEM ======================= First Aid Measures ======================= First Aid:CALL A DOCTOR IF SYMPTOMS PERSIST. EYE:FLUSH WITH WATER FOR 15 MINUTES, HOLDING EYELIDS OPEN. SKIN:FLUSH WITH PLENTY OF WATER. INHALED:REMOVE TO FRESH AIR. ORAL:IF CONSCIOUS, RINSE OUT MOUTH WITH WATE R. CALL A PHYSICIAN/POISON CONTROL CENTER IMMEDIATELY. ===================== Fire Fighting Measures ===================== Flash Point:NONE Lower Limits:NOT RELEVANT Upper Limits:NOT RELEVANT Extinguishing Media:WATER SPRAY, CARBON DIOXIDE, FOAM OR DRY CHEMICAL FOR SURROUNDING FIRE. USE WATER SPRAY TO COOL FIRE EXPOSED CONTAINERS. Fire Fighting Procedures:WEAR PROTECTIVE CLOTHING AND NIOSH-APPROVED SELF-CONTAINED BREATHING APPARATUS. Unusual Fire/Explosion Hazard:MAY EMIT TOXIC FUMES. ================== Accidental Release Measures ================== Spill Release Procedures:ABSORB SPILL WITH VERMICULITE OR OTHER INERT MATERIAL. PLACE IN A CONTAINER FOR DISPOSAL. CLEAN AREA WITH SOAP AND WATER. Neutralizing Agent:NOT RELEVANT ======================Handling and Storage ====================== Handling and Storage Precautions:STORE AT CONTROLLED ROOM TEMPERATURE, 15-30C (59-86F). DO NOT FREEEZE. KEEP OUT OF REACH OF CHILDREN. Other Precautions:AS A GENERAL RULE, WHEN HANDLING PHARMACEUTICAL PRODUCTS, AVOID ALL FORMS OF CONTACT AND INHALATION OF DUST, FUMES, MISTS, AND/OR VAPORS ASSOCIATED WITH THE PRODUCT. WASH THOROUGHLY AFTER HANDLING ANDBEFORE EATING OR DRINKING. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:NONE SHOULD BE NEEDED. Ventilation:ADEQUATE Other Protective Equipment:EYE WASH STATION, LAB COAT Work Hygienic Practices:OBSERVE GOOD PERSONAL HYGIENE PRACTICES AND RECOMMENDED PROCEDURES. DO NOT WEAR CONTAMINATED CLOTHING. Supplemental Safety and Health ================== Physical/Chemical Properties ================== HCC:N1 NRC/State Lic Num:NOT RELEVANT Boiling Pt:B.P. Text:212F,100C Melt/Freeze Pt:M.P/F.P Text:32.0F,0.0C Vapor Pres:17 Vapor Density:0.6 Spec Gravity:1 Evaporation Rate & Reference:1 (WATER=1) Solubility in Water:SOLUBLE Appearance and Odor:COLORLESS LIQUID - ODORLESS ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES NONE Stability Condition to Avoid:NONE Hazardous Decomposition Products:MAY EMIT TOXIC FUMES. ==================== Disposal Considerations ==================== Waste Disposal Methods:NOT A HAZARDOUS WASTE. OBSERVE LOCAL, STATE AND FEDERAL REGULATIONS. RECOMMENDED METHOD IS BY INCINERATION.
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:TRANSFER RECORDING CARTRIDGE FOR TELECOPIER CAGE:0E6G9 CAGE:0E6G9 CAGE:26921 ============= Composition/Information on Ingredients ============= Ingred Name:COATING (CONSISTING OF INGREDIENTS 3-11 IN COMPONENT PERCENTAGES SHOWN) RTECS #:9999999ZZ Fraction by Wt: 48% Ingred Name:CARNAUBA WAX CAS:8015-86-9 Fraction by Wt: 6% Ingred Name:PARAFFIN WAX CAS:8002-74-2 RTECS #:RV0350000 Fraction by Wt: 46% OSHA PEL:2 MG/M3 (FUME) ACGIH TLV:2 MG/M3 (FUME); 9192 Ingred Name:CARBON BLACK CAS:1333-86-4 RTECS #:FF5800000 Fraction by Wt: 12% OSHA PEL:3.5 MG/M3 ACGIH TLV:3.5 MG/M3; 9192 Ingred Name:MINERAL OIL CAS:64742-16-1 Fraction by Wt: <6% Ingred Name:KYNAR, 1-1-DIFLUORETHANE HOMOPOLYMER CAS:24937-79-9 Fraction by Wt: <2% Ingred Name:ETHYLENE, TETRAFLUORO, POLYMER; (TEFLON) CAS:116-14-3 RTECS #:KX4025000 Fraction by Wt: 2% Ingred Name:ETHYLENE-METHACRYLATE COPOLYMER CAS:24937-78-8 Fraction by Wt: 5% Ingred Name:CELLULOSE ACETATE BUTANOATE CAS:9004-36-8 Fraction by Wt: 1% Ingred Name:ADDITIVES CAS:24937-78-8 Fraction by Wt: 20% Ingred Name:MIXTURE TLV:10 MG/M3 (TDUST); PEL:15 MG/M3 (TDUST), 5 MG/M3 (RDUST); 2.5 MG/M3 (TDUST)-MFR; 0.4 MG/M3 (RDUST)-MFR RTECS #:9999999ZZ Ingred Name:POLY (OXYETHYLENEOXYTEREPHTHALOYL); (POLYETHYLENE TEREPHTHALATE FILM) CAS:25038-59-9 RTECS #:TR2725000 Fraction by Wt: 52% ===================== Hazards Identification ===================== LD50 LC50 Mixture:NONE SPECIFIED BY MANUFACTURER. Routes of Entry: Inhalation:NOSkin:NO Ingestion:NO Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:SKIN:NON IRRITATING; NON SENSITIZING. FURTHER INFORMATION ON POISINDEX. Explanation of Carcinogenicity:NOT RELEVANT. Effects of Overexposure:NONE SPECIFIED BY MANUFACTURER. Medical Cond Aggravated by Exposure:NONE WHEN USED AS DESCRIBED BY PRODUCT LITERATURE. ======================= First Aid Measures ======================= First Aid:EYE:IMMEDIATELY FLUSH W/POTABLE WATER FOR A MINIUMUM OF 15 MINS, SEEK ASSISTANCE FROM MD . SKIN:FLUSH W/COPIOUS AMOUNTS OF WATER. CALL MD . INHAL:REMOVE TO FRESH AIR. SUPPORT BREATHING (GI VE O2/ARTIFICIAL RESPIRATION) . INGEST:CALL MD IMMEDIATELY . ===================== Fire Fighting Measures ===================== Extinguishing Media:WATER, FOAM, CARBON DIOXIDE OR DRY CHEMICAL. Fire Fighting Procedures:WEAR NIOSH/MSHA APPROVED SCBA & FULL PROTECTIVE EQUIPMENT . Unusual Fire/Explosion Hazard:NONE. ================== Accidental Release Measures ================== Spill Release Procedures:NOT APPLICABLE. Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER. ======================Handling and Storage ====================== Handling and Storage Precautions:NONE. Other Precautions:NONE SPECIFIED BY MANUFACTURER. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:NONE REQUIRED WHEN USED AS INTENDED IN XEROX EQUIPMENT. Ventilation:NONE SPECIFIED BY MANUFACTURER. Other Protective Equipment:NONE REQUIRED WHEN USED AS INTENDED IN XEROX EQUIPMENT. Work Hygienic Practices:NONE SPECIFIED BY MANUFACTURER. Supplemental Safety and Health MFRS TRADE NAME/PART NO:7020/7021/7024/7032/ 7033/7033S; FAX TELECOPIER 7020/7021 IMAGING CARTRIDGE REFILLS, 3R91266 ================== Physical/Chemical Properties ================== HCC:N1 Melt/Freeze Pt:M.P/F.P Text:142F,61C Solubility in Water:NEGLIGIBLE Appearance and Odor:BLACK FILM. ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES NONE. Stability Condition to Avoid:NONE SPECIFIED BY MANUFACTURER. Hazardous Decomposition Products:IN A FIRE, CO & CO2 & OTHER TOXIC PRODUCTS OF DECOMPOSITION MAY BE EVOLVED. ==================== Disposal Considerations ==================== Waste Disposal Methods:NO SPECIFIC WASTE DISPOSAL METHOD REQUIRED. DISPOSE OF IN ACCORDANCE W/FEDERAL, STATE & LOCAL REGULATIONS.
0
eyes_protection_not_mandatory
======================================================= NIIN: 01-370-2182 Product ID: SIMPLE GREEN (R) HAND CLEANER GEL (TM) Cage: 1Z575 ======================================================= Contractor Summary ======================================================= Cage: 1Z575 ======================================================= Item Description Information ======================================================= Item Manager: GSA Item Name: HAND CLEANER Unit of Issue: BX UI Container Qty: * Type of Container: PLASTIC ======================================================= Ingredients ======================================================= Cas: 111-76-2 RTECS #: KJ8575000 Other REC Limits: NONE SPECIFIED OSHA PEL: 25 PPM (SKIN) ACGIH TLV: 25 PPM (SKIN) ------------------------------ RTECS #: 9999999VO Other REC Limits: NONE SPECIFIED ======================================================= Health Hazards Data ======================================================= LD50 LC50 Mixture: ORAL LD50 (RAT) IS UNKNOWN Carcinogenicity Inds - NTP: NO IARC: NO OSHA: NO Effects of Exposure: ADVERSE HUMAN HEALTH EFFECTS NOT EXPECTED FROM SIMPLE GREEN HAND CLEANER GEL BASED UPON AVAILABLE TOXICITY INFORMATION FOR INDIVIDUAL COMPONENTS & LABORATORY TOXICITY DATA FOR WHOLE PRODUCT. EYE IRRIT ATION COMMON TO SURFACTANTS OR HARD GRANULAR MATERIAL IN EYE, EXPECTED FROM SIMPLE GREEN. SKIN IRRITATION NOT LIKELY. Explanation Of Carcinogenicity: CONTAINS NO CARCINOGENIC COMPOUNDS AS DEFINED BY NTP, IARC, OR OSHA. Medical Cond Aggravated By Exposure: NONE ANTICIPATED First Aid: EYE: REDDENING. IMMED RINSE W/LRG QTY COOL WATER. REMOVE CONTACT LENSES, IF PRESENT & LIFT EYELIDS DURING RINSING. GET MED AID IF IRRIT PERSISTS. SKIN: ADVERSE EFFECTS NOT EXPECTED, IF REDDENING OCCUR S, GET MEDICAL ATTENTION. SWALLOWING: ESSENTIALLY NONTOXIC. GIVE SEVERAL GLASSES OF WATER TO DILUTE, DON'T INDUCE VOMITING. IF UPSET STOMACH, SEE DR. INHALATION: NONTOXIC. IF DIZZY, GET FRESH AIR. ======================================================= Handling and Disposal ======================================================= Spill Release Procedures: RECOVER USEABLE MATERIAL BY CONVENIENT METHOD; RESIDUAL MAY BE REMOVED BY WIPE OR WET MOP. IF NECESSARY, WASH TO SEWER OR DRAIN WITH LARGE QUANTITIES OF WATER. Waste Disposal Methods: SIMPLE GREEN HAND CLEANER GEL IS FULLY WATER SOLUBLE AND BIODEGRADABLE; IT WILL NOT HARM SEWAGE TREATMENT MICROORGANISM IF DILUTED AND DISPOSED BY SEWER OR DRAIN. DISPOSE OF IN ACCORDANCE WITH ALL APP LICABLE LOCAL, STATE, AND FEDERAL LAWS. Handling And Storage Precautions: NO SPECIAL PRECAUTIONS REQUIRED. THIS PRODUCT IS NON-HAZARDOUS FOR STORAGE AND TRANSPORT ACCORDING TO THE US DEPARTMENT OF TRANSPORTATION REGULATIONS. Other Precautions: SIMPLE GREEN HAND CLEANER GEL REQUIRES NO SPECIAL LABELING OR PLACARDING TO MEET US DEPARTMENT OF TRANSPORTATION REQUIREMENTS. STORAGE AT ELEVATED TEMPERATURES (UP TO 194F) WILL NOT CAUSE BREAKDOWN OF THE GEL. ======================================================= Fire and Explosion Hazard Information ======================================================= Flash Point Text: NONFLAMMABLE Autoignition Temp Text: NONE Lower Limits: NONFLAMMABLE Upper Limits: NONFLAMMABLE Extinguishing Media: NONFLAMMABLE, NONEXPLOSIVE, NONREACTIVE. NO SPECIAL MEDIA REQUIRED. Fire Fighting Procedures: NONE REQUIRED ======================================================= Control Measures ======================================================= Respiratory Protection: NO SPECIAL PRECAUTIONS REQUIRED. Ventilation: NO SPECIAL VENTILATION IS REQUIRED DURING USE. Other Protective Equipment: NONE REQUIRED. SIMPLE GREEN HAND CLEANER GEL IS INTENDED FOR USE ON SKIN, & CONTAINS MOISTURIZERS & EMOLLIENTS. Work Hygienic Practices: NO SPECIAL REQUIREMENTS. THOROUGHLY WIPE HANDS BEFORE TOUCHING EYES OR HANDLING CONTACT LENSES. ======================================================= Physical/Chemical Properties ======================================================= HCC: B3 PH: 7.68 Solubility in Water: COMPLETELY MISCIBLE Appearance and Odor: VISCOUS GREEN GEL WITH CHARACTERISTIC SASSAFRAS ODOR ======================================================= Reactivity Data ======================================================= Stability Indicator: YES Hazardous Polymerization Indicator: NO ======================================================= Toxicological Information ======================================================= ======================================================= Ecological Information ======================================================= ======================================================= ======================================================= ======================================================= Regulatory Information ======================================================= ======================================================= Other Information ======================================================= ======================================================= Transportation Information ======================================================= Trans ID NO: 130018 Product ID: SIMPLE GREEN (R) HAND CLEANER GEL (TM) Review Date: 12/27/1993 Net Unit Weight: 16 KGM Multiple KIT Number: 0 Review IND: Y Unit Of Issue: BX Container QTY: * Type Of Container: PLASTIC Additional Data: * UNIT OF ISSUE CONTAINER QUANTITY: FOUR - 4 KILOGRAM BOTTLES ======================================================= Detail DOT Information ======================================================= DOT PSN Code: ZZZ DOT Proper Shipping Name: NOT REGULATED BY THIS MODE OF TRANSPORTATION ======================================================= Detail IMO Information ======================================================= IMO PSN Code: ZZZ IMO Proper Shipping Name: NOT REGULATED FOR THIS MODE OF TRANSPORTATION ======================================================= Detail IATA Information ======================================================= IATA PSN Code: ZZZ IATA Proper Shipping Name: NOT REGULATED BY THIS MODE OF TRANSPORTATION ======================================================= Detail AFI Information ======================================================= AFI PSN Code: ZZZ AFI Proper Shipping Name: NOT REGULATED BY THIS MODE OF TRANSPORTATION ======================================================= HAZCOM Label ======================================================= Product ID: SIMPLE GREEN (R) HAND CLEANER GEL (TM) Cage: 1Z575 Company Name: SUNSHINE MAKERS, INC. Street: 15922 PACIFIC COAST HIGHWAY Zipcode: 92649 Label Required IND: Y Date Of Label Review: 12/16/1998 Status Code: C Label Date: 12/16/1998 Origination Code: G Hazard And Precautions: ADVERSE HUMAN HEALTH EFFECTS NOT EXPECTED FROM SIMPLE GREEN HAND CLEANER GEL BASED UPON AVAILABLE TOXICITY INFORMATION FOR INDIVIDUAL COMPONENTS & LABORATORY TOXICITY DATA FOR WHOLE PRODUCT. EYE IRRIT ATION COMMON TO SURFACTANTS OR HARD GRANULAR MATERIAL IN EYE, EXPECTED FROM SIMPLE GREEN. SKIN IRRITATION NOT LIKELY. N/K =======================================================
0
eyes_protection_not_mandatory
===================== Product Identification ===================== Product ID:P1429A00 EPOXY Kit Part:Y CAGE:GO235 CAGE:0NP78 CAGE:GO235 ============= Composition/Information on Ingredients ============= Ingred Name:TITANIUM DIOXIDE, TIO2 (SUSPECTED ANIMAL CARCINOGEN, IARC GROUP 3) *95-2* CAS:13463-67-7 RTECS #:XR2275000 OSHA PEL:10 MG/CUM ACGIH TLV:10 MG/CUM (DUST) Ingred Name:TALC (POWDER), (ASBESTOS FREE), TALCUM; HYDROUS MAGNESIUM SILICATE CAS:14807-96-6 RTECS #:WW2710000 OSHA PEL:2 MG/CUM ACGIH TLV:2 MG/CUM (RESP DUST) Ingred Name:SILICON DIOXIDE, CRYSTALLINE QUARTZ, SAND (ANIMAL CARC, SUSPECTED HUMAN CARC IARC-GROUP 2A; SUSPECTED CARC NTP) *95-2* CAS:14808-60-7 RTECS #:VV7330000 Fraction by Wt: 0.2% Other REC Limits:0.05 MG/CUM NIOSH OSHA PEL:0.1 MG/CUM RESP DUST ACGIH TLV:0.1 MG/CUM RESP DUST Ingred Name:HYDROCARBON EPOXY MODIFIER Ingred Name:CALCIUM CARBONATE, DOMOLITE, LIMESTONE, WHITING CAS:1317-65-3 RTECS #:EV9580000 OSHA PEL:15 MG/CUM ACGIH TLV:10 MG/CUM (DUST) Ingred Name:BISPHENOL A DIGLYCIDYL ETHER RESIN, EPOXY RESIN, EPON 820, ARALDITE 6004 *95-2* CAS:25068-38-6 RTECS #:KD4380000 Ingred Name:C10-16 ALKYLGLYCIDYL ETHER, ALIPHATIC MONOGLYCIDAL ETHER *95-2* CAS:68081-84-5 Ingred Name:HEXYLENE GLYCOL, 2-METHYL-2,4-PENTANEDIOL CAS:107-41-5 RTECS #:SA0810000 Fraction by Wt: 2.5% Other REC Limits:25 PPM ACGIH TLV:C 21 MG/CUM Ingred Name:LIGHT NAPHTHALIC DISTILLATE, HYDROTREATED LIGHT NAPHTHENIC DISTILLATE CAS:64742-53-6 RTECS #:PY8036000 OSHA PEL:5 MG/CUM ACGIH TLV:5 MG/CUM Ingred Name:PETROLEUM OIL, HYDROTREATED HEAVY NAPHTHENIC DISTILLATE (PETROLEUM), PETROLEUM DISTILLATES, MINERAL OIL (SEVERE) CAS:64742-52-5 RTECS #:PY8035001 OSHA PEL:5 MG/CUM ACGIH TLV:5 MG/CUM ===================== Hazards Identification ===================== Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES Reports of Carcinogenicity:NTP:YES IARC:YES OSHA:NO Health Hazards Acute and Chronic:EYES: MODERATE IRRITATION. SKNN: MODERATE IRRIATION, SENSITIZATION, MAY BE ABSORBED. INHALATION: RESPIRATORY TRACT IRRITATION, SENSITIZER, ALLERGIC RESPIRATORY REACTION. INGESTION: SLIGHTLY TOXIC, GI IRRITATION. Explanation of Carcinogenicity:SEE INGREDIENTS Effects of Overexposure:IRRITATION, STINGING, BURNING, TEARING, REDNESS, SWELLING, RASH, HIVES, HEADACHE, NAUSEA, DIZZINESS, WHEEZING, SHORTNESS OF BREATH, COUGHT, VOMITING, DIARRHEA. Medical Cond Aggravated by Exposure:PRE-EXISTING EYE, SKIN & RESPIRATORY DISORDERS. ======================= First Aid Measures ======================= First Aid:EYES: FLUSH W/WATER FOR 15 MINS. SKIN: WASH W/SOAP & WATER. INHALATION: REMOVE TO FRESH AIR. GIVE OXYGEN IF NEEDED. INGESTION: IF CONFINED TO MOUTH, RINSE OUT W/WATER. DON'T SWALLOW RINSE WATER. IF SW ALLOWED, DRINK 2 GLASSES OF WATER. NEVER GIVE ANYTHING BY MOUTH TO AN UNCONSCIOUS PERSON. DON'T INDUCE VOMITING. OBTAIN MEDICAL ATTENTION IN ALL CASES. ===================== Fire Fighting Measures ===================== Flash Point Method:TCC Flash Point:211F (SEE SUPP) Extinguishing Media:WATER FOG, CO2, DRY CHEMICAL. Fire Fighting Procedures:WEAR A SCBA. WATER MAY BE USED TO COOL CONTAINERS. AVOID SPREADING BURNING LIQUIDS W/WATER USED FOR COOLING PURPOSES. Unusual Fire/Explosion Hazard:WATER/FOAM MAY CAUSE FROTHING WHICH CAN BE VIOLENT IF SPRAYED INTO CONTAINERS OF HOT, BURNING LIQUID. MATERIAL MAY BURN, BUT WON'T IGNITE READILY. ================== Accidental Release Measures ================== Spill Release Procedures:WEAR PROTECTIVE EQUIPMENT. SMALL: ABSORB ON ABSORBENT MATERIAL & TRANSFER TO APPROPRIATELY MARKED CONTAINER. LARGE: EVACUATE AREA. STOP SOURCE/DIKE AREA/PUMP TO SALVAGE CONTAINER. TAKE UP REMAIDER W/A BSORBENT & SHOVEL INTO CONTAINER. ======================Handling and Storage ====================== Handling and Storage Precautions:STORE IN COOL/DRY/VENTILATED AREA AWAY FROM IGNITION SOURCES. KEEP CONTAINERS TIGHTLY CLOSED WHEN NOT IN USE. FOR INDUSTRIAL USE ONLY. Other Precautions:USE W/ADEQUATE VENTILATION. AVOID BREATHING SPRAY MIST/VAPORS/FUMES FROM HEATED MATERIAL, EYE CONTACT & PROLONGED/REPEATED SKIN CONTACT. DON'T TRANSFER TO UNMARKED CONTAINER. EMPTY CONTAINERS MAY BE H AZARDOUS DUE TO PRODUCT RESIDUES. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:WEAR A NIOSH APPROVED RESPIRATOR IF APPLYING, DRYING, CURING/IF FUMES, DUST/MIST ARE GENERATED DURING HEATING/USE OF PRODUCT. Ventilation:GENERAL MECHANICAL. LOCAL EXHAUST: AT POINT OF VAPOR &/FUMES EVOLUTION OF SUFFICIENT VELOCITY TO REMOVE VAPORS &/FUMES. Other Protective Equipment:COVERALLS, APRON, RUBBER FOOT COVERING, SAFETY SHOWER, EYEWASH FACILITY Work Hygienic Practices:REMOVE/LAUNDER CONTAMINATED CLOTHING BEFORE REUSE. WASH THOROUGHLY AFTER HANDLING. DISCARD CONTAMINATED SHOES. Supplemental Safety and Health DATA INFO IS FOR HEXYLENE GLYCOL. NOTES TO PHYSICIAN: NO SPECIFIC ANTIDOTE. CAREFUL LAVAGE MAY BE INDICATED AFTER INGESTION. IF LAVAGE IS PERFORMED, SUGGEST ENDOTRACHEAL &/ESOPHAGEAL CONTROL. ================== Physical/Chemical Properties ================== Boiling Pt:B.P. Text: 388F(SUPP) Vapor Pres:0.05(SUPP) Vapor Density:3.9 (SUPP) Evaporation Rate & Reference:(N-BU AC = 1): 0.01(SUPP) Solubility in Water:COMPLETE (SEE SUPP) Appearance and Odor:VISCOUS WHITE LIQUID. ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES STRONG OXIDIZING AGENTS/MINERAL ACIDS/ALKALIES, AMINES, MERCAPTAINS, SOME CURING AGENTS/PLASTICS & METALS. Stability Condition to Avoid:OPEN FLAMES, ELECTRIC ARCS, HEATING ELEMENTS & OTHER IGNITION SOURCES. Hazardous Decomposition Products:CO, CO2, ACRID SMOKE & FUMES, ALDEHYDES, ACIDS, OTHER UNIDENTIFIED ORGANIC COMPOUNDS & TOXIC SUBSTANCES. ==================== Disposal Considerations ==================== Waste Disposal Methods:PREVENT RUN-OFF TO SEWERS, STREAMS/OTHER BODIES OF WATER. DISPOSE OF IAW/FEDERAL, STATE & LOCAL REGULATIONS.
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:SUPER STATION FLOOR CLEANER, 0909 CAGE:86938 CAGE:86938 ============= Composition/Information on Ingredients ============= Ingred Name:NON-HAZARDOUS INGREDIENTS ===================== Hazards Identification ===================== Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:ACUTE: SKIN: CAN BE SLIGHTLY IRRITATING UPON PROLONGED CONTACT. EYES: CAN BE IRRITATING UPON CONTACT. INHALE: VERY SLIGHT, IF ANY, EFFECT. INGEST: MAY CAUSE NAUSEA. Effects of Overexposure:SEE HEALTH HAZARDS. ======================= First Aid Measures ======================= First Aid:SKIN: WASH WITH SOAP AND WATER. EYES: FLUSH IMMEDIATELY WITH PLENTY OF WATER FOR AT LEAST 15 MINUTES. INHALE: MOVE TO FRESH AIR. INGEST: GIVE LARGE AMOUNTS OF WATER TO DRINK. CONSULT A PHYSICIAN. ===================== Fire Fighting Measures ===================== Flash Point Method:TCC Flash Point:NONE Extinguishing Media:NOT APPLICABLE. MEDIA SUITABLE FOR SURROUNDING FIRE . Fire Fighting Procedures:NOT APPLICABLE. USE NIOSH APPROVED SCBA AND FULL PROTECTIVE EQUIPMENT . Unusual Fire/Explosion Hazard:NOT APPLICABLE. ================== Accidental Release Measures ================== Spill Release Procedures:MOP UP WITH WATER OR ABSORB SPILL WITH AN ABSORBENT MATERIAL (I.E. SELIG'S AP ABSORBENT); PICK UP AND DEPOSIT IN A SUITABLE WASTE CONTAINER. FLUSH AREA THOROUGHLY WITH A DETERGENT SOLUTION. RINSE AREA THOROUGHLY WITH CLEAN WATER. Neutralizing Agent:NEUTRALIZATION OF PH MAY BE REQUIRED. ======================Handling and Storage ====================== Handling and Storage Precautions:KEEP OUT OF REACH OF CHILDREN. HARMFUL IF SWALLOWED. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:NOT REQUIRED. NIOSH APPROVED RESPIRATOR APPROPRIATE FOR EXPOSURE OF CONCERN . Ventilation:NO SPECIAL VENTILATION REQURIED. Other Protective Equipment:EYE WASH & DELUGE SHOWER MEETING ANSI DESIGN CRITERIA . PROTECTIVE CLOTHING NOT NORMALLY NECESSARY. Supplemental Safety and Health PH (CONCENTRATE): 9. PH (USE DILUTION OF 1:128): 9.3. ================== Physical/Chemical Properties ================== Boiling Pt:=93.3C, 200.F Spec Gravity:1.00 pH:SUPDAT Solubility in Water:COMPLETE Appearance and Odor:12, CLEAR, RED, THIN LIQUID., CITRUS ODOR. Percent Volatiles by Volume:82 ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES CATIONIC MATERIAL. Hazardous Decomposition Products:NONE. ==================== Disposal Considerations ==================== Waste Disposal Methods:CHECK LOCAL, STATE AND FEDERAL REGULATIONS PRIOR TO DISPOSAL. PRODUCT IS NOT CONSIDERED A HAZARDOUS WASTE UNDER RCRA. LIQUIDS MAY BE ABLE TO BE DISPOSED OF BY FLUSHING INTO SANITARY SEWER WITH PLENTYOF WATER.
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:ELASE OINTMENT Preparer's Name:CHRISTINA J. BARRINGTON CAGE:EO410 CAGE:EO410 CAGE:0K706 ============= Composition/Information on Ingredients ============= Ingred Name:POLYETHYLENE CAS:9002-88-4 RTECS #:TQ3325000 Other REC Limits:NONE RECOMMENDED Ingred Name:SODIUM CHLORIDE CAS:7647-14-5 RTECS #:VZ4725000 Other REC Limits:NONE RECOMMENDED Ingred Name:SUCROSE CAS:57-50-1 RTECS #:WN6500000 Other REC Limits:NONE RECOMMENDED OSHA PEL:15 MG/M3 TDUST ACGIH TLV:10 MG/M3; 9394 Ingred Name:THIMEROSAL CAS:54-64-8 Other REC Limits:NONE RECOMMENDED Ingred Name:DESOXYRIBONUCLEASE CAS:533-67-5 Other REC Limits:NONE RECOMMENDED Ingred Name:FIBRINOLYSIN CAS:9004-09-5 Other REC Limits:NONE RECOMMENDED Ingred Name:GREASE, PETROLEUM CAS:8009-03-8 Other REC Limits:NONE RECOMMENDED ===================== Hazards Identification ===================== LD50 LC50 Mixture:LD50: NOT GIVEN Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:EYE, SKIN AND RESPIRATORY IRRITATION MAY OCCUR. DELAYED EFFECTS: HYPERSENSITIVITY REACTIONS RANGING FROM MILD TO SEVERE MAY OCCUR. NOTE: THIS PRODUCT INTENDED FOR THERAPEUTIC USE ONLY WHEN PRESCRIBED BY A PHYSICIAN. Explanation of Carcinogenicity:THIS COMPOUND CONTAINS NO INGREDIENTS AT CONCENTRATIONS OF 0.1% OR GREATER THAT ARE CARCINOGENS OR SUSPECT CARCINOGENS. Effects of Overexposure:EYE IRRITATION, SKIN IRRITATION, RESPIRATORY IRRITATION. Medical Cond Aggravated by Exposure:PRE-EXISITNG SKIN AND RESPIRATORY CONDITIONS MAY BE ADVERSELY AFFECTED BY EXPOSURE. ======================= First Aid Measures ======================= First Aid:INHALATION: MOVE PERSON TO FRESH AIR IMMEDIATELY. GIVE ARTIFICIAL RESPIRATION AND CPR IF REQUIRED. SEEK MEDICAL ATTENTION. INGESTION: FLUSH MOUTH WITH WATER IMMEDIATELY. SEEK MEDICAL ATTENTION. SKIN: REMOVE CONTAMINATED CLOTHING IMMEDIATELY. FLUSH AREA WITH WATER. SEEK MEDICAL ATTENTION. EYES: IMMEDIATELY FLUSH WITH WATER FOR AT LEAST 15 MINUTES. SEEK MEDICAL ATTENTION. ===================== Fire Fighting Measures ===================== Flash Point:NOT GIVEN Lower Limits:NOT GIVEN Upper Limits:NOT GIVEN Extinguishing Media:WATER SPRAY, DRY CHEMICAL, CARBON DIOXIE OR FOAM AS APPRORPIATE Fire Fighting Procedures:WEAR FIRE FIGHTING PROTECTIVE EQUIPMENT AND FULL FACE-PIECE SELF-CONTAINED BREATHING APPARATUS. Unusual Fire/Explosion Hazard:NONE SPECIFIED BY MANUFACTURER. ================== Accidental Release Measures ================== Spill Release Procedures:WEAR RECOMMENDED PERSONAL PROTECTIVE EQUIPMENT. USE ABSORBENT TOWELS OR BOOMS TO CLEAN-UP SPILL. WIPE SURFACES CLEAN AND WASH WITH SOAP AND WATER. Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER. ======================Handling and Storage ====================== Handling and Storage Precautions:WHEN HANDLING PHARMACEUTICAL PRODUCTS, AVOID ALL CONTACT AND INHALATION OF DUST, FUMES, MISTS AND/OR VAPOR ASSOCIATED WITH THE PRODUCT. Other Precautions:FOR ADVERSE DRUG REACTION INFORMATION, CALL 708-317-5937. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:WITH SATISFACTORY VENTILATION, RESPIRATORY PROTECTION NOT USUALLY REQUIRED. Ventilation:GENERAL ROOM VENTILATION IS USUALLY SATISFACTORY, USE LOCAL EXHAUST VENTIALTION WHEN NECESSARY. Other Protective Equipment:DISPOSABLE GARMENTS IF DIRECT SKIN CONTACT IS ANTICIPATED. Work Hygienic Practices:WASH WITH SOAP AND WATER AFTER HANDLING PRODUCT AND BEFORE EATING DRINKING OR SMOKING. Supplemental Safety and Health POTENTIAL ADVERSE REACTIONS FROM PRESCRIBED DOSES AND OVERDOSES ARE DESCRIBED MORE FULLY IN THE PACKAGE INSERT. OCCUPATIONL EXPOSURE HAS NOT BEEN FULLY INVESTIGATED. ================== Physical/Chemical Properties ================== HCC:N1 Boiling Pt:B.P. Text:NOT GIVEN Melt/Freeze Pt:M.P/F.P Text:NOT GIVEN Vapor Pres:NOT GIVEN Vapor Density:NOT GIVEN Spec Gravity:NOT GIVEN Evaporation Rate & Reference:NOT GIVEN Solubility in Water:NOT GIVEN Appearance and Odor:OINMENT ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES NONE SPECIFIED BY MANUFACTURER. Stability Condition to Avoid:NONE SPECIFIED BY MANUFACTURER. Hazardous Decomposition Products:NONE SPECIFIED BY MANUFACTURER. ==================== Disposal Considerations ==================== Waste Disposal Methods:PREVENT WASTE FROM CONTAMINATING SURROUNDING ENVIRONMENT. DISCARD ANY PRODUCT, RESIDUE, DISPOSAL CONTAINER OR LINER IN ACCORDANCE WITH ALL FEDERAL, STATE AND LOCAL REGULATIONS.
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:HYSOL PC18M; PRODUCT CODE:P00011 Preparer's Name:JAMES P. HORNBURG CAGE:04347 CAGE:04347 CAGE:7B953 ============= Composition/Information on Ingredients ============= Ingred Name:URETHANE PREPOLYMER Fraction by Wt: 30-60% Other REC Limits:**** SEE TDI ***** Ingred Name:PROPYLENE GLYCOL MONOMETHYL ETHER ACETATE; 2-PROPANOL 1-METHYOXY ACETATE CAS:108-65-6 RTECS #:AI8925000 Fraction by Wt: 10-30% OSHA PEL:NOT ESTABLISHEDNOT Ingred Name:XYLENES (O-,M-,P- ISOMERS)(SARA III) CAS:1330-20-7 RTECS #:ZE2100000 Fraction by Wt: 15-20% OSHA PEL:100 PPM/150 STEL ACGIH TLV:100 PPM/150STEL;9192 EPA Rpt Qty:1000 LBS DOT Rpt Qty:1000 LBS Ingred Name:TOLUENE-2,4-DIISOCYANATE (TDI) (SARA III) CAS:584-84-9 RTECS #:CZ6300000 OSHA PEL:C,0.02 PPM/0.02 STEL ACGIH TLV:0.005PPM/0.02STEL;93 EPA Rpt Qty:100 LBS DOT Rpt Qty:100 LBS Ingred Name:ETHYL BENZENE (SARA III) CAS:100-41-4 RTECS #:DA0700000 Fraction by Wt: 5-10% Other REC Limits:NONE SPECIFIED OSHA PEL:100 PPM/125 STEL ACGIH TLV:100 PPM/125STEL 9192 EPA Rpt Qty:1000 LBS DOT Rpt Qty:1000 LBS ===================== Hazards Identification ===================== LD50 LC50 Mixture:NONE SPECIFIED BY MANUFACTURER. Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:ACUTE:SHORT TERM LIQUID OR VAPOR CONTACT MAY CAUSE SLIGHT IRRITATION TO EYES,SKIN AND RESPIRATORY TRACT. CHRONIC:PROLONGED AND/OR REPEATED CONTACT MAY CAUSE SEVERE IRRITATION TO EYES, DEFATTING AND DR YING OF THE SKIN WHICH MAY RESULT IN DERMATITIS. BREATHING OF LIQUID INTO LUNGS MAY CAUSE CHEMICAL PNEUMONITIS. Explanation of Carcinogenicity:TOLUENE-2,4-DIISOCYANATE (TDI) IS LISTED BY NTP & IARC. NTP AS ANTICIPATED CARCINOGEN,IARC AS ANIMAL CARCINOGEN. Effects of Overexposure:EYES:LIQUID/VAPOR CONTACT CAUSES IRRITATION. SKIN:MAY CAUSE SLIGHT IRRITATION.PROLONGED CONTACT MAY CAUSE MILD DERMATITIS. INGESTION:MAY CAUSE NAUSEA, VOMITING, AND DIARRHEA. INHALATION:CAUSES IRRITAT ION TO RESPIRATORY TRACT. ALSO CAUSES DIZZINESS, NAUSEA,AND FATIGUE, AND CAN LEAD TO CNS DEPRESSION AND UNCONSCIOUSNESS. Medical Cond Aggravated by Exposure:PERSONS WITH A SKIN OR RESPIRATORY SYSTEM AILMENT OR DISORDER MAY BE MORE SUSCEPTIBLE TO EFFECTS OF THIS PRODUCT. THESE PERSONS SHOULD BE CAUTIONED WHEN HANDLING OR USING THIS PRODUCT. ======================= First Aid Measures ======================= First Aid:EYES: FLUSH WITH WATER 15 MIN. SKIN:WIPE EXCESS. WASH WITH SOAP & WATER,THEN ISOPROPANOL. IF INTENSE REACTION OCCURS OR IRRITATION PERSISTS AFTER FLUSHING/WASHING OF EYES OR SKIN, GET MEDICAL CARE. IN HALATION: REMOVE FROM EXPOSURE. IF SEVERE OR ASTHMA REACTION,GET PROMPT MEDICAL CARE. INGESTION: DO NOT INDUCE VOMITING. GET IMMEDIATE MEDICAL ATTENTION. IF VOMITING OCCURS, AVOID ASPIRATION TO LUNGS. ===================== Fire Fighting Measures ===================== Flash Point Method:TCC Flash Point:81F/27C Lower Limits:1.0 Upper Limits:7.0 Extinguishing Media:DRY CHEMICAL,CARBON DIOXIDE,FOAM (WATER MAY BE INEFFECTIVE). Fire Fighting Procedures:FIGHT AS FLAMMABLE LIQUID. COOL FIRE EXPOSED CONTAINERS WITH WATER. WEAR SELF CONTAINED BREATHING APPARATUS. Unusual Fire/Explosion Hazard:CONTAINERS MAY BURST/EXPLODE IN HEAT OF FIRE. ================== Accidental Release Measures ================== Spill Release Procedures:SMALL SPILL:ABSORB ON PAPER,VERMICULITE OR ABSORBENT & PLACE IN A CONTAINER; LARGE SPILL (>1 QT): REMOVE IGNITION SOURCES.EXCLUDE UNPROTECTED PERSONS FROM SPILL AREA. DIKE AREA OF SPILL. ABSORB WITH A BSORBENT AND SHOVEL TO A DOT CONTAINER FOR DISPOSL Neutralizing Agent:NONE. HMIS:SOLVENT IS ISOPROPANOL. ======================Handling and Storage ====================== Handling and Storage Precautions:THE SELECTION OF PERSONAL PROTECTIVE EQUIPMENT SHOULD BE MADE BY THE MATERIAL USER BASED ON THE PARTICULAR CONDITIONS WHERE THE MATERIAL IS TO BE USED Other Precautions:DO NOT TAKE INTERNALLY. DO NOT BREATHE MIST. AVOID PROLONGED OR REPEATED BREATHING OF VAPOR. AVOID CONTACT WITH EYES. USE WITH ADEQUATE VENTILATION. WASH THOROUGHLY AFTER HANDLING. FOR INDUSTRIAL USE ONLY. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:USE NIOSH RESPIRATOR FOR ORGANIC VAPORS OR SUPPLIED A MASK. Ventilation:USE MECHANICAL VENTILATION AND LOCAL EXHAUST TO MAINTAIN EXPOSURE BELOW TLV/PEL. Other Protective Equipment:RUBBER APRON. Work Hygienic Practices:USE VERY STRICT CHEMICAL HYGIENE PRACTICE. AVOID CONTACT IF AT ALL POSSIBLE. Supplemental Safety and Health PRODUCT CONTAINS SOME UNREACTED TOULENE DIISOCYANATE (TDI),THE MOST HAZARDOUS INGREDIENT. MANUFACTURER DOES NOT GIVE ANY INDICATION IN THE MSDS ABOUT THE PRESENCE AND PERCENT OF TDI. BUT MSDS DOES STA TE THE PEL OF TDI. THE TDI MAY BE LESS THAN 0.1% IN URETHANE PREPOLMER. IT IS A GUESS. ================== Physical/Chemical Properties ================== HCC:F3 Boiling Pt:=138.3C, 281.F Vapor Pres:9.5 Spec Gravity:1.02 Evaporation Rate & Reference:0.54 (BUAC) Solubility in Water:NEGLIGIBLE Appearance and Odor:LIGHT AMBER,MEDIUM VISCOSITY LIQUID,AROMATIC ESTER SOLVENT ODOR. Percent Volatiles by Volume:58 ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES OXIDIZING MATERIALS. Stability Condition to Avoid:HEAT,IGNITION SOURCES. Hazardous Decomposition Products:CARBON DIOXIDE, CARBON MONOXIDE, POSSIBLE NITROGEN OXIDES ==================== Disposal Considerations ==================== Waste Disposal Methods:DISPOSE OF IN ACCORDANCE FEDERAL, STATE, LOCAL REGULATIONS.
1
eyes_protection_mandatory
======================================================= Product ID: HBM-515A, CHLORINATED HERBICIDE ACIDS MIXTURE(SUPDAT) Cage: 0MU35 ======================================================= Contractor Summary ======================================================= Cage: 0MU35 ======================================================= Ingredients ======================================================= Cas: 1918-02-1 RTECS #: TJ7525000 2898 MG/KG. % Wt: 0.013 OSHA PEL: 15 MG/M3 TDUST ACGIH TLV: 10 MG/M3 ------------------------------ Cas: 100-02-7 RTECS #: SM2275000 LD50:(ORAL,RAT) 250 MG/KG. % Wt: 0.013 OSHA PEL: N/K (FP N) ACGIH TLV: N/K (FP N) EPA Rpt Qty: 100 LBS DOT Rpt Qty: 100 LBS ------------------------------ Cas: 51-36-5 RTECS #: DG7350000 % Wt: 0.013 OSHA PEL: N/K (FP N) ACGIH TLV: N/K (FP N) ----------------------------- Cas: 133-90-4 RTECS #: DG1925000 LD50:(ORAL,RAT) 5620 MG/KG. % Wt: 0.013 OSHA PEL: N/K (FP N) ACGIH TLV: N/K (FP N) EPA Rpt Qty: 1 LB DOT Rpt Qty: 1 LB ------------------------------ Cas: 87-86-5 RTECS #: SM6300000 MG/KG. % Wt: 0.013 OSHA PEL: 0.5 MG/M3, S ACGIH TLV: 0.5 MG/M3, S EPA Rpt Qty: 10 LBS DOT Rpt Qty: 10 LBS ------------------------------ Cas: 25057-89-0 RTECS #: DK9900000 (BENTAZON). LD50:(ORAL,RAT) 1100 MG/KG. % Wt: 0.025 OSHA PEL: N/K (FP N) ACGIH TLV: N/K (FP N) ------------------------------ Cas: 67-56-1 RTECS #: PC1400000 % Wt: 99.51 OSHA PEL: 200 PPM;250 STEL, S ACGIH TLV: 200 PPM;250 STEL, S EPA Rpt Qty: 5000 LBS DOT Rpt Qty: 5000 LBS ------------------------------ Cas: 94-75-7 RTECS #: AG6825000 375 MG/KG. % Wt: 0.025 OSHA PEL: 10 MG/M3 ACGIH TLV: 10 MG/M3 EPA Rpt Qty: 100 LBS DOT Rpt Qty: 100 LBS ------------------------------ Cas: 75-99-0 RTECS #: UF0690000 6600 MG/KG. % Wt: 0.164 OSHA PEL: 1 PPM ACGIH TLV: 1 PPM EPA Rpt Qty: 5000 LBS DOT Rpt Qty: 5000 LBS ------------------------------ Cas: 94-82-6 RTECS #: ES9100000 MG/KG. % Wt: 0.101 OSHA PEL: N/K (FP N) ACGIH TLV: N/K (FP N) ------------------------------ Cas: 1918-00-9 RTECS #: DG7525000 % Wt: 0.013 OSHA PEL: N/K (FP N) ACGIH TLV: N/K (FP N) EPA Rpt Qty: 1000 LBS DOT Rpt Qty: 1000 LBS ------------------------------ Cas: 120-36-5 RTECS #: UF1050000 800 MG/KG. % Wt: 0.038 OSHA PEL: N/K (FP N) ACGIH TLV: N/K (FP N) ------------------------------ Cas: 88-85-7 RTECS #: SJ9800000 58 MG/KG. % Wt: 0.025 OSHA PEL: N/K (FP N) ACGIH TLV: N/K (FP N) EPA Rpt Qty: 1000 LBS DOT Rpt Qty: 1000 LBS ------------------------------ Cas: 93-72-1 RTECS #: UF8225000 III). LD50:(ORAL,RAT) 650 MG/KG. % Wt: 0.013 OSHA PEL: N/K (FP N) ACGIH TLV: N/K (FP N) EPA Rpt Qty: 100 LBS DOT Rpt Qty: 100 LBS ------------------------------ Cas: 93-76-5 RTECS #: AJ8400000 LD50:(ORAL,RAT) 500 MG/KG. % Wt: 0.013 OSHA PEL: 10 MG/M3 ACGIH TLV: 10 MG/M3 EPA Rpt Qty: 1000 LBS DOT Rpt Qty: 1000 LBS ------------------------------ Cas: 62476-59-9 RTECS #: DG5643200 SALT; (ACTIFLUORFEN). LD50:(ORAL,RAT) 137 MG/KG. % Wt: 0.013 OSHA PEL: N/K (FP N) ACGIH TLV: N/K (FP N) ======================================================= Health Hazards Data ======================================================= LD50 LC50 Mixture: SEE INGREDIENTS. Route Of Entry Inds - Inhalation: YES Skin: YES Ingestion: YES Carcinogenicity Inds - NTP: NO IARC: YES OSHA: NO Effects of Exposure: CONTAINS CARCINOGEN(S) OR CANCER SUSPECT AGENT(S). TOXIC; IRRITANT. ALL CHEMICALS SHOULD BE CONSIDERED HAZARDOUS. Explanation Of Carcinogenicity: DICHLORPROP:IARC MONOGRAPHS, SUPP, VOL 7, PG 156, 1987:GRP 2B. Signs And Symptions Of Overexposure: SEE HEALTH HAZARDS. Medical Cond Aggravated By Exposure: NONE SPECIFIED BY MANUFACTURER. First Aid: INGEST:CALL MD IMMEDIATELY (FP N). EYE:FLUSH W/COPIOUS AMOUNTS OF WATER FOR AT LEAST 15 MINUTES. SKIN:FLUSH W/COPIOUS AMOUNTS OF WATER. INHAL:REMOVE TO FRESH AIR - GIVE OXYGEN, IF NECESSARY. CONTACT M D. ======================================================= Handling and Disposal ======================================================= Spill Release Procedures: DUE TO THE SMALL QUANTITY INVOLVED, SPILLS OR LEAKS SHOULD NOT POSE A SIGNIFICANT PROBLEM. A LEAKING BOTTLE MAY BE PLACED IN A PLASTIC BAG & NORMAL DISPOSAL PROCEDURES FOLLOWED. LIQUID SAMPLES MAY BE ABSORBED ON VERMICULITE OR SAND. Neutralizing Agent: NONE SPECIFIED BY MANUFACTURER. Waste Disposal Methods: BURN IN A CHEMICAL INCINERATOR EQUIPPED W/AN AFTERBURNER & SCRUBBER. OBSERVE ALL FEDERAL, STATE & LOCAL LAWS CONCERNING DISPOSAL. Handling And Storage Precautions: KEEP TIGHTLY CLOSED & STORE IN A COOL, DRY PLACE. DIRECT PHYSICAL CONTACT SHOULD BE AVOIDED. Other Precautions: THIS MATERIAL SHOULD ONLY BE USED BY THOSE PERSONS TRAINED IN THE SAFE HANDLING OF HAZARDOUS CHEMICALS. ======================================================= Fire and Explosion Hazard Information ======================================================= Extinguishing Media: CARBON DIOXIDE, DRY CHEMICAL POWDER OR WATER SPRAY. Fire Fighting Procedures: USE NIOSH/MSHA APPROVED SCBA & FULL PROTECTIVE EQUIPMENT (FP N). Unusual Fire/Explosion Hazard: COMBUSTIBLE. ======================================================= Control Measures ======================================================= Respiratory Protection: NIOSH/MSHA APPROVED RESPIRATOR APPROPRIATE FOR EXPOSURE OF CONCERN (FP N). Ventilation: NONE SPECIFIED BY MANUFACTURER. Other Protective Equipment: USE APPROP NIOSH/MSHA APPRVD SFTY EQUIP. WEAR CHEM RESIST CLTHG SUCH AS LAB COAT &/OR RUBBER APRON TO PVNT CONT (SUPDAT) Work Hygienic Practices: NONE SPECIFIED BY MANUFACTURER. Supplemental Safety and Health: MFR'S TRADE NAME/PART NO:IN METHANOL. OTHER LENGTH FACE SHIELD (FP N). ======================================================= Physical/Chemical Properties ======================================================= Appearance and Odor: LIQUID. ======================================================= Reactivity Data ======================================================= Stability Indicator: YES Stability Condition To Avoid: NONE SPECIFIED BY MANUFACTURER. Materials To Avoid: STRONG OXIDIZERS. Hazardous Polymerization Indicator: NO Conditions To Avoid Polymerization: NOT RELEVANT ======================================================= Toxicological Information ======================================================= ======================================================= Ecological Information ======================================================= ======================================================= ======================================================= ======================================================= Regulatory Information ======================================================= ======================================================= Other Information ======================================================= ======================================================= HAZCOM Label ======================================================= Product ID: LABEL COVERED UNDER EPA REGS - HAZCOM LABEL NOT AUTHORIZED =======================================================
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:6330M, GREASE Preparer's Name:DA POLSINELLI CAGE:01139 CAGE:01139 CAGE:33530 CAGE:2B613 ============= Composition/Information on Ingredients ============= Ingred Name:ZINC NAPHTHENATE CAS:12001-85-3 RTECS #:QK9275000 Fraction by Wt: 1-5% Other REC Limits:NONE RECOMMENDED Ingred Name:LITHIUM SOAP THICKENER CAS:4485-12-5 RTECS #:WI4370000 Fraction by Wt: 10-30% Other REC Limits:NONE RECOMMENDED OSHA PEL:15 MG/M3 TDUST ACGIH TLV:10 MG/M3 (STEARATES) Ingred Name:TEFLON (TETRAFLUORO ETHYLENE POLYMER) CAS:116-14-3 RTECS #:KX4025000 Fraction by Wt: 1-5% Other REC Limits:NONE RECOMMENDED OSHA PEL:15 MG/M3 TDUST ACGIH TLV:10 MG/M3 TDUST Ingred Name:METHYL DECYL POLYSILOXANE CAS:68607-71-6 Fraction by Wt: 60-80% Other REC Limits:NONE RECOMMENDED ===================== Hazards Identification ===================== LD50 LC50 Mixture:LD50 (ORAL, RAT) IS >16500 MG/KG. Routes of Entry: Inhalation:YES Skin:YES Ingestion:NO Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:INGESTION-NONE KNOWN. SKIN CONTACT-MAY CAUSE MILD SKIN IRRITATION. EYE CONTACT-MAY IRRITATE EYES. Explanation of Carcinogenicity:THIS PRODUCT IS NOT LISTED AS A CARCINOGEN OR SUSPECT CARCINOGEN BY NTP, IARC OR OSHA. Effects of Overexposure:SUBCHRONIC (TARGET ORGAN) EFFECTS: RESPIRATORY AILMENTS. Medical Cond Aggravated by Exposure:NONE KNOWN. ======================= First Aid Measures ======================= First Aid:INGESTION:RINSE MOUTH WITH WATER SEVERAL TIMES. SKIN: WASH WITH SOAP AND WATER. INHALATION: MOVE PERSON TO FRESH AIR. EYES: IN CASE OF CONTACT, IMMEDIATELY FLUSH EYES WITH PLENTY OF WATER FOR AT LEAST 15MINUTES AND GET MEDICAL ATTENTION IFIRRITATION PERSISTS. ===================== Fire Fighting Measures ===================== Flash Point:NA Lower Limits:NA Upper Limits:NA Extinguishing Media:ALL STANDARD FIREFIGHTING MEDIA. Fire Fighting Procedures:NONE KNOWN. ================== Accidental Release Measures ================== Spill Release Procedures:WIPE, SCRAPE OR SOAK UP IN AN INERT MTERIAL AND PUT IN A CONTAINER FOR DISPOSAL. WASH WALKING SURFACES WITH DETERGENT AND WATER TO REDUCE SLIPPING HAZARD WEAR PROPER PROTECTIVE EQUIPMENT AS SPECIFIED IN THE PROTECTIVE EQUIPMENT SECTION. Neutralizing Agent:NONE ======================Handling and Storage ====================== Handling and Storage Precautions:AVOID CONTACT WITH EYES. Other Precautions:NONE ============= Exposure Controls/Personal Protection ============= Respiratory Protection:NONE KNOWN. Ventilation:NONE KNOWN. Other Protective Equipment:EYE WASH STATIONS. Work Hygienic Practices:NONE KNOWN. Supplemental Safety and Health FORMULA CHANGE. ================== Physical/Chemical Properties ================== HCC:V6 Boiling Pt:B.P. Text:NA Melt/Freeze Pt:M.P/F.P Text:NA Decomp Temp:Decomp Text:NA Vapor Pres:NEGL Vapor Density:NEGL Spec Gravity:0.93 pH:NA Evaporation Rate & Reference:NEGL (N-BUTYL ACETATE=1) Solubility in Water:<1% Appearance and Odor:YELLOW TO PURPLE SOLID - ORGANIC ODOR Percent Volatiles by Volume:<1% Corrosion Rate:NA ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES NONE KNOWN. Stability Condition to Avoid:NONE KNOWN. Hazardous Decomposition Products:CARBON MONOXIDE. CARBON DIOXIDE. FORMALDEHYDE. Conditions to Avoid Polymerization:POLYMERIZATION WILL NOT OCCUR. ==================== Disposal Considerations ==================== Waste Disposal Methods:DISPOSAL SHOULD BE MADE IN ACCORDANCE WITH FEDERAL, STATE AND LOCAL REGULATIONS.
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:9058 WALL & CEILING LATEX SEMI-GLOSS PAINT CAGE:01PD6 CAGE:72818 CAGE:01PD6 ============= Composition/Information on Ingredients ============= Ingred Name:1,2-PROPANEDIOL (PROPYLENE GLYCOL) CAS:57-55-6 RTECS #:TY2000000 Fraction by Wt: 1-5% Ingred Name:TITANIUM DIOXIDE, TIO2 CAS:13463-67-7 RTECS #:XR2275000 Fraction by Wt: 10-20% OSHA PEL:15 MG/M3 TDUST ACGIH TLV:10 MG/M3 TDUST; 9293 Ingred Name:VINYL ACRYLIC RESIN *92-4* CAS:25067-01-0 Fraction by Wt: 10-20% Ingred Name:WATER CAS:7732-18-5 RTECS #:ZC0110000 Fraction by Wt: 50-60% Ingred Name:WEIGHT PER GALLON IN POUNDS: 10.1 RTECS #:9999999WG Ingred Name:CLAY (KAOLIN) CAS:1332-58-7 RTECS #:GF1670500 Fraction by Wt: 1-5% OSHA PEL:15 MG/M3 TDUST ACGIH TLV:2 MG/M3 TDUST; 9293 Ingred Name:GLYCOL ETHERS, DIETHYLENE GLYCOL, 2,2-OXYBISETHANOL CAS:111-46-6 RTECS #:ID5950000 Fraction by Wt: 1-5% Ingred Name:STYRENE-ACRYLATE COPOLYMER Fraction by Wt: 1-5% ===================== Hazards Identification ===================== Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:INHALATION: IRRITATION OF RESPIRATORY TRACT. SKIN: ABSORPTION. EYES: IRRITATION. Explanation of Carcinogenicity:NONE Effects of Overexposure:INHALATION: DIZZINESS &/OR LIGHTHEADEDNESS, HEADACHE, NAUSEA. SKIN: DERMATITIS, DIZZINESS &/OR LIGHTHEADEDNESS, NAUSEA. MAY BE ABSORBED. INGESTION: LARGE AMOUNTS COULD CAUSE SERIOUS INJURY. ======================= First Aid Measures ======================= First Aid:INHALATION: REMOVE TO FRESH AIR. RESTORE & SUPPORT BREATHING. GIVE OXYGEN IF NECESSARY & IF BREATHING DIFFICULTY. SKIN: WASH W/PLENTY OF WATER & SOAP. EYES: FLUSH W/WATER FOR AT LEAST 15 MINUTES. INGE STION: OBTAIN MEDICAL ATTENTION IN ALL CASES. ===================== Fire Fighting Measures ===================== Flash Point:>200F Extinguishing Media:DRY CHEMICAL, FOAM Fire Fighting Procedures:WATER MAY BE USED TO COOL & PROTECT EXPOSED CONTAINERS. Unusual Fire/Explosion Hazard:CLOSED CONTAINERS MAY BURST IF EXPOSED TO EXTREME HEAT OR FIRE. ================== Accidental Release Measures ================== Spill Release Procedures:VENTILATE AREA. SPILLS MAY BE COLLECTED W/ABSORBENT MATERIAL. COMPLY W/APPLICABLE & ENVIRONMENTAL REGULATIONS. ======================Handling and Storage ====================== Handling and Storage Precautions:STORE <100F. KEEP FROM FREEZING. USE ONLY W/ADEQUATE VENTILATION. DON'T TAKE INTERNALLY. KEEP OUT OF REACH OF CHILDREN. Other Precautions:KEEP CONTAINERS TIGHTLY CLOSED & UPRIGHT WHEN NOT IN USE. AVOID CONTACT W/SKIN, EYES & BREATHING OF VAPORS. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:IF SANDING IS DONE WEAR A DUST MASK. WHERE RESPIRATORY PROTECTION IS REQUIRED, USE ONLY NIOSH/MSHA APPROVED RESPIRATORS. Ventilation:DILUTE VENTILATION OR LOCAL EXHAUST TO PREVENT BUILD UP OF VAPORS. Other Protective Equipment:EYE WASH, SAFETY SHOWER Work Hygienic Practices:WASH HANDS THOROUGHLY AFTER HANDLING, BEFORE EATING OR SMOKING. REMOVE/LAUNDER CONTAMINATED CLOTHING BEFORE REUSE. Supplemental Safety and Health ================== Physical/Chemical Properties ================== Boiling Pt:B.P. Text: 212F Percent Volatiles by Volume:68.3% ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES OXIDIZERS Stability Condition to Avoid:ELEVATED TEMPERATURES Hazardous Decomposition Products:CO, CO2 ==================== Disposal Considerations ==================== Waste Disposal Methods:DISPOSE IN ACCORDANCE WITH ALL APPLICABLE REGULATIONS. AVOID DISCHARGE TO NATURAL WATERS.
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:PR-2911, BLACK, PART B Kit Part:Y Preparer's Name:A. OMAR CAGE:83574 CAGE:83574 ============= Composition/Information on Ingredients ============= Ingred Name:1-METHOX-2-PROPONAL ACETATE (PM ACETATE) CAS:108-65-6 RTECS #:AI8925000 Fraction by Wt: 15% Other REC Limits:100 PPM TLV Ingred Name:POLYTHIOETHER POLYMER WITH METHYLENE BIS CAS:83346-49-0 Fraction by Wt: 80% Other REC Limits:NONE RECOMMENDED Ingred Name:METHYLENE BIS(4-CYCLOHEXYL ISOCYANATE) (H12MDI) CAS:5124-30-1 RTECS #:NQ9250000 Fraction by Wt: <5% Other REC Limits:NONE RECOMMENDED OSHA PEL:CEILING 0.01 PPM ACGIH TLV:0.005 PPM Ingred Name:VOC: 510 G/L (MIXED) RTECS #:9999999VO Other REC Limits:NONE RECOMMENDED ===================== Hazards Identification ===================== Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES Health Hazards Acute and Chronic:EYE: (VAPOR) IRRITATION, TEARS. (LIQUID) IRRITATION, POSSIBLE PERMANENT DAMAGE. SKIN: SWELLING, SORENESS, ITCHING, ALLERGIC SKIN RASH. INHALATION: IRRITATION OF NOSE, THROAT, EYE. BRONCHIAL IRRITATN W /COUGH, TIGHTNESS IN CHEST, DIFFICULT BREATHING, ASTHMA-LIKE SYMPTOMS. INGESTION: IRRITATION OF DIGESTIVE TRACT, STOMACH ======================= First Aid Measures ======================= First Aid:EYE: FLUSH WITH LUKE WARM WATER FOR 15 MINUTES. CONSULT PHYSICIAN. SKIN: WASH THOROUGHLY WITH SOAP AND WATER. COVER EXPOSED AREAS WITH POLYEHTYLENE GLYCOL (300-500 MW). WASH AGAIN WITH SOAP AND WATER.DISCARD OR DECONTAMINATE CLOTHING. CONSULT PHYSICIAN IF SYMPTOMS PERSIST. INHALATION: REMOVE TO FRESH AIR. CONSULT PHYSICIAN IF SYMPTOMS ARE PRESENT. INGESTION: GIVE MILK OR WATER. CONSULT PHYSICIAN. ===================== Fire Fighting Measures ===================== Flash Point Method:PMCC Flash Point:116F,47C Lower Limits:1.5% Upper Limits:7% Extinguishing Media:CO2, DRY CHEMICAL, FOAM, WATER FOG Fire Fighting Procedures:USE WATER TO COOL HEAT EXPOSED CONTAINERS. Unusual Fire/Explosion Hazard:HIGH TEMPERATURES MAY CAUSE PRESSURE BUILDUP IN CLOSED CONTAINERS. ================== Accidental Release Measures ================== Spill Release Procedures:WEAR AIR-SUPPLIED RESPIRATOR FOR MAJOR UNVENTED SPILL. COVER W/ABSORBANT MATERIAL, ADD DECONTAMINATION SOLUTION (5% CONC AMMONIA, 2% DETERGENT, 93% WATER). ALLOW TO REACT 10 MIN. COLLECT IN CONTAINER, ADD ADDITIONAL DECONTAMINATION SOLUTION, KEEP ** Neutralizing Agent:**LOOSELY COVERED FOR 48 HOURS. CLEAN UP RESIDUE WITH A SUITABLE SOLVENT. ======================Handling and Storage ====================== Handling and Storage Precautions:USER MUST BE FULLY PROTECTED WHEN SPRAYING. FULL PERMEATION RESISTANT PROTECTIVE SUIT INCLUDING HEAD Other Precautions:SPRAY SHOULD BE ISOLATED/OPEN AREAS. SEPARATE AT LEAST 100 FT FROM NON-PROTECTED PERSONS. SEPARATE SPRAY AREAS WITH WALLS AND VENTILATE. AVOID MOISTURE CONTAMINATION WHICH WILL CAUSE CO2 PRESSURE. DON 'T RESEAL CONTAINR IF MOISTURE SUSPECTED ============= Exposure Controls/Personal Protection ============= Respiratory Protection:AN AIR-SUPPLIED RESPIRATOR MUST BE USED. Ventilation:GENERAL VENT MAINTAIN VAPORS BELOW TLV. WHEN APPLY IN CONFINED AREAS LIKELY TO PRODUCE AIRBORNE LVLS, USE AIR-SUPP RESP. Supplemental Safety and Health DURING SPRAY APPLICATION, STRINGENT PRECAUTIONS MUST BE TAKEN TO ENSURE THE SAFETY OF THE PERSONS INVOLVED WITH THE APPLICATION, OTHER PERSONS WORKING IN THE AREA, AND THE GENERAL PUBLIC. ================== Physical/Chemical Properties ================== HCC:F4 Vapor Density:4.61 (PM A Spec Gravity:1.12 Evaporation Rate & Reference:0.4 (PM ACETATE) Solubility in Water:APPRECIABLE Appearance and Odor:WHITE PASTE ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES WATER, ALCOHOLS, STRONG BASES, AMINES, STRONG OXIDIZING AGENTS. Hazardous Decomposition Products:OXIDES OF CARBON AND NITROGEN; POSSIBLE TRACES OF HCN. ==================== Disposal Considerations ==================== Waste Disposal Methods:EPA WASTE NO. D-001. DISPOSE OF SPILLAGE IN COMPLIANCE WITH FEDERAL AND STATE REGULATIONS.
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:S0101 SODIUM PHOSPHATE TRIBASIC TSP CAGE:8U825 CAGE:8U825 ============= Composition/Information on Ingredients ============= Ingred Name:PHOSPHORIC ACID, TRISODIUM SALT, DODECAHYDRATE CAS:10101-89-0 RTECS #:TC9575000 OSHA PEL:1 MG/CUM ACGIH TLV:1 MG/CUM EPA Rpt Qty:5000 LBS DOT Rpt Qty:5000 LBS ===================== Hazards Identification ===================== Routes of Entry: Inhalation:NOSkin:NO Ingestion:YES Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:SKIN: IRRITATION. INGESTION: MODERATELY TOXIC. Explanation of Carcinogenicity:NONE Effects of Overexposure:IRRITATION ======================= First Aid Measures ======================= First Aid:SKIN: WASH W/COPIOUS QUANTITIES OF WATER. INGESTION: WASH MOUTH. EYES: WASH CONTINUOUSLY FOR 15 MINS. OBTAIN MEDICAL ATTENTION IN ALL CASES. ===================== Fire Fighting Measures ===================== Flash Point:NON-FLAMMABLE Unusual Fire/Explosion Hazard:DECOMPOSITION RELEASES TOXIC FUMES. ================== Accidental Release Measures ================== Spill Release Procedures:GATHER UP MATERIAL IN A PILE (DON'T SWEEP). PLACE IN A SUITABLE CONTAINER. ======================Handling and Storage ====================== Other Precautions:AVOID BODY CONTACT. ============= Exposure Controls/Personal Protection ============= Supplemental Safety and Health ================== Physical/Chemical Properties ================== Melt/Freeze Pt:M.P/F.P Text:167F Spec Gravity:1.62 Solubility in Water:COMPLETE Appearance and Odor:COLORLESS, ODORLESS CRYSTALS ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES Hazardous Decomposition Products:TOXIC FUMES ==================== Disposal Considerations ==================== Waste Disposal Methods:DISPOSE OF IN ACCORDANCE W/LOCAL, STATE & FEDERAL REGULATIONS.
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:2753 CIDEX FORMULA 7 CAGE:DO393 CAGE:52780 CAGE:DO393 ============= Composition/Information on Ingredients ============= Ingred Name:GLUTARALDEHYDE CAS:111-30-8 RTECS #:MA2450000 Fraction by Wt: 2.5% Other REC Limits:0.2 PPM ACGIH TLV:C 0.82 MG/CUM Ingred Name:INERT BUFFER SALTS Fraction by Wt: 2.1% Ingred Name:WATER CAS:7732-18-5 RTECS #:ZC0110000 Fraction by Wt: 95.4% ===================== Hazards Identification ===================== LD50 LC50 Mixture:ORAL LD50 (RAT): 17,500 MG/KG Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:EYES: CAUSES DAMAGE, POSSIBLE CORNEAL INJURY. SKIN: IRRITATION, DAMAGE, SENSITIZATION, ALLERGIC DERMATITIS. INHALATION: IRRITATION OF THE RESPIRATORY TRACT. INGESTION: IRRITATION/CHEMICAL BURNS OF THE MOUTH, THROAT, ESOPHAGUS & STOMACH. Explanation of Carcinogenicity:NONE Effects of Overexposure:STINGING SENSATION, IRRITATION, DISCHARGE, BLEEDING FROM NOSE, COUGHING, DISCOMFORT, TIGHTNESS, BREATHING DIFFICULTY, BRONCHITIS, ASTHMA, HEADACHE, BURNS, NAUSEA, VOMITING, DIARRHEA, DIZZINESS, FAINTN ESS. Medical Cond Aggravated by Exposure:PRE-EXISTING DERMATITIS. GLUTARALDEHYDE: PRE-EXISTING ASTHMA, BRONCHITIS, INFLAMMATORY/FIBROTIC PULMONARY DISEASE. ======================= First Aid Measures ======================= First Aid:EYES/SKIN: IMMEDIATELY FLUSH W/WATER FOR 15 MINS. INHALATION: REMOVE TO FRESH AIR. GIVE OXYGEN IF NEEDED BY A QUALIFIED PERSONNEL. INGESTION: DON'T INDUCE VOMITING. DRINK LARGE QUANTITES OF WATER. OBT AIN MEDICAL ATTENTION IN ALL CASES. NOTE TO PHYSICICAN: PROBABLE MUCOSAL DAMAGE FROM ORAL EXPOSURE MAY CONTRAINDICATE THE USE OF GASTRIC LAVAGE. ===================== Fire Fighting Measures ===================== Flash Point:NONE Extinguishing Media:SMALL: CO2/DRY CHEMICAL. LARGE: ALCOHOL-TYPE/ALL-PURPOSE-TYPE FOAM. Fire Fighting Procedures:WEAR SELF CONTAINED BREATHING APPARATUS & PROTECTIVE CLOTHING. Unusual Fire/Explosion Hazard:AFTER WATER EVAPORATES, REMAINING MATERIAL WILL BURN. ================== Accidental Release Measures ================== Spill Release Procedures:WEAR SUITABLE PROTECTIVE EQUIPMENT. LARGE (> 1 GAL): NEUTRALIZED GLUTARALDEHYDE ODOR. COLLECT & DISCARD ACCORDING TO WASTE DISPOSAL GUIDELINE. SMALL (1 GAL/LESS): WIPE W/SPONGE/MOP DOWN W/AN EQUAL MIX TURE OF HOUSEHOLD AMMONIA & WATER. (SEESUPP) Neutralizing Agent:500 GRAMS OF AMMONIUM CARBONATE POWDER PER ESTIMATED GALLON OF SPILL ======================Handling and Storage ====================== Handling and Storage Precautions:PRIOR TO ACTIVATION, STORE IN ORIGINAL SEALED CONTAINER AT CONTROLLED ROOM TEMP, 59-86F. USE IN A WELL VENTILATED ROOM. Other Precautions:AVOID CONTAMINATION OF FOOD. DON'T USE NEOPRENE ============= Exposure Controls/Personal Protection ============= Respiratory Protection:EMERGENCY: ORGANIC VAPOR CARTRIDGE MASK/SELF CONTAINED BREATHING APPARATUS. Ventilation:ROOM W/MINIMUM OF 10 AIR CHANGES/HOUR. ROOMS W/<10 AIR CHANGES/HOUR/USE LOCAL EXHAUST/HOOD/DUCTLESS FUME HOODS/PORTABLES Other Protective Equipment:BUTYL RUBBER/STYRENE-ETHYLENE-BUTADIENE-STYRENE BLOCK COPOLYMER Work Hygienic Practices:AVOID CONTAMINATION OF FOOD. REMOVE/LAUNDER CONTAMINATED CLOTHING BEFORE REUSE. DISCARD CONTAMINATED SHOES/BELTS. Supplemental Safety and Health SPILL CONT'D: SMALL: FLUSH W/LARGE QUANTITIES OF WATER DOWN DRAIN. WASTE CONT'D: FOR 2 1/2 GAL CONTAINER/RINSE EMPTY CONTAINER THOROUGHLY W/WATER & DISPOSE IN AN INCINERATOR/LANDFILL APPROVED FOR PEST ICIDE CONTAINER IAW/FEDERAL, STATE & LOCAL REGULATIONS. ================== Physical/Chemical Properties ================== Boiling Pt:B.P. Text:212F Melt/Freeze Pt:M.P/F.P Text:32F Vapor Pres:16 Spec Gravity:1.003 pH:7-8.1 Evaporation Rate & Reference:(WATER =1): 0.98 Solubility in Water:COMPLETE Appearance and Odor:COLORLESS FLUID/LIQUID SALTS/GREEN IF ACTIVATED W/SHARP ODOR & PEPPERMINT SCENT ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES STRONG ALKALINE MATERIALS (PH >10) CATALYZE AN ALDOL-TYPE CONDENSATION WHICH IS EXOTHERMIC. Hazardous Decomposition Products:CO, CO2 ==================== Disposal Considerations ==================== Waste Disposal Methods:DISCARD RESIDUAL SOLUTION IN DRAIN. FLUSH THOROUGHLY W/LARGE QUANTITIES OF WATER. FOR QT & GAL CONTAINERS RINSE, RINSE EMPTY CONTAINER THOROUGHLY W/WATER, WRAP & PUT IN TRASH. DON'T REUSE EMPTY CONTAI NER. (SEE SUPP)
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:11-4276 DIAMOND/CUBIC BORON NITRIDE GRINDING WHEELS CAGE:09410 CAGE:09410 ============= Composition/Information on Ingredients ============= Ingred Name:SILICON CAS:7440-21-3 RTECS #:VW0400000 Fraction by Wt: 5% ACGIH TLV:10 MG/CUM Ingred Name:CRYSTALLINE-QUARTZ SILICA, SILICA DUST (SUSPECTED HUMAN CARCINOGEN BY IARC-GROUP 2A; SUSPECTED CARCINOGEN NTP) *96-2* CAS:14808-60-7 RTECS #:VV7330000 Fraction by Wt: <1% Other REC Limits:0.05 MG/CUM (NIOSH) OSHA PEL:10 MG/CUM %RESP SIO2 ACGIH TLV:0.1 MG/CUM RESP DUST Ingred Name:TUNGSTEN CARBIDE CAS:12070-12-1 RTECS #:YO7250000 Fraction by Wt: 20% Other REC Limits:5 MG(W)/M3 ACGIH TLV:5 MG(W)/M3 Ingred Name:SILVER* 96-2 * CAS:7440-22-4 RTECS #:VW3500000 Fraction by Wt: 85% OSHA PEL:0.01 MG/CUM ACGIH TLV:0.1 MG/CUM EPA Rpt Qty:1 LB DOT Rpt Qty:1 LB Ingred Name:COBALT (ANIMAL CARCINOGEN BY IARC - GROUP 2B) *96-2* CAS:7440-48-4 RTECS #:GF8750000 Fraction by Wt: 60% Other REC Limits:0.05 PPM OSHA PEL:0.1 MG/CUM ACGIH TLV:0.05 MG/CUM Ingred Name:COPPER (DUST & MIST), BRONZE POWDER *96-2* CAS:7440-50-8 RTECS #:GL5325000 Fraction by Wt: 85% Other REC Limits:1 MG(CU)/M3 (DUST) OSHA PEL:0.1 MG(CU)/M3 (FUME) ACGIH TLV:0.2 MG/M3 (FUME) EPA Rpt Qty:5000 LBS DOT Rpt Qty:5000 LBS Ingred Name:TIN (AS SN) CAS:7440-31-5 RTECS #:XP7320000 Fraction by Wt: 25% OSHA PEL:2 MG/CUM ACGIH TLV:2.0 MG/CUM Ingred Name:GRAPHITE CAS:7782-42-5 RTECS #:MD9659600 Fraction by Wt: 20% Other REC Limits:2.5MG/CUM ACGIH TLV:2 MG/CUM RESP IC Ingred Name:SILICON CARBIDE CAS:409-21-2 RTECS #:VW0450000 Fraction by Wt: 73% ACGIH TLV:10 MG/CUM Ingred Name:ALUMINUM OXIDE, BAUXITE, ALUMINA, DIALUMINUM TRIOXIDE *96-2* CAS:1344-28-1 RTECS #:BD1200000 Fraction by Wt: 81% OSHA PEL:15 MG/CUM ACGIH TLV:10 MG/CUM Ingred Name:NICKEL (SUSPECTED ANIMAL/HUMAN CARCINOGEN BY IARC GROUP 2B, SUSPECTED CARCINOGEN BY NTP) *96-2* CAS:7440-02-0 RTECS #:QR5950000 Fraction by Wt: 82% Other REC Limits:1 MG/CUM OSHA PEL:1 MG/CUM ACGIH TLV:0.05 MG/CUM IC Ingred Name:PHOSPHORUS (YELLOW & WHITE) CAS:7723-14-0 RTECS #:TH3500000 Fraction by Wt: 1% Other REC Limits:100 UG/CUM OSHA PEL:0.1 MG/CUM ACGIH TLV:0.1 MG/CUM EPA Rpt Qty:1 LB DOT Rpt Qty:1 LB Ingred Name:MANGANESE, MN COMPOUNDS CAS:7439-96-5 RTECS #:OO9275000 Fraction by Wt: 3% OSHA PEL:5 MG/CUM ACGIH TLV:5 MG/CUM (DUST) Ingred Name:MOLYBDENUM (SOLUBLE COMPOUND) CAS:7439-98-7 RTECS #:QA4680000 Fraction by Wt: 1% OSHA PEL:5 MG/CUM ACGIH TLV:5 MG/CUM ===================== Hazards Identification ===================== Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES Reports of Carcinogenicity:NTP:YES IARC:YES OSHA:NO Health Hazards Acute and Chronic:INHALATION: CHRONIC-MAY AFFECT BREATHING CAPACITY. SKIN/EYES: IRRITATION. Explanation of Carcinogenicity:SEE INGREDIENTS Effects of Overexposure:COUGH, IRRITATION. Medical Cond Aggravated by Exposure:PRE-EXISTING RESPIRATORY CONDITIONS. ======================= First Aid Measures ======================= First Aid:INHALATION: REMOVE TO FRESH AIR. GIVE CPR IF NEEDED. SKIN: WASH W/SOAP & WATER. EYES: WASH W/WATER. OBTAIN MEDICAL ATTENTION IN ALL CASES. ===================== Fire Fighting Measures ===================== Extinguishing Media:WATER Fire Fighting Procedures:NONE ================== Accidental Release Measures ================== Spill Release Procedures:NORMAL CLEANUP PROCEDURES. ======================Handling and Storage ====================== Handling and Storage Precautions:HANDLE W/ADEQUATE VENTILATION. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:AS NEEDED FOR APPROVED DUST RESPIRATORS. Ventilation:LOCAL EXHAUST, MECHANICAL: RECOMMENDED. Other Protective Equipment:AS NEEDED HEARING PROTECTION. Supplemental Safety and Health ================== Physical/Chemical Properties ================== Melt/Freeze Pt:M.P/F.P Text:>428F Spec Gravity:2-4 Solubility in Water:SLIGHT Appearance and Odor:MAY GIVE OFF ODOR IN USE. ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES Hazardous Decomposition Products:IN USE DUST & DECOMPOSING ODORS ARE GENERATED. COOLANTS MAY PRODUCE OTHER DECOMPOSITION PRODUCTS. ==================== Disposal Considerations ==================== Waste Disposal Methods:DISPOSE OF IAW/FEDERAL, STATE & LOCAL REGULATIONS.
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:667884 WEST PATH SUPP 1 W/CAP SLGP CAGE:1W937 CAGE:1W937 ============= Composition/Information on Ingredients ============= Ingred Name:ETHYLENE GLYCOL, GLYCOL CAS:107-21-1 RTECS #:KW2975000 Fraction by Wt: <40% Other REC Limits:10 MG/CUM ACGIH TLV:C 127 MG/CUM EPA Rpt Qty:1 LB DOT Rpt Qty:1 LB Ingred Name:HUMAN PROTEIN Fraction by Wt: <10% ===================== Hazards Identification ===================== LD50 LC50 Mixture:LD50 ORAL RAT: 8.54 G/KG ETHYLENE GLYCOL Routes of Entry: Inhalation:YES Skin:NO Ingestion:YES Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:INHALATION: ETHYLENE GLYCOL MAY CAUSE IRRITATION OF MUCOUS MEMBRANES & RESPIRATORY PASSAGES. INGESTION: ETHYLENE GLYCOL MAY CAUSE INTOXICATION & COMA. SKIN: ETHYLENE GLYCOL MAY CAUSE IRRITATION. HUMANPROTEIN SOURCES ARE CAPABLE OF TRANSMITTING INFECTIOUS DISEASE. Explanation of Carcinogenicity:NONE ======================= First Aid Measures ======================= First Aid:SKIN: WASH AFFECTED AREAS THOROUGHLY. INGESTION, EYES OR CONTACT W/OPEN WOUND. OBTAIN MEDICAL ATTENTION IN ALL CASES. ================== Accidental Release Measures ================== Spill Release Procedures:HANDLE AS IF CAPABLE OF TRANSMITTING INFECTIOUS DISEASE. ABSORB ON INERT MATERIAL. ======================Handling and Storage ====================== Handling and Storage Precautions:HEAT WILL DEGRADE EFFICACY. HANDLE AS IF CAPABLE OF TRANSMITTING INFECTIOUS DISEASE. Other Precautions:STORE AS INDICATED ON DIRECTION INSERT. FOR IN VITRO DIAGNOSTIC USE ONLY. NOT FOR HUMAN OR ANIMAL USE. HANDLE BROKEN OR ============= Exposure Controls/Personal Protection ============= Respiratory Protection:AS REQUIRED Ventilation:GENERAL IS ACCEPTABLE Other Protective Equipment:EYE BATH Supplemental Safety and Health ================== Physical/Chemical Properties ================== Boiling Pt:B.P. Text:>100C Vapor Pres:18 Vapor Density:0.6 Spec Gravity:>1 Evaporation Rate & Reference:(WATER = 1): <1 Solubility in Water:COMPLETE Appearance and Odor:AMBER VISCOUS LIQUID, W/SLIGHT ODOR Percent Volatiles by Volume:>75% ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES STRONG OXIDIZERS Stability Condition to Avoid:HEAT ==================== Disposal Considerations ==================== Waste Disposal Methods:DISPOSE AS NECESSARY FOR BIOHAZARDOUS MATERIALS. DISPOSE OF IN ACCORDANCE W/APPLICABLE FEDERAL, STATE, & LOCAL LAWS & REGULATIONS.
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:S-495 SODIUM CARBONATE HPLC GRADE CAGE:1B464 CAGE:1B464 ============= Composition/Information on Ingredients ============= Ingred Name:SODIUM CARBONATE (SODA ASH, TRONA, CARBONIC ACID, CRYSTOL CARBONATE, DISODIUM CARBONATE) CAS:497-19-8 RTECS #:VZ4050000 Fraction by Wt: 100% ===================== Hazards Identification ===================== LD50 LC50 Mixture:ORAL LD50 (RAT): 4090 MG/KG Routes of Entry: Inhalation:YES Skin:NO Ingestion:YES Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:INHALATION: TOXIC/MUCOUS MEMBRANE IRRITATION/COUGH/BREATH SHORTNESS/GASTROINTESTINAL CHANGE. SKIN: IRRITATION/RED/ERYTHEMA/BLISTER/NECROSIS. EYE: IRRITATION/RED/PAIN/BLURRY VISION/TEMPORARY CORNEAL EP ITHELIUM DAMAGE/NECROSIS. INGESTION: GASTRIC MUCOSA CORROSION/SORE THROAT/NAUSEA/VOMIT/ABDOMINAL PAIN/TOXIC/DIARRHEA. Explanation of Carcinogenicity:NONE Effects of Overexposure:INHALATION: PERFORATION OF THE NASAL SEPTUM. SKIN: DERMATITIS & POSSIBLE SODA ULCERS OF THE HANDS & WRISTS, SENSITIVITY. EYES: IRRITATION, REDNESS, PAIN, BLURRED VISION, TEMPORARY DAMAGE OF CORNEAL EP ITHELIUM, NECROSIS. INGESTION: DEATH ISGENERALLY DUE TO CIRCULATORY COLLAPSE. LETHAL HUMAN DOSE: 30 GRAMS. ======================= First Aid Measures ======================= First Aid:INHALATION: REMOVE TO FRESH AIR. GIVE CPR. KEEP WARM/QUIET. SKIN: WASH W/SOAP/MILD DETERGENT/WATER FOR 15-20 MIN. EYE: FLUSH W/WATER FOR 15-20 MIN. USE NORMAL SALINE FOR 30-60 MIN. COVER W/STERILE BAN DAGE. INGESTION: DILUTE W/WATER/MILK. AVOID GASTRIC LAVAGE/EMETIC. USE ESOPHAGOSCOPY TO AVOID CORROSION. TREAT SHOCK. KEEP HEAD BELOW HIPS TO PREVENT ASPIRATION. OBTAIN MEDICAL ATTENTION IN ALL CASES. ===================== Fire Fighting Measures ===================== Extinguishing Media:DRY CHEMICAL/CO2/WATER SPRAY/REGULAR FOAM. FOR LARGE FIRES USE WATER SPRAY/FOG/REGULAR FOAM. Fire Fighting Procedures:MOVE CONTAINER FROM FIRE AREA IF POSSIBLE. AVOID BREATHING VAPORS OR DUSTS. KEEP UPWIND. WEAR SELF-CONTAINED BREATHING APPARATUS W/FULL FACEPIECE. Unusual Fire/Explosion Hazard:NEGLIGIBLE FIRE HAZARD WHEN EXPOSED TO HEAT OR FLAME. ================== Accidental Release Measures ================== Spill Release Procedures:SWEEP UP & PLACE IN SUITABLE (FIBERBOARD) CONTAINERS FOR RECLAMATION OR LATER DISPOSAL. ======================Handling and Storage ====================== Handling and Storage Precautions:STORE AWAY FROM INCOMPATIBLE SUBSTANCES. Other Precautions:AVOID CONTACT W/EYES & SKIN. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:DUST/MIST/AIR-PURIFYING FULL FACEPIECE/POWERED AIR-PURIFYING/TYPE C SUPPLIED-AIR/SCBA W/HIGH EFFICIENCY PARTICULATE FILTER/TIGHT-FITTING FACEPIECE & HIGH EFFICIENCY PARTICULATE FILTER/HELMET/HOOD OPER ATED IN POSITIVE PRESSURE MODE. Ventilation:LOCAL EXHAUST OR GENERAL DILUTION VENTILATION SYSTEM Other Protective Equipment:EYE WASH FOUNTAIN, QUICK DRENCH SHOWER, IMPERVIOUS CLOTHING & EQUIPMENT Work Hygienic Practices:REMOVE/LAUNDER CONTAMINATED CLOTHING & SHOES BEFORE REUSE. Supplemental Safety and Health NOTE TO PHYSICIAN: NO SPECIFIC ANTIDOTE. TREAT SYMPTOMATICALLY & SUPPORTIVELY. ================== Physical/Chemical Properties ================== Boiling Pt:B.P. Text:DECOMPOSES Melt/Freeze Pt:M.P/F.P Text:1564F/851C Spec Gravity:2.536 pH:11.5 Solubility in Water:7.1% Appearance and Odor:ODORLESS/COLORLESS TO WHITE/HYGROSCOPIC SMALL CRYSTALLINE POWDER/GRANULES ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES WATER, ACIDS, METALS Stability Condition to Avoid:HEAT, FLAME Hazardous Decomposition Products:TOXIC SODIUM OXIDE & TOXIC CO & CO2 ==================== Disposal Considerations ==================== Waste Disposal Methods:DISPOSE OF IN ACCORDANCE W/LOCAL, STATE, & FEDERAL REGULATIONS.
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:WAY LUBRICANT HM, 0193 CAGE:18056 CAGE:18056 ============= Composition/Information on Ingredients ============= Ingred Name:SOLVENT REFINED PARAFFINIC OIL CAS:72623-86-0 Fraction by Wt: 93.0% OSHA PEL:5 MG/M3(MFR) ACGIH TLV:5 MG/M3(MFR) Ingred Name:SULFURIZED FATTY MATERIAL;(SULFURIZED FATTY OIL) CAS:61790-49-6 Fraction by Wt: 6.0% OSHA PEL:N/K ACGIH TLV:N/K Ingred Name:PROPENE, 2-METHYL-, POLYMERS; (POLYISOBUTYLENE) CAS:9003-27-4 RTECS #:UD1010000 Fraction by Wt: 1.0% OSHA PEL:N/K ACGIH TLV:N/K ===================== Hazards Identification ===================== LD50 LC50 Mixture:NONE SPECIFIED BY MANUFACTURER. Routes of Entry: Inhalation:YES Skin:NO Ingestion:YES Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:INHAL: BREATHING DIFFICULTY. EYE: MINOR IRRITATION. SKIN: DEFATTING &/MINOR IRRITATION. INGEST: NAUSEA &/DIARRHEA. Explanation of Carcinogenicity:NOT RELEVANT. Effects of Overexposure:SEE HEALTH HAZARDS. Medical Cond Aggravated by Exposure:NONE SPECIFIED BY MANUFACTURER. ======================= First Aid Measures ======================= First Aid:INHAL: REMOVE PERSON TO FRESH AIR. IF NECESSARY, SUPPORT BREATHING. GET MED ATTN. EYE: FLUSH W/WATER FOR AT LEAST 15 MINUTES. IF IRRIT PERSISTS, GET MED ATTN. SKIN: WASH EXPOSED AREA W/MILD SOAP & WAR M WATER ONLY. DO NOT USE HARSH SOAP OR SOLVENT. GET MED ATTN. INGEST: KEEP PERSON WARM & QUIET. GET MED ATTN. ===================== Fire Fighting Measures ===================== Flash Point Method:COC Flash Point:400F,204C Extinguishing Media:CARBON DIOXIDE, FOAM OR DRY CHEMICAL. Fire Fighting Procedures:WEAR NIOSH/MSHA APPRVD SCBA & FULL PROT EQUIP. WATER STREAM/SPRAY, TO COOL CNTNRS TO PVNT VAPOR FORMATION & IGNIT, MAY SPREAD FIRE. FOG NOZZ(SUPDAT) Unusual Fire/Explosion Hazard:NONE SPECIFIED BY MANUFACTURER. ================== Accidental Release Measures ================== Spill Release Procedures:SMALL SPILLS: USE ABSORBENT MATERIAL. LGE SPILLS: DIKE & PUMP INTO DRUMS. RESIDUE: MOP W/SOAP & WATER. Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER. ======================Handling and Storage ====================== Handling and Storage Precautions:STORE DRY IN A CLOSED CONTAINER IN A COOL PLACE AWAY FROM ANY FIRE SOURCE. Other Precautions:AVOID BREATHING MIST. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:USE NIOSH/MSHA APPROVED RESPIRATOR APPROPRIATE FOR EXPOSURE OF CONCERN. Ventilation:GENERAL MECHANICAL VENT SHOULD BE ADEQUATE. IF MISTING OCCURS, PROVIDE LOCAL VENTILATION. Other Protective Equipment:EMER SHOWER & EYEWASH SHOULD BE AVAIL IN WORK AREA. Work Hygienic Practices:PRACTICE REASONABLE PERS HYGIENE. WASH EXPOSED SKIN W/MILD SOAP & WARM WATER ONLY. OIL-SOAKED CLTHG SHOULD BE (SUPDAT) Supplemental Safety and Health FIRE FIGHT PROC: ARE PREFERRED IF WATER IS USED. HYGIENE PRAC: BE CHANGED PROMPTLY & LAUNDERED BEFORE RE-WEARING. ================== Physical/Chemical Properties ================== Vapor Density:>1 Spec Gravity:0.890(H*2O=1) Solubility in Water:INSOLUBLE Appearance and Odor:DARK BROWN LIQUID W/OILY ODOR. ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES STRONG OXIDIZERS. Stability Condition to Avoid:NONE SPECIFIED BY MANUFACTURER. Hazardous Decomposition Products:OXIDES OF CARBON & SULFUR COMPOUNDS. ==================== Disposal Considerations ==================== Waste Disposal Methods:TREAT AS AN OILY WASTE & DISPOSE OF IN ACCORDANCE WITH LOCAL, STATE & FEDERAL REGULATIONS.
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:THIOKOL MC-236 BASE TYPE II Kit Part:Y Preparer's Name:DAVID B.WIENCKOWSKI,DABT CAGE:KO006 CAGE:KO006 CAGE:0U317 ============= Composition/Information on Ingredients ============= Ingred Name:CALCIUM CARBONATE CAS:471-34-1 RTECS #:FF9335000 Fraction by Wt: 40.2% Other REC Limits:NONE RECOMMENDED Ingred Name:TITANIUM DIOXIDE CAS:13463-67-7 RTECS #:XR2275000 Fraction by Wt: 2.5% Other REC Limits:NONE RECOMMENDED OSHA PEL:15 MG/M3 TDUST ACGIH TLV:10 MG/M3 TDUST; 9495 Ingred Name:SILICA, CRYSTALLINE - QUARTZ CAS:14808-60-7 RTECS #:VV7330000 Fraction by Wt: 0.36% Other REC Limits:NONE RECOMMENDED OSHA PEL:SEE TABLE Z-3 ACGIH TLV:0.1 MG/M3 RDUST;9495 Ingred Name:NON-HAZARDOUS INGREDIENTS Fraction by Wt: 55% Other REC Limits:NONE RECOMMENDED Ingred Name:FORMALDEHYDE (SARA 302/313) (CERCLA) CAS:50-00-0 RTECS #:LP8925000 Fraction by Wt: <0.1% Other REC Limits:NONE RECOMMENDED OSHA PEL:SEE 1910.1048 ACGIH TLV:C 0.3 PPM, A2; 9495 EPA Rpt Qty:100 LBS DOT Rpt Qty:100 LBS Ingred Name:ETHYLENE OXIDE (SARA 302/313) (CERCLA) CAS:75-21-8 RTECS #:KX2450000 Other REC Limits:NONE RECOMMENDED OSHA PEL:1 PPM; SEE 1910.1047 ACGIH TLV:1 PPM, A2; 9495 EPA Rpt Qty:10 LBS DOT Rpt Qty:10 LBS ===================== Hazards Identification ===================== Health Hazards Acute and Chronic:EYES:MAY CAUSE MECHANICAL IRRITATION.SKIN:PROLONGED CONTACT MAY CAUSE IRRITATION.INGEST:MAY CAUSE GI TRACT IRRITATION.INHAL:NO ADVERSE EFFECTS EXPECTED.CHRONIC:MAY CAUSE ALLERGIC REACTION.EXPOSURE TO CRYSTALLINE SILICA DUST MAY CAUSE SILICOSIS. Explanation of Carcinogenicity:CRYSTALLINE SILICA:NTP-AC,IARC-2A.ETHYLENE OXIDE:NTP-AC,IARC-2A,EPA-B2.FORMALDEHYDE IS LOWER THAN REPORTABLE AMOUNT. Effects of Overexposure:INGEST:NAUSEA,VOMITING AND GASTROINTESTINAL UPSET.SILICOSIS:COUGHING,WHEEZING,CHEST PAIN. Medical Cond Aggravated by Exposure:UNLIKELY TO AGGRIVATE EXISTING MEDICAL CONDITIONS UNDER NORMAL CONDITIONS OF USE. ======================= First Aid Measures ======================= First Aid:SKIN:REMOVE CONTAMINATED CLOTHING;WASH WITH SOAP AND WATER.SEE DOCTOR IF IRRITATION DEVELOPS.EYES:FLUSH WITH WATER FOR 15 MINUTES.SEE DOCTOR IF IRRITATION DEVELOPS.INHAL:REMOVE TO FRESH AIR.GIVE OXYGE N OR ARTIFICIAL RESPIRATION IF NEEDED.INGEST:GET PROMPT QUALIFIED MEDICAL ATTENTION.INDUCE VOMITING WITH SYRUP OF IPECAC,FOLLOWED BY 2 GLASSES WATER OR STICK FINGER DOWN THROAT. ===================== Fire Fighting Measures ===================== Flash Point Method:SCC Flash Point:>200F,>93C Extinguishing Media:USE AGENTS APPROVED FOR CLASS A HAZARD(HALOGENATED AGENTS,FOAM,STEAM,WATER FOG). Fire Fighting Procedures:USE A SELF-CONTAINED BREATHING APPARATUS AND FULL PROTECTIVE EQUIPMENT. Unusual Fire/Explosion Hazard:FIRE CONDITIONS MAY EVOLVE TOXIC FUMES. ================== Accidental Release Measures ================== Spill Release Procedures:SHOVEL OR VACUUM;PLACE COLLECTED MATERIAL IN AN APPROPRIATE CONTAINER FOR DISPOSAL;CLEAN SPILL AREA TO REMOVE SLIPPERINESS.DO NOT POLLUTE SEWERS,STREAMS OR WATERWAYS. Neutralizing Agent:NOT APPLICABLE. ======================Handling and Storage ====================== Handling and Storage Precautions:STORE IN A COOL,DRY,WELL-VENTILATED PLACE.KEEP CONTAINER CLOSED WHEN NOT IN USE. Other Precautions:THIS PRODUCT CONTAINS FORMALDEHYDE,WHICH MAY ACCUMULATE IN THE HEADSPACE OF SEALED CONTAINERS;USE PROPER RESPIRATORY PROTECTIVE EQUIPMENT.EMPTY CONTAINERS MAY CONTAIN HAZARDOUS RESIDUE;DISPOSE OF PROP ERLY. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:WHERE ENVIRONMENTAL CONTROLS ARE LACKING OR IN ENCLOSED SPACES USE A SELF-CONTAINED BREATHING APPARATUS.IF THE PEL FOR FORMALDEHYDE(2PPM-STEL) IS EXCEEDED USE A NIOSH/MSHA APPROVED RESPIRATOR FOR FORM ALDEHYDE. Ventilation:LOCAL VENTILATION AT THE WORKSITE;MECHANICAL(GENERAL) VENTILATION TO MAINTAIN TLV/PEL. Other Protective Equipment:PROVIDE A LOCAL EYE WASH STATION AND SAFETY SHOWER. Work Hygienic Practices:USE GOOD MANUFACTURING AND HANDLING PRACTICES.WASH AFTER HANDLING PRODUCT AND BEFORE EATING,DRINKING OR SMOKING. Supplemental Safety and Health KEY1:N1. ================== Physical/Chemical Properties ================== HCC:N1 Spec Gravity:1.61 Viscosity:9000-14000P Solubility in Water:INSOLUBLE Appearance and Odor:NOT REPORTED. Percent Volatiles by Volume:97 ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES NONE SPECIFIED BY MANUFACTURER. Stability Condition to Avoid:NONE SPECIFIED BY MANUFACTURER. Hazardous Decomposition Products:CARBON DIOXIDE,CARBON MONOXIDE,OXIDES OF NITROGEN AND SULFUR,PHENOLICS,HYDROGEN SULFIDE. ==================== Disposal Considerations ==================== Waste Disposal Methods:RECYCLE,INCINERATE OR SURRENDER TO A WASTE TREATMENT FACILITY IN ACCORDANCE WITH FEDERAL,STATE AND LOCAL REGULATIONS.
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:SSR ULTRA COOLANT CAGE:6K358 CAGE:6K358 ============= Composition/Information on Ingredients ============= Ingred Name:POLYOXYALKYLENE GLYCOL Other REC Limits:NONE SPECIFIED Ingred Name:PENTAERYTHRITOL ESTER Other REC Limits:NONE SPECIFIED ===================== Hazards Identification ===================== LD50 LC50 Mixture:ORAL RAT LD50 IS >4000 MG/KG Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:THIS PRODUCT IS ESSENTIALLY NON-IRRITATING AND OF LOW TOXICITY. NO IRRITATION IS EXPECTED UNLESS THE PRODUCT IS MISTED OR HIGH TEMPERATURES CREATE IRRITATING VAPORS. CHRONIC INGESTION MAY CAUSE DAMA GE TO THE LIVER AND/OR KIDNEYS Explanation of Carcinogenicity:THE PRODUCT CONTAINS NO INGREDIENT THAT IS LISTED BY IARC, NTP OR OSHA AS A CARCINOGEN. Effects of Overexposure:EYES:NONE SKIN:NONE INHALED:(MIST OR VAPORS) RESPIRATORY IRRITATION INGESTED: LOW SINGLE DOSE TOXICITY. CHRONIC INGESTION MAY DAMAGE THE LIVER AND/OR KIDNEYS. Medical Cond Aggravated by Exposure:NO INFORMATION GIVEN ON MSDS BY SUPPLIER ======================= First Aid Measures ======================= First Aid:ONLY ONE PAGE OF MSDS AVAILABLE. THIS INFORMATION NOT INCLUDED ON IT. ===================== Fire Fighting Measures ===================== Flash Point Method:PMCC Flash Point:540F,282C Extinguishing Media:USE WATER FOG,FOAM,ALCOHOL RESISTANT FOAM, DRY CHEMICAL, CARBON DIOXIDE Fire Fighting Procedures:FIRE FIGHTERS SHOULD USE NIOSH APPROVED SCBA & FULL PROTECTIVE EQUIPMENT WHEN FIGHTING CHEMICAL FIRE. USE WATER SPRAY TO COOL NEARBY CONTAINERS EXPOSED TO FIRE. Unusual Fire/Explosion Hazard:NONE KNOWN ================== Accidental Release Measures ================== Spill Release Procedures:ONLY ONE PAGE OF MSDS AVAILABLE. THIS INFORMATION NOT INCLUDED ON IT. Neutralizing Agent:ONLY ONE PAGE OF MSDS AVAILABLE. THIS INFORMATION NOT INCLUDED ON IT. ======================Handling and Storage ====================== Handling and Storage Precautions:ONLY ONE PAGE OF MSDS AVAILABLE. THIS INFORMATION NOT INCLUDED ON IT. Other Precautions:ONLY ONE PAGE OF MSDS AVAILABLE. THIS INFORMATION NOT INCLUDED ON IT. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:ONLY ONE PAGE OF MSDS AVAILABLE. THIS INFORMATION NOT INCLUDED ON IT. Ventilation:ONLY ONE PAGE OF MSDS AVAILABLE. THIS INFORMATION NOT INCLUDED ON IT. Other Protective Equipment:ONLY ONE PAGE OF MSDS AVAILABLE. THIS INFORMATION NOT INCLUDED ON IT. Work Hygienic Practices:ONLY ONE PAGE OF MSDS AVAILABLE. THIS INFORMATION NOT INCLUDED ON IT. Supplemental Safety and Health NONE ================== Physical/Chemical Properties ================== HCC:V6 Vapor Pres:<0.01 MM Spec Gravity:0.9901 pH:UNKNON Solubility in Water:<1 GM/100 ML Appearance and Odor:LIGHT AMBER LIQUID,LOW ODOR ================= Stability and Reactivity Data ================= ONLY ONE PAGE OF MSDS AVAILABLE. THIS INFORMATION NOT INCLUDED ON IT. Stability Condition to Avoid:ONLY ONE PAGE OF MSDS AVAILABLE. THIS INFORMATION NOT INCLUDED ON IT. Hazardous Decomposition Products:ONLY ONE PAGE OF MSDS AVAILABLE. THIS INFORMATION NOT INCLUDED ON IT. Conditions to Avoid Polymerization:ONLY ONE PAGE OF MSDS AVAILABLE. THIS INFORMATION NOT INCLUDED ON IT. ==================== Disposal Considerations ==================== Waste Disposal Methods:ONLY ONE PAGE OF MSDS AVAILABLE. THIS INFORMATION NOT INCLUDED ON IT.
0
eyes_protection_not_mandatory
===================== Product Identification ===================== Product ID:NATURE-SOL 100 CAGE:94058 CAGE:94058 ============= Composition/Information on Ingredients ============= Ingred Name:DIPROPYLENE GLYCOL METHYL ETHER CAS:34590-94-8 RTECS #:JM1575000 Fraction by Wt: 1-5% Other REC Limits:NONE RECOMMENDED OSHA PEL:S,100PPM ACGIH TLV:S,100PPM/150STEL; 94 Ingred Name:D-LIMONENE CAS:5989-27-5 RTECS #:GW6360000 Fraction by Wt: 70-90% Other REC Limits:NONE RECOMMENDED ===================== Hazards Identification ===================== Routes of Entry: Inhalation:YES Skin:YES Ingestion:NO Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:EYE:DIRECT CONTACT MAY CAUSE IRRIT. INGEST: MAY CAUSE GASTROINTESTINAL IRRIT. INHAL:EXCESSVIE EXPOSURE MAY CAUSE NASAL & RESPIRATORY IRRIT. SKIN:PROLONGED/REPEATED CONTACT MAY CAUSE IRRIT. Explanation of Carcinogenicity:PER MSDS:CARCINOGENICITY:NTP/IARC/OSHA:NO. Effects of Overexposure:EYE:REDNESS, TEARAING. SKIN:SLIGHT REDNESS. INHAL:SDROWSINESS, LIGHTHEADEDNESS, WEAKNESS, HEADACHE. Medical Cond Aggravated by Exposure:NONE KNOWN. ======================= First Aid Measures ======================= First Aid:EYE:FLUSH W/LARGE AMTS OF WATER FOR 15MINS LIFTING UPPER/LOWER LIDS OCCASIONALLY. INHAL:REMOVE TO FRESH AIR. ADMINISTER OXYGEN IF BREATHING IS DIFFICULT. SKIN:WASH W/MILD SOAP & WATER. REMOE CONTAMIN CLOTHING. INGEST:IF CONSC DILUTE BY GIVING 2 GLASSES OF WATER. KEEP WARM, QUIET AND CALL PHYSICIAN OR LOCAL POISON CONTROL CENTER IMMED. ===================== Fire Fighting Measures ===================== Flash Point Method:PMCC Flash Point:120F,49C Extinguishing Media:WATER FOG, ALCOHOL FOAM, CARBON DIOXIDE, DRY CHEMICAL. Fire Fighting Procedures:USE SELF-CONTAINED BREATHING APPARATUS. WATER FOG MAY BE USED TO COOL CLOSED CONTAINERS. Unusual Fire/Explosion Hazard:NEVER USE WELDING OR CUTTING TORCH ON OR NEAR DRUM EVEN EMPTY. ================== Accidental Release Measures ================== Spill Release Procedures:REMOVE ALL SOURCES OF IGNITION. VENTILATE AREA WEEL. ABSORB ON SOLID ABSORBENT & SHOVEL INTO CONTAINER FOR DISPOSAL. ======================Handling and Storage ====================== Handling and Storage Precautions:STORE BETWEEN 40 AND 120F. Other Precautions:NONE SPECIFIED BY MANUFACTURER. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:IF TLV IS EXCEEDED USE NIOSH/MSHA APPROVED RESPIRATOR. CONTACT YOUR LOCAL SAFETY EQUIPMENT SUPPLIER FOR RECOMMENDATIONS. Ventilation:PROVIDE SUFFICIENT MECHANICAL (GENERAL &/OR LOCAL EXHAUST) VENTILATION TO MAINTAIN EXPOSURE BELOW TLV. Other Protective Equipment:NONE. Work Hygienic Practices:AVOID BREATHING SPRAY MIST. WASH HANDS AFTER HANDLING. LAUNDER CONTAMIN CLOTHING PRIOR TO REUSE. Supplemental Safety and Health VAP PRESS:DPM 0.55 @77F, VAP DEN:DPM 5.15. ================== Physical/Chemical Properties ================== HCC:F4 NRC/State Lic Num:NONE Boiling Pt:B.P. Text:347F,175C Melt/Freeze Pt:M.P/F.P Text:<0F,<-18C Vapor Pres:SUPPLEMENT Vapor Density:SUPLEMENT Spec Gravity:0.807 Evaporation Rate & Reference:1.0, WATER=1 Solubility in Water:APPRECIABLE Appearance and Odor:CLEAR YELLOWISH LIQUID, MILD CITRUS ODOR. ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES STRONG OXIDIZERS. Stability Condition to Avoid:AVOID HEAT, SPARKS, OPEN FLAMES. Hazardous Decomposition Products:UPON THERMAL DECOMPOSITION CAN PRODUCT CARBON MONOXIDE AND CARBON DIOXIDE. ==================== Disposal Considerations ==================== Waste Disposal Methods:DISPOSE ACCORDING TO LOCAL, STATE AND FEDERAL LAWS & 40 CFR.
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:B/N MATRIX SPIKE MIX, 31174 CAGE:0JL17 CAGE:0JL17 ============= Composition/Information on Ingredients ============= Ingred Name:METHYL ALCOHOL (METHANOL) (SARA 313) (CERCLA) CAS:67-56-1 RTECS #:PC1400000 Fraction by Wt: 79.0% OSHA PEL:S, 200 PPM ACGIH TLV:S,200PPM/250STEL EPA Rpt Qty:5000 LBS DOT Rpt Qty:5000 LBS Ingred Name:ACENAPHTHENE (CERCLA) CAS:83-32-9 RTECS #:AB1000000 Fraction by Wt: 0.5% OSHA PEL:N/K ACGIH TLV:N/K EPA Rpt Qty:100 LBS DOT Rpt Qty:100 LBS Ingred Name:PYRENE (SARA 302) (CERCLA) CAS:129-00-0 RTECS #:UR2450000 Fraction by Wt: 0.5% OSHA PEL:N/K ACGIH TLV:N/K EPA Rpt Qty:5000 LBS DOT Rpt Qty:5000 LBS Ingred Name:BENZENE, P-DICHLORO-; (1,4-DICHLOROBENZENE) (SARA 313) (CERCLA) CAS:106-46-7 RTECS #:CZ4550000 Fraction by Wt: 0.5% OSHA PEL:75 PPM ACGIH TLV:10 PPM EPA Rpt Qty:100 LBS DOT Rpt Qty:100 LBS Ingred Name:BENZENE, 1,2,4-TRICHLORO-; (1,2,4-TRICHLOROBENZENE) (SARA 313) (CERCLA) CAS:120-82-1 RTECS #:DC2100000 Fraction by Wt: 0.5% OSHA PEL:C, 5 PPM ACGIH TLV:C, 5 PPM EPA Rpt Qty:100 LBS DOT Rpt Qty:100 LBS Ingred Name:TOLUENE, 2,4-DINITRO-; (2,4-DINITROTOLUENE) (SARA 313) (CERCLA) CAS:121-14-2 RTECS #:XT1575000 Fraction by Wt: 0.5% OSHA PEL:S, 1.5 MG/M3 ACGIH TLV:0.15 MG/M3 EPA Rpt Qty:10 LBS DOT Rpt Qty:10 LBS Ingred Name:DIPROPYLAMINE, N-NITROSO-; (N-NITROSO-DI-N-PROPYLAMINE) (SARA 313) (CERCLA) CAS:621-64-7 RTECS #:JL9700000 Fraction by Wt: 0.5% OSHA PEL:N/K ACGIH TLV:N/K EPA Rpt Qty:10 LBS DOT Rpt Qty:10 LBS ===================== Hazards Identification ===================== LD50 LC50 Mixture:NONE SPECIFIED BY MANUFACTURER. Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES Reports of Carcinogenicity:NTP:YES IARC:YES OSHA:NO Health Hazards Acute and Chronic:ACUTE:IRRITANT, HEADACHE, FATIGUE, DILATED PUPILS, VISUAL DISTURBANCES, BLINDNESS, SHALLOW RESPIRATION, RESPIRATORY FAILURE, CYANOSIS, CONVULSIONS, COMA, HYPOTENSION, DEATH, SIGNS/SYMPS:NAUS, DROWS, I NTOX, SEV DEPRESS, HDCH, VISUAL DISTURBS LEADING TO BLNDNESS, COUGHING, SHORTNESS OF BRTH; BURNING, (EFTS OF OVEREXP) Explanation of Carcinogenicity:P-DICHLOROBENZENE:IARC MONOGRAPHS, SUPP, VOL 7, PG 192, 1987:GROUP 2B. NTP 7TH ANNUAL RPT ON CARCINS, 1994:(SUPP DATA) Effects of Overexposure:HLTH HAZS:ITCHING, REDNESS/BLISTERS ON SKIN; BURNING, WATERING, SWELLING AND REDNESS IN EYES. CHRONIC:POSITIVE MUTAGEN (RTECS); GASTRO-INTESTINAL, LIVER, KIDNEY AND CARDIOVASCULAR SYSTEM INJURY, VISUA L IMPAIRMENT, DERMATITIS. Medical Cond Aggravated by Exposure:DERMATITIS, DISEASES OF EYES, LIVER, KIDNEYS, LUNGS AND CARDIOVASCULAR. ======================= First Aid Measures ======================= First Aid:EYES:REMOVE CONT LENSES IF PRESENT. HOLD EYELIDS OPEN & IRRITATE W/LG VOL OF WATER FOR @ LST 15 MIN. SEEK MED TREATMENT. SKIN:IMMED WASH W/SOAP & WATER. CONTINUE RINSING W/LG VOL OF WATER FOR 15 MIN. REMOVE CONTAM CLTHG. INHAL:REMOVE TO FRESH AIR. HAVE TRAINED PERSON ADMIN OXYG & CPR IF NEEDED. SEEK MED TREATMENT. INGEST:MAY CAUSE BLNDNESS. DRINK LG VOL OF WATER THEN INDUCE VOMIT. DO NOT (SUPDAT) ===================== Fire Fighting Measures ===================== Flash Point:51.8F,11.0C Lower Limits:6.7% Upper Limits:36.5% Extinguishing Media:DRY CHEMCIAL, CO*2, HALON, ALCOHOL FOAM, WATER MIST OR FOG. Fire Fighting Procedures:WEAR NIOSH/MSHA APPROVED SCBA & FULL PROTECTIVE EQUIPMENT . HEAT MAY BUILD PRESS & RUPTURE CLSD STOR CNTNRS. KEEP FIRE-EXPOSED CNTNRS COOL W/WATER SPRAY. Unusual Fire/Explosion Hazard:MAY FORM EXPLOSIVE VAPOR/AIR MIXTURES. INCOMPLETE COMBUSTION MAY GENERATE TOXIC VAPORS. ================== Accidental Release Measures ================== Spill Release Procedures:WEAR PERSONAL PROTECTIVE EQUIPMENT. ABSORB SMALL SPILLS ON PAPER, VERMICULITE, OR OTHER ABSORBENT. COLLECT AND STORE IN CLOSED CONTAINER FOR DISPOSAL. Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER. ======================Handling and Storage ====================== Handling and Storage Precautions:AVOID ALL INHALATION AND CONTACT. KEEP IN A TIGHTLY CLOSED CONTAINER AT ALL TIMES. HANDLE WITH UTMOST CARE, STORE IN AN EXPLO PROOF REFRIGERATOR @ 4C. Other Precautions:NOT APPLICABLE. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:NIOSH/MSHA APPROVED RESPIRATOR WITH ORGANIC VAPOR CARTRIDGE. Ventilation:USE IN AN AREA PROVIDED WITH GENERAL AND LOCAL EXHAUST VENTILATION MEETING OSHA REQUIREMENTS. Other Protective Equipment:ANSI APPROVED EMERGENCY EYE WASH AND DELUGE SHOWER . PROTECTIVE CLOTHING MEETING LABORATORY SAFETY REQUIREMENTS. Work Hygienic Practices:NONE SPECIFIED BY MANUFACTURER. Supplemental Safety and Health FIRST AID PROC:ATTEMPT TO GIVE FLUIDS OR INDUCE VOMITING IF PERSON IS UNCONSCIOUS. CONTACT POISON CONTROL CENTER. EXPLAN OF CARCIN:ANTIC TO BE CARCIN. N-NITROSODIPROPYLAMINE:IARC MONOGRAPHS, SUPP, VOL 7, PG 56, 1987:GROUP 2B. NTP 7TH ANNUAL RPT ON CARCIN, 1994:ANTIC TO BE CARCIN. ANIMAL:LIVER, G.I ================== Physical/Chemical Properties ================== Boiling Pt:B.P. Text:149F,65C Vapor Pres:97 @ 20C Spec Gravity:0.791 Solubility in Water:MISCIBLE Appearance and Odor:COLORLESS/ALCOHOL ODOR. ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES OXIDIZERS, REDUCING AGENTS, REACTIVE METALS. Stability Condition to Avoid:HEAT, CONTACT WITH IGNITION SOURCE. Hazardous Decomposition Products:NONE SPECIFIED BY MANUFACTURER. ==================== Disposal Considerations ==================== Waste Disposal Methods:INCINERATE AT AN APPROVED FACILITY IN ACCORDANCE WITH FEDERAL, STATE AND LOCAL REGULATIONS.
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:26R444, VERSATEC CLEAR DISPERSANT FOR V-80, (SUPDAT) CAGE:0E6G9 CAGE:0E6G9 CAGE:26921 ============= Composition/Information on Ingredients ============= Ingred Name:NAPHTHOL SPIRITS; (ISOPARAFFINIC HYDROCARBON SOLVENT) CAS:64742-48-9 Fraction by Wt: 100% OSHA PEL:N/K ACGIH TLV:N/K ===================== Hazards Identification ===================== LD50 LC50 Mixture:LD50: (ORAL, RAT) >10 G/KG Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:HIGH VAPOR CONCENTRATIONS (>1000 PPM) ARE IRRITATING TO THE EYES AND RESPIRATORY TRACT AND MAY CAUSE HEADACHES, DIZZINESS, ANESTHESIA, DROWSINESS, UNCONSCIOUSNESS AND OTHER CENTRAL NERVOUS SYSTEM EFFE CTS, INCLUDING FATALITY. ADDITIONAL INFO: ISOPARAFFINIC HYDROCARBON SOLVENT HAS A LOW ORDER OF ACUTE (EFTS OF OVEREXP) Explanation of Carcinogenicity:NOT RELEVANT Effects of Overexposure:HLTH HAZ: ORAL AND DERMAL TOXICITY, BUT MINUTE AMOUNTS ASPIRATED INTO THE LUNGS DURING INGESTION OR VOMITING MAY CAUSE MILD TO SEVERE PULMONARY INJURY, INCLUDING FATALITY. Medical Cond Aggravated by Exposure:SKIN CONTACT MAY AGGRAVATE AN EXISTING DERMATITIS. ======================= First Aid Measures ======================= First Aid:EYES: FLUSH WITH WATER FOR AT LEAST 15 MINUTES. IF IRRITATION PERSISTS, CALL MD. SKIN: WASH WITH SOAP AND WATER. IF SKIN IS BROKEN, CALL MD. INHALATION: REMOVE FROM EXPOSURE. INGESTION: DO NOT INDUCEVOMITING. CALL MD IMMEDIATELY. ===================== Fire Fighting Measures ===================== Flash Point Method:TCC Flash Point:105F,41C Lower Limits:0.8% Upper Limits:7.0% Extinguishing Media:FOAM, DRY CHEMICAL, CARBON DIOXIDE, WATER FOG OR SPRAY. Fire Fighting Procedures:USE NIOSH APPROVED SCBA AND FULL PROTECTIVE EQUIPMENT . COOL EXPOSED CONTAINERS WITH WATER SPRAY. AVOID BREATHING VAPOR OR FUMES. Unusual Fire/Explosion Hazard:DO NOT MIX OR STORE WITH STRONG OXIDANTS LIKE LIQUID CHLORINE OR CONCENTRATED OXYGEN. ================== Accidental Release Measures ================== Spill Release Procedures:REMOVE IGNITION SOURCES. RECOVER FREE LIQUID, USING AN ABSORBENT MATERIAL (VERMICULITE, FIRE RETARDANT, SAWDUST, ETC). Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER. ======================Handling and Storage ====================== Handling and Storage Precautions:KEEP CONTAINERS CLOSED WHEN NOT IN USE. DO NOT HANDLE OR STORE NEAR HEAT, SPARKS, FLAME OR STRONG OXIDANTS. Other Precautions:ADEQUATE VENTILATION REQUIRED (EQUIVALENT TO OUTDOORS). ============= Exposure Controls/Personal Protection ============= Respiratory Protection:NONE REQUIRED WHEN USED AS INTENDED IN XEROX PRODUCTS. USE NIOSH APPROVED RESPIRATOR APPROPRIATE FOR EXPOSURE OF CONCERN . Ventilation:NONE SPECIFIED BY MANUFACTURER. Other Protective Equipment:ANSI APPRVD EYE WASH & DELUGE SHOWER . CHEM RESIST APRON/OTHER CLTHG IF NEEDED TO AVOID RPTD & PRLNGD SKIN CNTCT. Work Hygienic Practices:NONE SPECIFIED BY MANUFACTURER. Supplemental Safety and Health MFR'S TRADE NAME/PART NO: 8000 SERIES, 800, 900, 1100, 1200, 1600, 2000, 3000, 7000, 8500. ================== Physical/Chemical Properties ================== Boiling Pt:B.P. Text:>320F,>160C Vapor Pres:<10 @ 25C Vapor Density:5.0 Spec Gravity:0.77 (H*2O=1) VOC Pounds/Gallon:750 Evaporation Rate & Reference:0.3 (N-BUTYL ACETATE=1) Solubility in Water:NEGLIGIBLE Appearance and Odor:WATER WHITE LIQUID; MILD ODOR. ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES STRONG OXIDANTS LIKE LIQUID CHLORINE, CONCENTRATED OXYGEN, SODIUM OR CALCIUM HYPOCHLORITE. Stability Condition to Avoid:NONE SPECIFIED BY MANUFACTURER. Hazardous Decomposition Products:FUMES, SMOKE AND CARBON MONOXIDE IN THE CASE OF INCOMPLETE COMBUSTION. ==================== Disposal Considerations ==================== Waste Disposal Methods:THE RESIDUAL CLEAR DISPERSANT MAY BE CLASSIFIED AS AN IGNITABLE HAZARDOUS WASTE UNDER FEDERAL AND/OR STATE REGULATIONS AND SHOULD BE DISPOSED OF AT AN APPROVED DISPOSAL SITE OR FACILITY IN ACCORDANCE WITH FEDERAL, STATE AND LOCAL REGULATIONS. ======================= Other Information =======================
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:CYALUME PERSONEL MARKER LIGHT Preparer's Name:MARVIN A. FRIEDMAN CAGE:83289 DEP CAGE:83289 ============= Composition/Information on Ingredients ============= Ingred Name:DIBUTYL PHTHALATE (SARA III) CAS:84-74-2 RTECS #:TI0875000 Fraction by Wt: 45-92% OSHA PEL:5 MG/M3 ACGIH TLV:5 MG/M3; 9192 EPA Rpt Qty:10 LBS DOT Rpt Qty:10 LBS Ingred Name:TERT-BUTYL ALCOHOL(SARA III) CAS:75-65-0 RTECS #:EO1925000 Fraction by Wt: 1-6.5% OSHA PEL:100 PPM ACGIH TLV:100PPM 9394 Ingred Name:HYDROGEN PEROXIDE CAS:7722-84-1 RTECS #:MX0899000 Fraction by Wt: 0.3-2.2% OSHA PEL:1 PPM ACGIH TLV:1 PPM Ingred Name:DIMETHYLPHTHALATE (SARA III) CAS:131-11-3 RTECS #:TI1575000 Fraction by Wt: 0-40% OSHA PEL:5 MG/M3 ACGIH TLV:5 MG/M3; 9192 EPA Rpt Qty:5000 LBS DOT Rpt Qty:5000 LBS ===================== Hazards Identification ===================== LD50 LC50 Mixture:ORAL RAT LD50 GREATER THAN 5.0 GM/KG Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:PRODUCT IS AN ARTICLE CONSISTING OF A PLASTIC TUBE OR SHAPE.CONTAINING AN ACTIVATOR AND A GLASS AMPOULE OF LUMINESCER. PRIME HEALTH HAZARD IS FROM BROKEN GLASS IN THE UNLIKELY EVENT THE EXTERIOR PLAST IC CONTAINER IS RUPTURED. Effects of Overexposure:OVER EXPOSURE IS NOT LIKELY TO CAUSE SIGNIFICANT ACUTE EFFECTS. PRODUCT MUST BE DAMAGED IN ORDER FOR ANY SIGNIFICANT PERSONAL CONTACT TO OCCUR. EYE:GLASS CHIPS MAY CAUSE PHYSICAL INJURY. SKIN:NO IRRIT ATION OBSERVED WITH ANIMAL TESTS,SO NO HUMAN IRRITATION EXPECTED. Medical Cond Aggravated by Exposure:NONE KNOWN. ======================= First Aid Measures ======================= First Aid:EYE:FLUSH WITH WATER AS PRODUCT MAY CONTAIN GLASS CHIPS. IF IRRITATION PERSISTS,GET MEDICAL ATTENTION. SKIN:WASH WITH SOAP & WATER. ===================== Fire Fighting Measures ===================== Flash Point:>200F/93C Extinguishing Media:WATER SPRAY,CARBON DIOXIDE,DRY CHEMICAL. Fire Fighting Procedures:USE WATER SPRAY TO COOL FIRE EXPOSED CONTAINERS. WEAR SELF CONTAINED BREATHING APPARATUS. Unusual Fire/Explosion Hazard:NONE ================== Accidental Release Measures ================== Spill Release Procedures:ABSORB WITH INERT MATERIAL. FLUSH AREA WITH WATER. Neutralizing Agent:NONE ======================Handling and Storage ====================== Handling and Storage Precautions:NO SPECIAL HANDLING OR STORAGE SPECIFIED BY MFR. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:NONE NECESSARY UNLESS PRODUCT IS BROKEN. USE NIOSH CARTRIDGE OR SUPPLIED AIR RESPIRATOR IF TLV'S ARE EXCEEDED. Ventilation:NONE NECESSARY. Work Hygienic Practices:USE NORMAL GOOD PERSONAL HYGIENE PRACTICE. Supplemental Safety and Health MFR ALSO SELLS PRODUCT UNDER THE FOLLOWING TRADE NAMES:LIGHT-UP,LUNKER LIGHTS,LITE-ROPE,GLOW STICK,LIGHT SHAPE,PML,MAGIC IN THE NIGHT. ================== Physical/Chemical Properties ================== HCC:N1 Spec Gravity:1.05 Solubility in Water:IMMISCIBLE Appearance and Odor:5 1/2 IN PLASTIC WAND WITH HANDLE. EMITS GREEN LIGHT WHEN ACTIVATED. ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES NONE REPORTED. Stability Condition to Avoid:NONE REPORTED. Hazardous Decomposition Products:NORMAL PRODUCTS OF COMBUSTION. ==================== Disposal Considerations ==================== Waste Disposal Methods:DISPOSE I/A/W FEDERAL,STATE,LOCAL REGULATIONS. HMIS:PRODUCT SHOULD QUALIFY AS ORDINARY WASTE.
1
eyes_protection_mandatory
===================== Product Identification ===================== Preparer's Name:DOD HMIS/DGSC-SSH CAGE:JO772 CAGE:14153 CAGE:JO772 ============= Composition/Information on Ingredients ============= Ingred Name:ASBESTOS, CHRYSOTILE CAS:12001-29-5 RTECS #:CI6478500 OSHA PEL:0.2 FIBERS/CC ACGIH TLV:2 FIBERS/CC; A1;9192 Ingred Name:ASBESTOS & NATURAL/SYNTHETIC RUBBER COMPOSITION RTECS #:9999999ZZ Ingred Name:GENERIC "MSDS". SPECIFIC ASBESTOS TYPE NOT KNOWN. ONE CITED IS ASSUMED. INFORMATION BASED ON SEGMENT "M" OF "DLSC TIR" RTECS #:9999999ZZ ===================== Hazards Identification ===================== Routes of Entry: Inhalation:YES Skin:NO Ingestion:NO Reports of Carcinogenicity:NTP:YES IARC:YES OSHA:YES Health Hazards Acute and Chronic:ACUTE: NO ACUTE EFFECTS ARE KNOWN; CHRONIC: DUST FROM ABRASIVE ACTIONS(EG. CUTTING, MACHINING, FILING, ETC.) MAYCONTAIN ASBESTOS FIBERS. CHRONIC OVEREXPOSURE TO AIRBORNE FIBERS MAY LEAD TO ASBESTOSIS & MESOTHELIOMA. SMOKINGCOMBINED W/FIBER INHALATION GREATLY INCREASES LUNG CANCER RISK! Explanation of Carcinogenicity:OVEREXPOSURE TO AIRBORNE CONCENTRATIONS OF ASBESTOS MAY LEAD TO ASBESTOSIS AND MESOTHELIOMA. Effects of Overexposure:INHAL: INHALATION OF AIRBORNE DUST CONTAINING ASBESTOS FIBERS ON REPEATED EXPOSURE MAY CAUSE OR CAN LEAD TO ASBESTOSIS/ MESOTHELIOMA; SKIN: N/K; EYE: POTENTIAL IRRITATION FROM AIRBORNE DUST; INGEST: N/K. Medical Cond Aggravated by Exposure:RESPIRATORY DEFICIENCIES DUE TO REPEATED INHALATION OF AIRBORNE FIBERS. ======================= First Aid Measures ======================= First Aid:INHAL: REMOVE TO FRESH AIR. OBTAIN MEDICAL ADVICE; SKIN: WASH EXPOSED AREA WITH SOAP & WATER; EYE: FLOOD W/ WATER. IF IRRITATION OCCURS, GET MEDICAL ATTN; INGEST: CONSULT A PHYSICIAN; OTHER: CHANGE CLOTHING AS REQUIRED TO AVOIDCARRYING DUST PARTICLES INTO OTHER AREAS ===================== Fire Fighting Measures ===================== Flash Point:NONE Extinguishing Media:MATERIAL IS NOT FLAMMABLE ; USE MEDIA APPROPRIATE FOR SURROUNDING FIRE. Fire Fighting Procedures:COMBUSTION PRODUCTS OF THIS MATERIAL MAY BE TOXIC. USE A SELF-CONTAINED BREATHING APPARATUS WHEN FIGHTING FIRES INVOLVING CHEMICAL PRODUCTS. Unusual Fire/Explosion Hazard:NONE KNOWN ================== Accidental Release Measures ================== Spill Release Procedures:USE PROPER PERSONAL PROTECTION. VACUUM OR WET CLEAN IF DUST IS INVOLVED. ANY VACUUM SYSTEM SHOULD BE EQUIPPED W/ AN OUTLET "HEPA" FILTER TO PREVENT REINTRODUCING ASBESTOS FIBERS TO THE ATMOSPHERE. ======================Handling and Storage ====================== Handling and Storage Precautions:HANDLE IN A MATTER TO MINIMIZE FORMATION OR RETENTION OF AIRBORNE DUST. USE PROPER PERSONAL PROTECTION FOR TASK AT HAND. CHECK W/YOUR SAFETY OFFICE!!! Other Precautions:AS MANUFACTURED, LOCKED-IN ASBESTOS DOES NOT PRESENT A HAZARD. ONLY WHEN THE ITEM IS SUBJECTED TO ABRASIVE ACTIONS & DUST IS GENERATED, THEN ASBESTOS FIBERS MAY BE RELEASED & BECOME AIRBORNE. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:IF EXPOSURES EXCEED ESTABLISHED LIMITS, A NIOSH/MSHA APPROVED RESPIRATOR FOR ASBESTOS SHOULD BE USED. CONSULT YOUR SAFETY OFFICE/IH PERSONNEL FOR GUIDANCE FOR THE TASK AT HAND. Ventilation:LOCAL EXHAUST IS RECOMMENDED IN SITUATIONS WHERE DUST IS GENERATED BY ABRASIVE ACTIONS, ABRASION OR OTHER MEANS. Other Protective Equipment:AS REQUIRED FOR TASK AT HAND, AND THE GUIDANCE SET FORTH BY YOUR SAFETY OFFICE OR IH PERSONNEL Work Hygienic Practices:DONOT INHALE DUST CREATED BY ABRADING ACTIONS. USE FULL PROTECTION AGAINST AIRBORNE FIBERS. AVOID AIRBORNE DUST CREATION Supplemental Safety and Health GENERIC "MSDS" CREATED FOR "NSN" IDENTIFIED BY "DISC" AS CONTAINING ASBESTOS.WHEN A MANUFACTURER'S SPECIFIC "MSDS" IS PROVIDED FOR MATERIAL PROCURED UNDER THIS NSN, THIS GENERIC "MSDS" WILL BE REMOVED. ================== Physical/Chemical Properties ================== HCC:T6 Evaporation Rate & Reference:NONE Solubility in Water:NOT SOLUBLE Appearance and Odor:MANUFACTURED COMMODITY DESCRIBED BY LOGISTICS: "ITEM-NAME" Percent Volatiles by Volume:NONE ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES NONE KNOWN Stability Condition to Avoid:NONE KNOWN ==================== Disposal Considerations ==================== Waste Disposal Methods:DUST SHOULD BE HANDLED AS A HAZARDOUS AIR POLLUTANT I/A/W 40CFR61 SUBPART "M" PERTAINING TO ASBESTOS. USE LANDFILLS APPROVED FOR ASBESTOS DISPOSAL. NOTE IF ITEM UNDER CONSIDERATION FOR DISPOSAL IS "FRIABLE OR NON-FRIABLE".
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:0516 WHITE WALL TIRE CLEANER Preparer's Name:R. W. KLUG CAGE:FO778 CAGE:FO778 CAGE:0WT79 ============= Composition/Information on Ingredients ============= Ingred Name:SODIUM DODECYLBENZENESULFONATE, SODIUM LAURYLBENZENESULFONATE, DODECYL BENZENE SODIUM SULFONATE CAS:25155-30-0 RTECS #:DB6825000 Fraction by Wt: 5% EPA Rpt Qty:1000 LBS DOT Rpt Qty:1000 LBS Ingred Name:2-BUTOXYETHANOL (ETHYLENEGLYCOL MONOBUTYL ETHER), BUTYL CELLOSOLVE, BUTYL GLYCOL, GLYCOL ETHER EB CAS:111-76-2 RTECS #:KJ8575000 Fraction by Wt: 4% Other REC Limits:25 PPM (SKIN) OSHA PEL:S, 50 PPM ACGIH TLV:S, 25 PPM; 9293 Ingred Name:SODIUM PHOSPHATE, TRISODIUM PHOSPHATE, TSP, SODIUM PHOSPHATE, TRIBASIC CAS:7601-54-9 RTECS #:TC9490000 Fraction by Wt: 6% Other REC Limits:5 MG/CUM ACGIH TLV:5 MG/CUM (DUST) EPA Rpt Qty:5000 LBS DOT Rpt Qty:5000 LBS ===================== Hazards Identification ===================== Routes of Entry: Inhalation:NOSkin:YES Ingestion:YES Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:EYES: IRRITATION, TISSUE BURNS, PAIN, REDNESS, TEARING, & BLURRED VISION. SKIN: CHEMICAL BURNS, REDNESS, SWELLING, & PAIN. INGESTION: GASTROINTESTINAL IRRITATION. Explanation of Carcinogenicity:NONE Effects of Overexposure:EYES: IRRITATION, TISSUE BURNS, PAIN, REDNESS, TEARING, & BLURRED VISION. SKIN: CHEMICAL BURNS, REDNESS, SWELLING, & PAIN. INGESTION: GASTROINTESTINAL IRRITATION. Medical Cond Aggravated by Exposure:EYE & SKIN DISORDERS ======================= First Aid Measures ======================= First Aid:EYES: FLUSH W/WATER FOR 15 MINS. SKIN: WASH OFF W/WATER. INGESTION: OBTAIN MEDICAL ATTENTION IN ALL CASES. ===================== Fire Fighting Measures ===================== Extinguishing Media:MATERIAL DOES NOT SUPPORT COMBUSTION ================== Accidental Release Measures ================== Spill Release Procedures:CONTAIN & COLLECT W/INERT ABSORBENT. PLACE IN CLOSED CONTAINER FOR DISPOSAL. ======================Handling and Storage ====================== Handling and Storage Precautions:STORE IN CLOSED CONTAINERS. KEEP FROM FREEZING. Other Precautions:PREVENT SKIN CONTACT. ============= Exposure Controls/Personal Protection ============= Ventilation:NORMAL MECHANICAL VENTILATION Other Protective Equipment:EYE WASH STATION, APRON OR OTHER EQUIPMENT Work Hygienic Practices:REMOVE/LAUNDER CONTAMINATED CLOTHING BEFORE REUSE. Supplemental Safety and Health ================== Physical/Chemical Properties ================== Boiling Pt:B.P. Text:212F Spec Gravity:1.032 Solubility in Water:COMPLETE Appearance and Odor:CLEAR, PALE YELLOW LIQUID W/SOAPY ODOR ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES Stability Condition to Avoid:FREEZING ==================== Disposal Considerations ==================== Waste Disposal Methods:DISPOSE OF IN ACCORDANCE W/LOCAL, STATE, & FEDERAL REGULATIONS.
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:146 4825 DEVELOPER D-76,C-0027.100,CONCENTRATE CAGE:19139 CAGE:19139 CAGE:5K871 ============= Composition/Information on Ingredients ============= Ingred Name:SODIUM SULFITE CAS:7757-83-7 RTECS #:WE2150000 Fraction by Wt: 85 - 90% Other REC Limits:NONE RECOMMENDED Ingred Name:HYDROQUINONE (SARA 302/313) (CERCLA) CAS:123-31-9 RTECS #:MX3500000 Fraction by Wt: 4% Other REC Limits:NONE RECOMMENDED OSHA PEL:2 MG/M3 ACGIH TLV:2 MG/M3; 9596 EPA Rpt Qty:1 LB DOT Rpt Qty:1 LB Ingred Name:SODIUM BORATE (TETRABORATE), PENTAHYDRATE CAS:12179-04-3 RTECS #:VZ2540000 Fraction by Wt: 1 - 5% Other REC Limits:NONE RECOMMENDED OSHA PEL:10 MG/M3 ACGIH TLV:1 MG/M3; 9596 Ingred Name:P-METHYLAMINOPHENOL SULFATE (METOL) CAS:55-55-1 RTECS #:SL8650000 Fraction by Wt: 1 - 5% Other REC Limits:NONE RECOMMENDED Ingred Name:BORON OXIDE/BORIC ANHYDRIDE CAS:1303-86-2 RTECS #:ED7900000 Fraction by Wt: <1% Other REC Limits:NONE RECOMMENDED OSHA PEL:15 MG/M3 TDUST ACGIH TLV:10 MG/M3; 9596 ===================== Hazards Identification ===================== LD50 LC50 Mixture:LD50 (ORAL, RAT) IS NOT KNOWN. Routes of Entry: Inhalation:YES Skin:NO Ingestion:NO Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:TARGET ORGANS:EYE, SKIN, RESPIRATORY & GI TRACTS. ACUTE- INHALE:LOW HAZARD FOR RECOMMENDED HANDLING. IF SULFUR DIOXIDE IS RELEASED, CAUSES IRRITATION. AIRBORNE DUST IRRITATING. EYE/SKIN:CAUSES IRRITAT ION. MAY CAUSE ALLERGIC SKIN REACTION. ORAL:HARMFUL IF SWALLOWED. CHRONIC- UNKNOWN. Explanation of Carcinogenicity:NONE Effects of Overexposure:IRRITATION, ALLERGIC SKIN REACTION Medical Cond Aggravated by Exposure:INDIVIDUALS WITH PRE-EXISTING SKIN DISORDERS OR SOME ASTHMATICS OR HYPERSENSITIVE INDIVIDUALS MAY BE MORE SUCCEPTIBLE TO THE EFFECTS FROM EXPOSURE TO THIS PRODUCT. ======================= First Aid Measures ======================= First Aid:GET MEDICAL ATTENTION IF SYMPTOMS PERSIST. SKIN:REMOVE CONTAMINATED CLOTHING. WASH SKIN WITH SOAP & WATER. EYE:FLUSH WITH WATER FOR 15 MINUTES. HOLD EYELIDS OPEN. INHALED:REMOVE TO FRESH AIR. PROVIDE OXYGEN/CPR IF NEEDED. ORAL:IF CONSCIOUS, INDUCE VOMITING IMMEDIATELY AS DIRECTED BY MEDICAL PERSONNEL. CALL A PHYSICIAN/POISON CONTROL CENTER IMMEDIATELY. NEVER GIVE ANYTHING TO AN UNCONSCIOUS PERSON. ===================== Fire Fighting Measures ===================== Flash Point:NONE Extinguishing Media:WATER SPRAY, CARBON DIOXIDE, FOAM OR DRY CHEMICAL FOR SURROUNDING FIRE. USE WATER SPRAY TO COOL FIRE EXPOSED CONTAINERS. Fire Fighting Procedures:WEAR PROTECTIVE CLOTHING AND NIOSH-APPROVED SELF-CONTAINED BREATHING APPARATUS. HAZARDOUS DECOMPOSITION PRODUCTS MAY BE FORMED. Unusual Fire/Explosion Hazard:NONE ================== Accidental Release Measures ================== Spill Release Procedures:FLUSH TO SEWER WITH LARGE AMOUNT OF WATER IF PERMITTED OR SWEEP UP AND PLACE IN A CONTAINER FOR CHEMICAL WASTE. CLEAN SURFACE THOROUGHLY TO REMOVE RESIDUAL CONTAMINATION. AVOID RAISING DUST. Neutralizing Agent:NOT RELEVANT ======================Handling and Storage ====================== Handling and Storage Precautions:STORE AWAY FROM STRONG ACIDS. KEEP CONTAINER CLOSED. KEEP OUT OF REACH OF CHILDREN. Other Precautions:AVOID CONTACT WITH EYES, SKIN AND CLOTHING. USE WITH ADEQUATE VENTILATION. WASH THOROUGHLY AFTER HANDLING. THE ROUTINE USE OF A NONALKALINE (ACID) TYPE OF HAND CLEANER AND REGULAR CLEANING OF WORKING SURFACES WILL MINIMIZE SKIN REACTION. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:IF ENGINEERING CONTROLS DO NOT MAINTAIN AIRBORNE CONCENTRATIONS TO AN ACCETABLE LEVEL, A NIOSH-APPROVED RESPIRATOR FOR DUST MUST BE WORN. IF RESPIRATORS ARE USED, A PROGRAM SHOULD BE INSTITUTED TO ASS URE COMPLIANCE WITH OSHA 29CFR 1910.134. Ventilation:GOOD GENERAL VENTILATION (TYPICALLY 10 AIR CHANGES/HR) SHOULD BE USED. VENTILATION RATES SHOULD BE MATCHED TO CONDITIONS Other Protective Equipment:EYE BATH, WASHING FACILITIES, SAFETY SHOWER AND IMPERVIOUS CLOTHING Work Hygienic Practices:OBSERVE GOOD PERSONAL HYGIENE PRACTICES AND RECOMMENDED PROCEDURES. Supplemental Safety and Health FORMULA CHANGED. FOR PREVIOUS FORMULATIONS, SEE PNI A-D, SAME NSN. SEE PNI X FOR WORKING SOLUTION. ECOLOGICAL INFORMATION:A MODERATE BIOCHEMICAL OXYGEN DEMAND, A HIGH POTENTIAL TO AFFECT AQUATIC ORGAN ISMS. AFTER DILUTION WITH WATER, FOLLOWED BY WASTE TREATMENT, IT IS NOT EXPECTED TO CAUSE ADVERSE ENVIRONMENT EFFECTS ================== Physical/Chemical Properties ================== HCC:N1 NRC/State Lic Num:NOT RELEVANT Viscosity:NOT RELEVANT Evaporation Rate & Reference:NOT RELEVANT Solubility in Water:APPRECIABLE Appearance and Odor:OFF-WHITE SOLID - ODORLESS ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES STRONG ACIDS Stability Condition to Avoid:NONE Hazardous Decomposition Products:SULFUR DIOXIDE MAY BE FORMED. ==================== Disposal Considerations ==================== Waste Disposal Methods:DISCHARGE, TREATMENT OR DISPOSAL MAY BE SUBJECT TO FEDERAL, STATE OR LOCAL LAWS. FLUSH TO SEWER WITH LARGE AMOUNT OF WATER IF ALLOWED.
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:674077 CAVI-LINE CAGE:11107 CAGE:11107 ============= Composition/Information on Ingredients ============= Ingred Name:DICHLOROMETHANE (METHYLENE CHLORIDE) (SUSPECTED HUMAN CARCINOGEN BY ACGIH, NTP, IARC - GROUP 2B) CAS:75-09-2 RTECS #:PA8050000 ACGIH TLV:174 MG/CUM (A2) EPA Rpt Qty:1000 LBS DOT Rpt Qty:1000 LBS Ingred Name:TRICHLOROTRIFLUOROETHANE CAS:354-58-5 RTECS #:KJ3975000 ===================== Hazards Identification ===================== Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES Reports of Carcinogenicity:NTP:YES IARC:YES OSHA:NO Health Hazards Acute and Chronic:INHALATION: PROLONGED EXCESSIVE BREATHING OF VAPORS MAY RESULT IN LUNG/KIDNEY DEMAGE. MAY ALSO CAUSE CARDIAC ARTHYTHMIES. EYES: REVERSIBLE CORNEAL INJURY. SKIN: MAY DRY THE SKIN.CAUSING DERMATITIS. Explanation of Carcinogenicity:METHYL CHLORIDE IS CONSIDERED TO BE AN A2 CARCINOGEN. Medical Cond Aggravated by Exposure:PERSONS W/ANGINA OR HEART DISEASE OR THOSE WHO ARE SMOKERS, OR HEAVY DRINKERS SHOULDN'T BE EXPOSED TO THIS PRODUCT. ======================= First Aid Measures ======================= First Aid:INHALATION: REMOVE TO FRESH AIR. GIVE ARTIFICIAL RESPIRATION IF NOT BREATHING. EYES: FLUSH W/WATER FOR 15 MINS. INGESTION: DON'T INDUCE VOMITING. IF VOMITING OCCURS SPONTANEOUS KEEP VICTIM HEAD BELOW HIS HIPS. DON'T GIVE EPINEPHRINE/SIMILAR DRUGS. OBTAIN MEDICAL ATTENTION IN ALL CASES. ===================== Fire Fighting Measures ===================== Flash Point:NON-FLAMMABLE Extinguishing Media:THIS MATERIAL ISN'T COMBUSTIBLE. USE EXTINGUISHING MEDIA APPROPRIATE FOR SURROUNDING FIRE. Fire Fighting Procedures:FIRE FIGHTERS SHOULD WEAR SCBA/FULL PROTECTIVE CLOTHING. USE WATER SPRAY TO COOL CONTAINERS/STRUCTURES EXPOSED TO FIRE. Unusual Fire/Explosion Hazard:EXTINGUISH NEARBY SOURCES OF IGNITION SINCE VAPORS DECOMPOSE TO HAZARDOUS PRODUCTS AT HIGH TEMPERATURES. ================== Accidental Release Measures ================== Spill Release Procedures:WEAR FULL PROTECTIVE CLOTHING INCLUDING SCBA & W/INERT MATERIAL & PLACE IN DOT-APPROVED WASTE CONTAINERS. KEEP OUT OF SEWERS, STORMDRA INS, SURFACE WATERS, & SOIL. ======================Handling and Storage ====================== Handling and Storage Precautions:STORE AT 75F OR BELOW. KEEP TIGHTLY CLOSED WHEN NOT IN USE. WASH THOROUGHLY AFTER HANDLING. DON'T WELD, CUT, GRIND, OR DRILL NEAR THIS MATERIAL. Other Precautions:KEEP AWAY FROM FOOD & BEVERAGE. VAPORS OF THIS MATERIAL ARE DENSER THAN AIR & WILL COLLECT IN LOW-LYING AREAS. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:NIOSH APPROVED SELF-CONTAINED BREATHING APPARATUS IN PRESSURE DEMAND MODE IR USE CONDITIONS GENERATE VAPOR OR MISTS. CANISTER RESPIRATORS MAY BE INEFFECTIVE. Ventilation:LOCAL EXHAUST: CAPABLE OF MAINTAINING EMISSIONS OF POINT OF USE <PEL. Other Protective Equipment:LONG-SLEEVED SHIRT, TROUSERS, SAFETY SHOES. Work Hygienic Practices:OBSERVE NORMAL CARE WHEN WORKING WITH CHEMICALS. Supplemental Safety and Health ================== Physical/Chemical Properties ================== Boiling Pt:B.P. Text: 40C Vapor Density:2.9 Spec Gravity:1.4 Evaporation Rate &amp; Reference:(BU AC = 1): <1 Solubility in Water:INSOLUBLE Appearance and Odor:CLEAR YELLOW LIQUIS W CHARACTERISTIC ODOR ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES ALKALI OR ALKALINE EARTH METALS, ALUMINUM, ZINC, WATER, MOIST AIR, OXIDIZING MATERIALS. Stability Condition to Avoid:IGNITION SOURCES, OPEN FLAMES, WELDING ARC, OTHER HIGH TEMPERATURE SOURCES. Hazardous Decomposition Products:CO, CO2, HYDROCHLORIC ACID, CHLORINE, PHOSGENE, HYDROGEN FLUORIDE. Conditions to Avoid Polymerization:OPEN FLAMES, WELDING ARCS, OTHER HIGH TEMPERATURES SOURCES WHICH MAY INDUCE THERMAL DECOMPOSITION. ==================== Disposal Considerations ==================== Waste Disposal Methods:DISPOSE OF IN ACCORDANCE WITH LOCAL, STATE, AND FEDERAL REGULATIONS.
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:ADH CAGE:53798 CAGE:53798 ============= Composition/Information on Ingredients ============= Ingred Name:HEXANE (N-HEXANE) (CERCLA) CAS:110-54-3 RTECS #:MN9275000 Fraction by Wt: <65% OSHA PEL:500 PPM ACGIH TLV:50 PPM; 9495 EPA Rpt Qty:1 LB DOT Rpt Qty:1 LB Ingred Name:PROPANE CAS:74-98-6 RTECS #:TX2275000 Fraction by Wt: <25% OSHA PEL:1000 PPM ACGIH TLV:ASPHYXIANT; 9495 ===================== Hazards Identification ===================== LD50 LC50 Mixture:NONE SPECIFIED BY MANUFACTURER. Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:ACUTE: IN A CONFINED AREA, VAPORS IN HIGH CONCENTRATIONS MAY BE ANESTHETIC. THIS PRODUCT MAY BE AN IRRITANT TO SKIN OR NOSE. OVEREXPOSURE MAY RESULT IN HEADACHE, DIZZINESS, OR NAUSEA. HARMFUL OR FATAL IF SWALLOWED. CHRONIC: CAN CAUSE MENTAL CONFUSION, DEPRESSION, FATIGUE, LOSS OF APPETITE, NAUSEA, (EFTS OF OVEREXP) Explanation of Carcinogenicity:NOT RELEVANT. Effects of Overexposure:HLTH HAZ:VOMITING, COUGH, LOSS OF SENSE OF BALANCE, AND VISUAL DISTURBANCES. ALSO COULD CAUSE LIVER AND KIDNEY DAMAGE. Medical Cond Aggravated by Exposure:NONE SPECIFIED BY MANUFACTURER. ======================= First Aid Measures ======================= First Aid:INGEST:DO NOT INDUCE VOMIT. HARMFUL/FATAL IF SWALLOWED. CONTAINS HEXANE. CALL PHYSICIAN IMMED. INHAL:REMOVE PERSON TO FRESH AIR. IF IRRIT DEVELOPS, CONSULT A PHYSICIAN. EYES:FLUSH EYES IMMED WITH PLEN TY OF COOL H*2O FOR AT LEAST 15 MIN. IFIRRIT DEVELOPS, CONSULT A PHYSICIAN. DO NOT WEAR CONTACT LENSES WHILE USING THIS PROD. SKIN:WASH THOROUGHLY W/SOAP & WATER. IF IRRITATION DEVELOPS, CONSULT MD. ===================== Fire Fighting Measures ===================== Flash Point Method:TOC Flash Point:<20F,<-7C Extinguishing Media:CARBON DIOXIDE, DRY CHEMICAL, OR FOAM. Fire Fighting Procedures:USE NIOSH APPRVD SCBA & FULL PROT EQUIP . H*2O MAY BE INEFT. KEEP CNTNRS COOL. USE SHIELDING TO PROTECT PERS FROM VENTING, RUPTURING, OR BURSTING CANS. Unusual Fire/Explosion Hazard:DO NOT SPRAY NEAR OPEN FLAME. EXPOSE TO TEMPERATURES ABOVE 120F MAY CAUSE CANS TO VENT, RUPTURE, OR BURST. ================== Accidental Release Measures ================== Spill Release Procedures:REMOVE SOURCES OF FLAME, SPARK, OR HEAT. VENTILATE AREA OF SPILL. ABSORB SPILL ON STATE OIL ABSORBENT. WASH RESIDUE WITH PLENTY OF WATER. Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER. ======================Handling and Storage ====================== Handling and Storage Precautions:WARNING: CONTENTS UNDER PRESS. DO NOT PUNCTURE, INCINERATE/STORE CANS IN DIRECT SUNLIGHT, NEAR OPEN FLAMES/SPARKS, OR WHERE TEMP MAY EXCEED 120F. Other Precautions:HARMFUL/FATAL IF SWALLOWED. EXTREMELY FLAMM. READ & FOLLOW ALL LABEL DIRECTIONS & PREC BEFORE USING THE PROD. THESE PRODS ARE INTENDED FOR INDUSTRIAL & INSTITUTIONAL USE ONLY. NOT FOR HOUSEHOLD USE/RE SALE KEEP OUT OF THE REACH OF CHILDREN. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:IF TLV IS EXCEEDED, WEAR NIOSH APPROVED RESPIRATOR WITH ORGANIC VAPOR CARTRIDGES. Ventilation:MECHANICAL VENTILATION IS REQUIRED. DO NOT USE IN A CONFINED SPACE. Other Protective Equipment:EYE WASH FOUNTAIN & DELUGE SHOWER WHICH MEET ANSI DESIGN CRITERIA . CLEAN WATER SOURCE IN CASE OF EYE CONTACT. Work Hygienic Practices:NONE SPECIFIED BY MANUFACTURER. Supplemental Safety and Health NONE SPECIFIED BY MANUFACTURER. ================== Physical/Chemical Properties ================== Boiling Pt:B.P. Text:0F,-18C Appearance and Odor:AN AEROSOL ADHESIVE WITH A SOLVENT LIKE ODOR. Percent Volatiles by Volume:80 ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES STRONG OXIDIZERS, CAUSTICS, CHEMICALLY ACTIVE LIGHT METALS. MAY AFFECT SOME PLASTICS, SUCH AS POLYSTYRENE. Stability Condition to Avoid:TEMPERATURES ABOVE 120F. Hazardous Decomposition Products:BURNING THIS PRODUCT MAY RESULT IN THE FORMATION OF CARBON DIOXIDE, CARBON MONOXIDE. ==================== Disposal Considerations ==================== Waste Disposal Methods:DO NOT INCINERATE CANS. GIVE CANS TO A DISPOSAL SERVICE EQUIPPED TO PROPERLY DISPOSE OF PRESSURIZED CANS. FOLLOW ALL FEDERAL, STATE AND LOCAL REGULATIONS REGARDING WASTE DISPOSAL.
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:08545, INSTITUTIONAL BOWL QUICK TOILET (SUPDAT) CAGE:DO549 CAGE:DO549 CAGE:74188 ============= Composition/Information on Ingredients ============= Ingred Name:HYDROCHLORIC ACID; (HYDROGEN CHLORIDE) (SARA 302/313) (CERCLA) CAS:7647-01-0 RTECS #:MW4025000 Fraction by Wt: 15% OSHA PEL:C 5 PPM ACGIH TLV:C 5 PPM EPA Rpt Qty:5000 LBS DOT Rpt Qty:5000 LBS Ingred Name:PHOSPHORIC ACID (SARA 313) (CERCLA) CAS:7664-38-2 RTECS #:TB6300000 Fraction by Wt: 6% OSHA PEL:1 MG/M3 ACGIH TLV:1 MG/M3/3 STEL EPA Rpt Qty:5000 LBS DOT Rpt Qty:5000 LBS ===================== Hazards Identification ===================== LD50 LC50 Mixture:NONE SPECIFIED BY MANUFACTURER. Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:ACUTE:PRODUCT IS CORROSIVE. CONTACT MAY RESULT IN TISSUE DAMAGE. MAY BE FATAL IF SWALLOWED. MAY CAUSE SERIOUS PERMANENT EYE INJURY & BURNS TO SKIN. ACID VAPORS WILL BE IRRITATING TO MUCOUS MEMBRANES O F THE UPPER RESPIRATORY TRACT. Explanation of Carcinogenicity:NOT RELEVANT. Effects of Overexposure:SEE HEALTH HAZARDS. Medical Cond Aggravated by Exposure:NONE. ======================= First Aid Measures ======================= First Aid:INHAL:REMOVE TO FRESH AIR. SUPPORT BREATHING (GIVE O*2/ARTF RESP) . EYES:FLUSH THORO W/WATER FOR @ LEAST 15 MINS. GET MED ATTN. SKIN:FLUSH W/WATER & WASH THORO, THEN COVER WITH MOIST MAGNESIA OR BAKING SODA. GET MED ATTN. INGEST:CALLPHYS IMMED. DRINK TEASPOONFUL OR MORE OF MAGNESIA, CHALK, OR SMALL PIECES OF SOAP, SOFTENED WITH WATER OR RAW EGG WHITE. ===================== Fire Fighting Measures ===================== Fire Fighting Procedures:NIOSH/MSHA APPRVD SCBA & FULL PROT EQUIP . WHEN PRESENT IN FIRE FIGHTING, CARE SHOULD BE TAKEN TO AVOID EXPOS TO SKIN & EYES FROM MISTS & (SUPDAT) Unusual Fire/Explosion Hazard:ACIDS CAN REACT WITH METALS TO LIBERATE HYDROGEN. ================== Accidental Release Measures ================== Spill Release Procedures:NEUT W/ALKALINE MATL SUCH AS LIME OR SODA ASH & FLUSH NEUTRALIZED RESIDUE TO SANITARY SEWER DRAIN W/LG QTY OF WATER/COMBINE W/SAND & EARTH & DISPOSE OF AS SOLID WASTE. PROD IS U.S. EPA REGISTERED PEST ICIDE. EMPTY CNTNRS MUST BE RINSED. (SUPDAT) Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER. ======================Handling and Storage ====================== Handling and Storage Precautions:STORE IN COOL, DRY, WELL VENTILATED AREA. DO NOT STORE IN AREAS WHERE FOOD INGREDIENTS ARE KEPT. Other Precautions:DO NOT SOTRE NEAR EXPLOSIVES. PRODUCT IS CLASSIFIED AS CORROSIVE UNDER DOT REGULATIONS. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:NIOSH/MSHA APPROVED RESPIRATOR APPROPRIATE FOR EXPOSURE OF CONCERN . Ventilation:MECHANICAL(GENERAL):ACCEPTABLE. Other Protective Equipment:RUBBER OR PLASTIC APRONS. EYE WASH FOUNTAIN; SAFETY SHOWER. Work Hygienic Practices:NONE SPECIFIED BY MANUFACTURER. Supplemental Safety and Health MFR TRADE NAME/PART NO:BOWL CLEANER. FIRE FIGHT PROC:SPLASHES, AVOID INHAL OF VAPORS. SPILL/RELEASE:SPILLED PROD MEETS U.S. EPA DEFINITION OF HAZ WASTE. WAREHOUSES & DISTRIBUTORS MUST RECORD METH & LO CATION OF DISP OF CONTENTS & CNTNRS. EYE PROT:& FULL LENGTH FACESHIELD . ================== Physical/Chemical Properties ================== Boiling Pt:B.P. Text:200F,93C Spec Gravity:1.11 (H*2O=1) Solubility in Water:APPRECIABLE Appearance and Odor:VISCOUS, YELLOW-GREEN LIQUID, FRESH SMELL Percent Volatiles by Volume:65.7 ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES AVOID CONTACT W/METALS, CHLORINE BLEACH, OR OTHER CHLORINE PRODUCTS, NH*4 COMPOUNDS & OTHER BASIC MATERIALS. Stability Condition to Avoid:DO NOT STORE AT HIGH TEMPERATURES. Hazardous Decomposition Products:CAN REACT W/METALS TO LIBERATE HYDROGEN & W/CHLORINE & AMMONIUM CONTAINING PROD TO FORM CHLORINE CONTAINING GASES. ==================== Disposal Considerations ==================== Waste Disposal Methods:U.S. EPA REGS PROHIBIT LANDFILL BURIAL OF LIQ HAZ WASTES & REQ THAT DMG/WASTE CNTNR OF PROD MUST BE NEUTRALIZED AND/OR SOLIDIFIED. DISPOSAL IS TO BE PERFOMED IN COMPLIANCE WITH ALL FEDERAL, STATE AND LOCAL REGULATIONS.
1
eyes_protection_mandatory